European Journal of Chemistry 2015, 6(3), 237-241. doi:10.5155/eurjchem.6.3.237-241.1265

Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)


Ilkay Gumus (1,*) , Ummuhan Solmaz (2) , Omer Celik (3) , Gun Binzet (4) , Gulten Kavak Balcı (5) , Hakan Arslan (6)

(1) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, 33343, Turkey
(2) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, 33343, Turkey
(3) Science and Technology Application and Research Center, Dicle University, Diyarbakır, 21280, Turkey
(4) Department of Chemistry, Faculty of Education, Mersin University, Mersin, 33343, Turkey
(5) Department of Physics, Faculty of Sciences, Dicle University, 21280 Diyarbakır, Turkey
(6) Department of Chemistry, Faculty of Arts and Science, Mersin University, Mersin, 33343, Turkey
(*) Corresponding Author

Received: 08 Apr 2015, Accepted: 28 May 2015, Published: 30 Sep 2015

Abstract


cis-Bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II), cis-[Pt(L-O,S)2], was synthesized and characterized by elemental analyses, FT-IR and NMR techniques. The obtained metal complex was also characterized by a single crystal X-ray diffraction study. Molecule formula of the title compound is C24H28F2N4O2PtS2: tetragonal, space group I41/a, a = 19.7530(4) Å, b = 19.7530(4) Å, c = 13.7137(3) Å, = 5350.83(19) Å3, Z = 8, Dcalc = 1.742 g/mm3, 22890 reflections measured (3.62 ≤ 2Θ ≤ 52.72), 2733 (Rint = 0.0272), which were used in all calculations. A square-planar coordination geometry is formed around the Pt atom by two S atoms and two O atoms of the N-(diethylcarbamothioyl)-4-fluorobenzamide ligand which are a cis configuration.


Keywords


Thiourea; Synthesis; Cis-configuration; Benzoyl thiourea; Platinum complex; X-ray single crystal diffraction

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DOI: 10.5155/eurjchem.6.3.237-241.1265

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References

[1]. Katritzky, A. R.; Gordeev, M. F. J. Chem. Soc. Perkin 1991, 1, 2199-2203.
http://dx.doi.org/10.1039/p19910002199

[2]. Saeed, S.; Rashid, N.; Jones, P.; Hussain R. Eur. J. Chem. 2011, 2, 77-82.
http://dx.doi.org/10.5155/eurjchem.2.1.77-82.183

[3]. Gunasekaran, N.; Jerome, P.; Ng, S. W. J. Mol. Catal. A. 2012, 353-354, 156-162.
http://dx.doi.org/10.1016/j.molcata.2011.11.019

[4]. Gunasekaran, N.; Remya, N.; Radhakrishnan, S.; Karvembu, R. J. Coord. Chem. 2011, 64, 491-501.
http://dx.doi.org/10.1080/00958972.2010.548007

[5]. Gunasekaran, N.; Karvembu, R. Inorg. Chem. Commun. 2010, 13, 952-955.
http://dx.doi.org/10.1016/j.inoche.2010.05.004

[6]. Duan, L. P.; Xue, J.; Xu, L. L.; Zhang, H. B. Molecules 2010, 15, 6941-6947.
http://dx.doi.org/10.3390/molecules15106941

[7]. Saeed, A.; Rafique, H.; Hameed, A.; Rasheed, S. Pharm. Chem. J. 2008, 42, 191-195.
http://dx.doi.org/10.1007/s11094-008-0094-x

[8]. Cunha, S.; Macedo, F. C.; Costa, G. A. N.; Rodrigues, M. T.; Verde, R B. V.; Souza, N. L. C.; Vencato, I.; Lariucci, C.; Sa, F. P. Monatsh. Chem. 2007, 138, 511-516.
http://dx.doi.org/10.1007/s00706-007-0600-y

[9]. Diþu, L. M.; Mihaescu, G.; Chifiriuc, C.; Bleotu, C.; Morusciag, L.; Niþulescu, G. M.; Missir, A. Roum. Arch. Microbiol. Immunol. 2010, 69, 41-47.

[10]. Limban, C.; Missir, A. V.; Chirita, I. C.; Badiceanu, C. D.; Draghici, C.; Balostescu, M. C.; Stamatoiu, O. Rev. Roum. Chim. 2008, 53, 595-602.

[11]. Limban, C.; Missir, A. V.; Chirita, I. C.; Neagu, A. F.; Draghici, C.; Chifiriuc, M. C. Rev. Chim (Bucharest) 2011, 62, 168-173.

[12]. Nitulescu, G.; Draghici, C.; Chifiriuc, M.; Marutescu, L.; Bleotu, C.; Missir, A. Med. Chem. Res. 2012, 21, 308-314.
http://dx.doi.org/10.1007/s00044-010-9541-9

[13]. Binzet, G.; Kulcu, N.; Florke, U.; Arslan, H. J. Coord. Chem. 2009, 62, 3454-3462.
http://dx.doi.org/10.1080/00958970903082200

[14]. Gale, P. A.; Garcia-Garrido, S. E.; Garric, J. Chem. Soc. Rev. 2008, 37, 151-190.
http://dx.doi.org/10.1039/B715825D

[15]. Doyle, A. G.; Jacobsen, E. N. Chem. Rev. 2007, 107, 5713-5743.
http://dx.doi.org/10.1021/cr068373r

[16]. Svetlana, B. T. Eur. J. Org. Chem. 2007, 2007, 1701-1716.

[17]. Boiocchi, M.; Del Boca, L.; Gomez, D. E.; Fabbrizzi, L.; Licchelli, M.; Monzani, E. J. Am. Chem. Soc. 2004, 126, 16507-16514.
http://dx.doi.org/10.1021/ja045936c

[18]. Bonizzoni, M.; Fabbrizzi, L.; Taglietti, A.; Tiengo, F. Eur. J. Org. Chem. 2006, 2006, 3567-3574.

[19]. Chen, H. L.; Guo, Z. F.; Lu, Z. L. Org. Lett. 2012, 14, 5070-5073.
http://dx.doi.org/10.1021/ol302313x

[20]. Liu, W. X.; Yang, R.; Li, A. F.; Li, Z.; Gao, Y. F.; Luo, X. X.; Ruan, Y. B.; Jiang, Y. B. Org. Biomol. Chem. 2009, 7, 4021-4028.
http://dx.doi.org/10.1039/b910255h

[21]. Zhang, Y.; Qin, J.; Lin, Q.; Wei, T. J. Fluorine Chem. 2006, 127, 1222-1227.
http://dx.doi.org/10.1016/j.jfluchem.2006.06.018

[22]. Zhang, Y. M.; Cao, C.; Wei, W.; Xie, T. B. Chin. J. Chem. 2007, 25, 709-713.
http://dx.doi.org/10.1002/cjoc.200790133

[23]. Henderson, W.; Kemmitt, R. D. W.; Mason, S.; Moore, M. R.; Fawcett, J.; Russell, D. R. Dalton Trans. 1992, 1, 59-66.
http://dx.doi.org/10.1039/dt9920000059

[24]. Lipowska, M.; Hayes, B. L.; Hansen, L.; Taylor, A.; Marzilli, L. G. Inorg. Chem. 1996, 35, 4227-4231.
http://dx.doi.org/10.1021/ic9514657

[25]. Sacht, C.; Datt, M. S.; Otto, S.; Roodt, A. Dalton Trans. 2000, 4579-4586.
http://dx.doi.org/10.1039/b007589m

[26]. Hu, J. H.; Fan, X. H.; Du, X. L.; Wei, T. B. Phosphorus Sulfur 2010, 185, 2558-2562.
http://dx.doi.org/10.1080/10426501003752187

[27]. Merdivan, M.; Karipcin, F.; Kulcu, N.; Aygun, R. S. J. Therm. Anal. Calorim. 1999, 58, 551-557.
http://dx.doi.org/10.1023/A:1010140125400

[28]. Binzet, G.; Arslan, H.; Florke, U.; Kulcu, N.; Duran, N. J. Coord. Chem. 2006, 59, 1395-1406.
http://dx.doi.org/10.1080/00958970500512633

[29]. Mansuroglu, D. S.; Arslan, H.; Florke, U.; Kulcu, N. J. Coord. Chem. 2008, 61, 3134-3146.
http://dx.doi.org/10.1080/00958970802010567

[30]. Fitzl, G.; Beyer, L.; Sieler, R.; Richter, R.; Kaiser, J.; Hoyer, E. Z. Anorg. Allg. Chem. 1977, 433, 237-241.
http://dx.doi.org/10.1002/zaac.19774330127

[31]. Ozer, C. K.; Arslan, H.; Vanderveer, D.; Binzet, G. J. Coord. Chem. 2009, 62, 266-276.
http://dx.doi.org/10.1080/00958970802209623

[32]. Koch, K. R.; Sacht, C.; Grimmbacher, T.; Bourne, S. S. Afr. J. Chem. 1995, 48, 71-77.

[33]. Williams, J. A. G. Top. Curr. Chem. 2007, 281, 205- 268.
http://dx.doi.org/10.1007/128_2007_134

[34]. Lu, W.; Mi, B. X.; Chan, M. C. W.; Hui, Z.; Che, C. M.; Zhu, N.; Lee, S. T. J. Am. Chem. Soc. 2004, 126, 4958-4971.
http://dx.doi.org/10.1021/ja0317776

[35]. Evans, R. C.; Douglas, P.; Winscom, C. J. Coord. Chem. Rev. 2006, 250, 2093-2126.
http://dx.doi.org/10.1016/j.ccr.2006.02.007

[36]. Laskar, I. R.; Hsu, S. F.; Chen, T. M. Polyhedron 2005, 24, 881-888.
http://dx.doi.org/10.1016/j.poly.2005.02.009

[37]. McMillin, D. R.; Moore, J. J. Coord. Chem. Rev. 2002, 229, 113-121.
http://dx.doi.org/10.1016/S0010-8545(02)00041-3

[38]. Siu, P. K. M., Ma, D. L.; Che, C. M. Chem. Commun. 2005, 8, 1025-1027.

[39]. Kennedy, F.; Shavaleev, N. M.; Koullourou, T.; Bell, Z. R.; Jeffery, J. K.; Faulkner, S.; Ward, M. D. Dalton Trans. 2007, 15, 1492-1499.
http://dx.doi.org/10.1039/b616423d

[40]. Thomas, S. W.; Yagi, S.; Swager, T. M. J. Mater. Chem. 2005, 15, 2829-2835.
http://dx.doi.org/10.1039/b503539b

[41]. Yang, Q. Z.; Wu, L. Z.; Zhang, H.; Chen, B.; Wu, Z. W.; Zhang, L. P.; Tung, C. H. Inorg. Chem. 2004, 43, 5195-5197.
http://dx.doi.org/10.1021/ic049815p

[42]. Bruker, SADABS. Bruker AXS Inc., Madison, Wisconsin, USA, 2007.

[43]. Sheldrick, G. M. Acta Cryst. A 2008, 64, 112-122.
http://dx.doi.org/10.1107/S0108767307043930

[44]. Farrugia, L. J. ORTEP-3 for Windows-a version of ORTEP-III with a graphical user interface (GUI). J. Appl. Cryst. 1997, 30, 565-566.
http://dx.doi.org/10.1107/S0021889897003117

[45]. Selvakumaran, N.; Ng, S. W.; Tiekink, E. R. T.; Karvembu, R. Inor. Chim. Acta 2011, 376, 278-284.
http://dx.doi.org/10.1016/j.ica.2011.06.031

[46]. Reilly, B. O.; Plutin, A. M.; Perez, H.; Calderon, O.; Ramos, R.; Martinez, R.; Toscano, R. A.; Duque, J.; Rodriguez-Solla, H.; Martinez-Alvarez, R.; Suarez, M.; Martin, N. Polyhedron 2012, 36, 133-140.
http://dx.doi.org/10.1016/j.poly.2012.02.008

[47]. Binzet, G.; Florke, U.; N. Kulcu, H. Arslan. Acta Cryst. E 2009, 65, o427-o428.
http://dx.doi.org/10.1107/S1600536809003183

[48]. Morsali, A.; Masoomi, M. Y. Coord. Chem. Rev. 2009, 253, 1882-1905.
http://dx.doi.org/10.1016/j.ccr.2009.02.018

[49]. Arslan, H.; Kulcu, N. Trans. Metal Chem. 2003, 28, 816-819.
http://dx.doi.org/10.1023/A:1026064232260

[50]. Arslan, H.; Florke, U.; Kulcu, N.; Kayhan, E. Turk. J. Chem. 2006, 30, 429-440.

[51]. Dauglass, I. B.; Dains, F. B. J. Am. Chem. Soc. 1934, 56, 719-721.
http://dx.doi.org/10.1021/ja01318a057


How to cite


Gumus, I.; Solmaz, U.; Celik, O.; Binzet, G.; Balcı, G.; Arslan, H. Eur. J. Chem. 2015, 6(3), 237-241. doi:10.5155/eurjchem.6.3.237-241.1265
Gumus, I.; Solmaz, U.; Celik, O.; Binzet, G.; Balcı, G.; Arslan, H. Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II). Eur. J. Chem. 2015, 6(3), 237-241. doi:10.5155/eurjchem.6.3.237-241.1265
Gumus, I., Solmaz, U., Celik, O., Binzet, G., Balcı, G., & Arslan, H. (2015). Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II). European Journal of Chemistry, 6(3), 237-241. doi:10.5155/eurjchem.6.3.237-241.1265
Gumus, Ilkay, Ummuhan Solmaz, Omer Celik, Gun Binzet, Gulten Kavak Balcı, & Hakan Arslan. "Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)." European Journal of Chemistry [Online], 6.3 (2015): 237-241. Web. 24 Mar. 2019
Gumus, Ilkay, Solmaz, Ummuhan, Celik, Omer, Binzet, Gun, Balcı, Gulten, AND Arslan, Hakan. "Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)" European Journal of Chemistry [Online], Volume 6 Number 3 (30 September 2015)

DOI Link: https://doi.org/10.5155/eurjchem.6.3.237-241.1265

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