European Journal of Chemistry 2014, 5(2), 370-373 | doi: https://doi.org/10.5155/eurjchem.5.2.370-373.1032 | Get rights and content






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Synthesis and recognition properties of colorimetric anion chemosensor bearing 2,4-dinitrophenylhydrazone and indene-1,3-dione moieties


Fatma Aydın (1,*)

(1) Çanakkale Onsekiz Mart University, Department of Chemistry, 17100, Çanakkale, Turkey
(*) Corresponding Author

Received: 06 Feb 2014 | Accepted: 02 Mar 2014 | Published: 30 Jun 2014 | Issue Date: June 2014

Abstract


A new receptor named, 2-(2-(2,4-dinitrophenyl)hydrazono)2H-indene-1,3-dione, used as a colorimetric sensor based on 2,4-dinitrophenylhydrazone derivative of ninhydrin was synthesized by simple step with good yields and characterized by IR and 1H, 13C NMR and MS spectroscopic techniques. The anion recognition properties were studied by UV-Vis spectroscopic technique. The results showed that the receptor had a higher affinity to F-, CN-, H2PO4-, CH3COO- and OH-, but showed no evident binding with Cl-, Br- and I-. Binding of the reseptor to anions such as CN-, AcO-, F-, H2PO4- and OH-exhibited an obvious color change from greenish yellow to purplish blue, which was possible to observe by the naked eye.


Keywords


Ninhydrin; Naked-eye; Anion receptor; UV-Vis titration; Association constant; 2,4-Dinitrophenylhydrazine

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DOI: 10.5155/eurjchem.5.2.370-373.1032

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Funding information


Çanakkale Onsekiz Mart University Research Fund (Project No: BAP-2010-57), Çanakkale Onsekiz Mart University, Çanakkale, Turkey

Citations

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[1]. Vetriarasu Venkatesan, S. K. Ashok Kumar, Suban K. Sahoo
Spectrophotometric and RGB performances of a new tetraphenylcyclopenta-derived Schiff base for the quantification of cyanide ions
Analytical Methods  11(8), 1137, 2019
DOI: 10.1039/C8AY02401D
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How to cite


Aydın, F. Eur. J. Chem. 2014, 5(2), 370-373. doi:10.5155/eurjchem.5.2.370-373.1032
Aydın, F. Synthesis and recognition properties of colorimetric anion chemosensor bearing 2,4-dinitrophenylhydrazone and indene-1,3-dione moieties. Eur. J. Chem. 2014, 5(2), 370-373. doi:10.5155/eurjchem.5.2.370-373.1032
Aydın, F. (2014). Synthesis and recognition properties of colorimetric anion chemosensor bearing 2,4-dinitrophenylhydrazone and indene-1,3-dione moieties. European Journal of Chemistry, 5(2), 370-373. doi:10.5155/eurjchem.5.2.370-373.1032
Aydın, Fatma. "Synthesis and recognition properties of colorimetric anion chemosensor bearing 2,4-dinitrophenylhydrazone and indene-1,3-dione moieties." European Journal of Chemistry [Online], 5.2 (2014): 370-373. Web. 5 Dec. 2020
Aydın, Fatma. "Synthesis and recognition properties of colorimetric anion chemosensor bearing 2,4-dinitrophenylhydrazone and indene-1,3-dione moieties" European Journal of Chemistry [Online], Volume 5 Number 2 (30 June 2014)

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DOI Link: https://doi.org/10.5155/eurjchem.5.2.370-373.1032

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