European Journal of Chemistry 2014, 5(3), 388-393 | doi: https://doi.org/10.5155/eurjchem.5.3.388-393.1038 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2


Ikram Dhouib (1,*) , Philippe Guionneau (2) , Tahar Mhiri (3) , Zakaria Elaoud (4)

(1) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia
(2) CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr A. Schweitzer, Pessac, F-33608, France
(3) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia
(4) Laboratoire de Physico-Chimie de l’Etat Solide, Département de Chimie, Faculté des Sciences de Sfax, Université de Sfax, Sfax 3000, Tunisia
(*) Corresponding Author

Received: 26 Feb 2014 | Revised: 13 Mar 2014 | Accepted: 13 Mar 2014 | Published: 30 Sep 2014 | Issue Date: September 2014

Abstract


An organic-inorganic hybrid compound of tetraethylammonium dihydrogenarsenate bis-arsenic acid salts of formula [(CH3CH2)4N].[H2AsO4].[H3AsO4]2(TEAs) were grown by the slow evaporation and characterized by means of single crystal X-ray diffraction, thermal analysis, FT-IR and Raman spectroscopy. This compound crystallize in the space groups Cc with unit cell parameters, a= 20.105(2) Å; b= 7.342(4) Å, c = 15.292(2) Å, γ = 115(4)°, Z = 4, R= 0.07. The structure has solved using direct methods and refined by least-squares analysis. In this case, the structure consists of infinite parallel two-dimensional planes built of mutually H2AsO4, H3AsO4 tetrahedra connected by strong O-H···O hydrogen bonding. The thermoanalytical properties were studied using TG of TEAs method in the temperature ranges from 300 to 440 K for this hygroscopic sample. DSC measurement was carried out in the temperature range from 305 to 425 K.


Keywords


Arsenic acid; Crystal structure; Organic compounds; Raman spectroscopy; Infrared spectroscopy; Differential scanning calorimetry

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.5.3.388-393.1038

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 980 times | PDF Article downloaded 330 times


Citations

/


[1]. Ikram Dhouib, Philippe Guionneau, Zakaria Elaoud
Vibrational spectroscopy, electrical characterization, nonlinear optical properties and DFT calculation of (NEt4)(H2AsO4)(H3AsO4)2
Journal of Coordination Chemistry  70(21), 3585, 2017
DOI: 10.1080/00958972.2017.1406082
/


[2]. Karolina Schwendtner, Uwe Kolitsch
Three new acid M + arsenates and phosphates with multiply protonated As/PO4 groups
Acta Crystallographica Section C Structural Chemistry  75(8), 1134, 2019
DOI: 10.1107/S2053229619008489
/


[3]. Dhouha Abid, Ikram Dhouib, Philippe Guionneau, Stanislav Pechev, Iskandar Chaabane, Nathalie Daro, Zakaria Elaoud
Proton conduction study of a new selenate-based hybrid compound
Journal of Alloys and Compounds  824, 153826, 2020
DOI: 10.1016/j.jallcom.2020.153826
/


References

[1]. Laine, R.; Sanchez, C.; Brinker, C. J.; Gianellis (Eds.), E. Organic/Inorganic Hybrid Materials, Materials Research Society Series, Vol. 628, Pittsburgh, PA. 2000.

[2]. Sanchez, C.; Lebeau, B. Mater. Res. Soc. Bull. 2001, 26, 377-387.
http://dx.doi.org/10.1557/mrs2001.91

[3]. Zdanowska-Fraczek, M.; Holderna-Natkaniec, K.; Fraczek, Z. J.; Jakubas, R. Solid State Ion. 2009, 180, 9-12.
http://dx.doi.org/10.1016/j.ssi.2008.10.018

[4]. Chaabane, I.; Hlel, F.; Guidara, K. J. Alloys Compd. 2008, 461, 495-500.
http://dx.doi.org/10.1016/j.jallcom.2007.07.031

[5]. Sakai, K.; Takemura, M.; Kawabe, Y. J. Lumin. 2010, 130, 2505-2507.
http://dx.doi.org/10.1016/j.jlumin.2010.08.026

[6]. Pradeesha, K.; Sharachandar, Y. G.; Singhb, M.; Vijaya, P. G. Mater. Chem. Phys. 2010, 124, 44-47.
http://dx.doi.org/10.1016/j.matchemphys.2010.07.037

[7]. Vishwakarma, A.; Ghalsasi, P.; Navamoney, A.; Lan, Y.; Powell, A. Polyhedron 2011, 30, 1565-1570.
http://dx.doi.org/10.1016/j.poly.2011.03.025

[8]. Aruta, C.; Licci, F.; Zappettini, A.; Bolzoni, F.; Rastelli, F.; Ferro, P.; Bezagni, T. Appl. Phys. A 2005, 81, 963-968.
http://dx.doi.org/10.1007/s00339-004-3102-3

[9]. Bujak, M.; Zaleski, J. Cryst. Eng. 2001, 4, 241-243.
http://dx.doi.org/10.1016/S1463-0184(01)00018-1

[10]. Karoui, K.; Rhaiem, A. B.; Guidara, K. Physica B 2012, 407, 489-493.
http://dx.doi.org/10.1016/j.physb.2011.11.021

[11]. Baouab, L.; Jouini, A. J. Solid State Chem. 1998, 141, 343-351.
http://dx.doi.org/10.1006/jssc.1998.7933

[12]. Averbuch-Pouchot, M. T.; Durif, A. Acta Cryst. C 1987, 43, 1894-1896.
http://dx.doi.org/10.1107/S0108270187089716

[13]. Averbuch-Pouchot, M. T.; Durif, A.; Guitel, J. C. Acta Cryst. C 1988, 44, 1968-1972.
http://dx.doi.org/10.1107/S0108270188000502

[14]. Averbuch-Pouchot, M. T.; Durif, A.; Guitel, J. C. Acta Cryst. C 1988, 44, 99-102.
http://dx.doi.org/10.1107/S0108270187008539

[15]. Bagieu-Beucher, M. Acta Cryst. C 1990, 46, 238-240.
http://dx.doi.org/10.1107/S0108270189006177

[16]. Averbuch-Pouchot, M. T.; Durif, A.; Guitel, J. C. Acta Cryst. C 1989, 45, 421-423.
http://dx.doi.org/10.1107/S0108270188011977

[17]. Baran, J.; Sledz, M.; Drozd, M.; Pietraszko, A.; Haznar, A.; Ratajczak, H. J. Mol. Struct. 2000, 526, 361-371.
http://dx.doi.org/10.1016/S0022-2860(00)00530-5

[18]. Amirthaganesan, G.; Kandaswamy, M. A.; Dhandapani, M. Mater. Chem. Phys. 2008, 110, 328-331.
http://dx.doi.org/10.1016/j.matchemphys.2008.02.006

[19]. Dhouib, I.; Al-Juaid, S.; Mhiri, T.; Elaoud, Z. Cryst. Struct. Theory Appl. 2013, 2, 8-15.
http://dx.doi.org/10.4236/csta.2013.21002

[20]. Dhouib, I.; Elaoud, Z.; Mhiri, T.; Daoud, A. J. Chem. Crystallogr. 2012, 42, 5, 513-518.
http://dx.doi.org/10.1007/s10870-011-9997-6

[21]. Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Eur. J. Chem. 2013, 4(2), 117-120.
http://dx.doi.org/10.5155/eurjchem.4.2.117-120.738

[22]. Sheldrick, G. M.; SHELX-97, Program for the Solution of Crystal Structures and Crystal Determination, Univ. of Göttingen: Germany, 1997.

[23]. Baur, W. Acta Crystallgr. B 1974, 30, 1195-1215.
http://dx.doi.org/10.1107/S0567740874004560

[24]. Brown, I. D. Acta Cryst. A 1976, 32, 24-31.
http://dx.doi.org/10.1107/S0567739476000041

[25]. Blessing, R. H. Acta Cryst. B 1986, 42, 604-613.
http://dx.doi.org/10.1107/S0108768186097641

[26]. Nailii, H.; Mhiri, T.; Jaud, J. J. Solid. State Chem. 2001, 161, 9-16.

[27]. Le Calve, N.; Romain, F.; Limage, M. H.; A. Novak, A. J. Mol. Struct. 1989, 200, 131-137.

[28]. Hubert, J. I.; Jayakumar, V. S.; Aruldhas, G. J. Solid State Chem. 1995, 120, 343-347.
http://dx.doi.org/10.1006/jssc.1995.1418

[29]. Romain, F.; Novak, A. J. Mol. Struct. 1991, 263, 69-74.
http://dx.doi.org/10.1016/0022-2860(91)80056-A

[30]. Rui-Zhou, Z.; Xiao-Hong, L. Xian-Zhou, Z. Chin. J. Struct. Chem. 2012, 31, 1395-1408.

[31]. Silverstein, R. M.; Webster, F. X. Spectrometric, Identification of Organic Compounds, Wiley, New York, 1973.

[32]. Gosniowska, M.; Ciunik, Z.; Bator, G.; Jakubas, R.; Baran, J. J. Mol. Struct. 2000, 555, 243-255.
http://dx.doi.org/10.1016/S0022-2860(00)00607-4

[33]. Karbowiak, M.; Hanuza, J.; Janczak, J.; Drozdzynski, J. J. Alloys Compd. 1995, 225, 338-343.
http://dx.doi.org/10.1016/0925-8388(94)07117-9

[34]. Karabacak, M.; Cinar, Z.; Kurt, M.; Sudha, S.; Sundaraganesan, N. Spectrochim. Acta A 2012, 85, 179-189.
http://dx.doi.org/10.1016/j.saa.2011.09.058

[35]. Colthup, N. B.; Daly, L. H.; Wiberley, S. E. Introduction to Infrared and Raman Spectroscopy, Academic Press, New York, 1990.

[36]. Heddrich, H. G.; Blom, C. E. J. Chem. Phys. 1989, 90, 4660-4663.
http://dx.doi.org/10.1063/1.456610

[37]. Heddrich, H. G.; Blom, C. E. J. Mol. Spectrosc. 1990, 140, 103-106.
http://dx.doi.org/10.1016/0022-2852(90)90009-F

[38]. Kirkwood, A. D.; Bier, K. D.; Thompson, J. K.; Haslett, T. L.; Hubber, A. S.; Moskovits, M. J. Phys. Chem. 1991, 95, 2644-2652.
http://dx.doi.org/10.1021/j100160a006

[39]. Edsall, J. T. J. Chem. Phys. 1937, 5, 225-232.
http://dx.doi.org/10.1063/1.1750013

[40]. Hajlaoui, S.; Chaabane, I.; Oueslati, A.; Guidara, K.; Bulou, A. Spectrochimi Acta A. 2014, 117, 225-233.
http://dx.doi.org/10.1016/j.saa.2013.07.088

[41]. Marchon B.; Novak, A. J. Chem. Phys. 1985, 78, 2105-2110.
http://dx.doi.org/10.1063/1.445073

[42]. Ohno, N.; Lockwood, D. J. J. Chem. Phys. 1985, 83, 4374-3379.
http://dx.doi.org/10.1063/1.449053

[43]. Choi. B. K.; Kim, J. J. Jpn. J. Appl. Phys. 1985, 24, 912-914.

[44]. Baran, J. J. Mol. Struct. 1987, 162, 211-228.
http://dx.doi.org/10.1016/0022-2860(87)87054-0

[45]. Hadzi, D.; Bratos, S. The Hydrogen Bond, Vol. 2, North-Holland, Amsterdam, 1976, p. 565.

[46]. Hofacker, G. L.; Marechal, Y.; Ratner, M. A. The Hydrogen Bond, Vol. 1, North-Holland, Amsterdam, 1976, p. 295.

Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Dhouib, I.; Guionneau, P.; Mhiri, T.; Elaoud, Z. Eur. J. Chem. 2014, 5(3), 388-393. doi:10.5155/eurjchem.5.3.388-393.1038
Dhouib, I.; Guionneau, P.; Mhiri, T.; Elaoud, Z. Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2. Eur. J. Chem. 2014, 5(3), 388-393. doi:10.5155/eurjchem.5.3.388-393.1038
Dhouib, I., Guionneau, P., Mhiri, T., & Elaoud, Z. (2014). Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2. European Journal of Chemistry, 5(3), 388-393. doi:10.5155/eurjchem.5.3.388-393.1038
Dhouib, Ikram, Philippe Guionneau, Tahar Mhiri, & Zakaria Elaoud. "Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2." European Journal of Chemistry [Online], 5.3 (2014): 388-393. Web. 27 May. 2020
Dhouib, Ikram, Guionneau, Philippe, Mhiri, Tahar, AND Elaoud, Zakaria. "Crystal structure, thermal behavior and vibrational studies of tetraethylammonium dihydrogenarsenate bis-arsenic acid [(C2H5)4N].[H2AsO4].[H3AsO4]2" European Journal of Chemistry [Online], Volume 5 Number 3 (30 September 2014)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.5.3.388-393.1038

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2014, 5(3), 388-393 | doi: https://doi.org/10.5155/eurjchem.5.3.388-393.1038 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort