European Journal of Chemistry 2016, 7(1), 81-90 | doi: https://doi.org/10.5155/eurjchem.7.1.81-90.1356 | Get rights and content






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Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide


Ahmed Abd-Elhamied El-Asmy (1,*) , Bakir Jeragh (2) , Mayada Samir Ali (3)

(1) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(2) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(3) Department of Chemistry, Faculty of Science, Kuwait University, Safat, 13060, Kuwait
(*) Corresponding Author

Received: 03 Nov 2015 | Revised: 25 Nov 2015 | Accepted: 29 Nov 2015 | Published: 31 Mar 2016 | Issue Date: March 2016

Abstract


Single crystal of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)succinohydrazide (SHBH) was grown by slow evaporation method. Its, Co(II), Ni(II), Cu(II), Zn(II), Co(II)/Zn(II), Ni(II)/Zn(II) and Cu(II)/Zn(II) complexes have been prepared and characterized by elemental analysis, UV-Vis, IR, NMR, MS spectra, thermal and magnetic measurements. The data confirm the formation of tri- and tetra-metallic complexes (homo- and hetero-nuclear). The ligand behaves as a tetranegative hexadentate in the Co(II)/Zn(II) complex; hexanegative hexadentate in the Co(II) complex and hexanegative octadentate in the tetrametallic complexes. A square-planar for [Co3(SHBH-6H)(H2O)6], [Cu4(SHBH-H)(H2O)4(OAc)2]⋅3H2O, [Ni3Zn(SHBH-6H)(H2O)6Cl2]⋅H2O and [Cu3Zn(SHBH-6H)(H2O)6Cl2] and tetrahedral for [Ni4(SHBH-H)(H2O)4(OAc)2]⋅6H2O, [Zn3(SHBH-4H)-(H2O)4Cl2]⋅2H2O and [Co2Zn(SHBH-6H) (H2O)6Cl2]⋅2H2O were suggested based on the magnetic and spectral data. The TGA data confirm hydrated and coordinated water as well as the final product. The mass spectra depict their molecular ion peaks and the isotopic species of each complex. It is found that the homometallic complexes are highly stable than the heterometallic complexes. The calculated energies for [Co2Zn(SHBH-4H)(H2O)4Cl2].2H2O are higher than [Co3(SHBH-6H)-(H2O)6] indicating that the three Co stabilized the complex.


Keywords


Bis(hydrazones); Metal complexes; Thermal analysis; Magnetic moment; X-ray crystallography; Tetrametallic complexes

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DOI: 10.5155/eurjchem.7.1.81-90.1356

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Funding information


Kuwait University Research Grant No. SC05/14, Kuwait

Citations

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[1]. Ahmed Abdel-Hameed El-Asmy, Bakir Jeragh, Mayada Samir Ali
Chelation activity of N'1,N'6-bis((E)-3,4-dihydroxybenzylidene)adipohydrazide towards some transition metal ions
European Journal of Chemistry  7(3), 283, 2016
DOI: 10.5155/eurjchem.7.3.283-289.1461
/


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Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


El-Asmy, A.; Jeragh, B.; Ali, M. Eur. J. Chem. 2016, 7(1), 81-90. doi:10.5155/eurjchem.7.1.81-90.1356
El-Asmy, A.; Jeragh, B.; Ali, M. Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide. Eur. J. Chem. 2016, 7(1), 81-90. doi:10.5155/eurjchem.7.1.81-90.1356
El-Asmy, A., Jeragh, B., & Ali, M. (2016). Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide. European Journal of Chemistry, 7(1), 81-90. doi:10.5155/eurjchem.7.1.81-90.1356
El-Asmy, Ahmed, Bakir Jeragh, & Mayada Samir Ali. "Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide." European Journal of Chemistry [Online], 7.1 (2016): 81-90. Web. 5 Dec. 2020
El-Asmy, Ahmed, Jeragh, Bakir, AND Ali, Mayada. "Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide" European Journal of Chemistry [Online], Volume 7 Number 1 (31 March 2016)

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DOI Link: https://doi.org/10.5155/eurjchem.7.1.81-90.1356

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