European Journal of Chemistry 2018, 9(2), 121-125 | doi: https://doi.org/10.5155/eurjchem.9.2.121-125.1712 | Get rights and content






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X-ray structures of organic salts between diethanolamine and ortho- and para-isomers of aminobenzoic acid: A specific synthon responsible for an association of the components


Aziz Bakhtiyarovich Ibragimov (1,*) orcid , Bakhtiyar Sabirkhanovich Zakirov (2) orcid , Bakhtiyar Tulyaganovich Ibragimov (3) orcid , Jamshid Mengnorovich Ashurov (4) orcid

(1) Institute of General and Inorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
(2) Institute of General and Inorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
(3) Institute of Bioorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
(4) Institute of Bioorganic Chemistry of Academy of Sciences, Tashkent, 100125, Uzbekistan
(*) Corresponding Author

Received: 12 Apr 2018 | Revised: 03 May 2018 | Accepted: 05 May 2018 | Published: 30 Jun 2018 | Issue Date: June 2018

Abstract


Two organic salts between diethanolamine (DEA) and ortho- and para-isomers (OABA and PABA) of aminobenzoic acid (ABA) have been obtained and their X-ray single crystal structures determined. In both salts, cationic and anionic components are incorporated into dimers by the two H-bonds formed between ABA carboxylate oxygen atoms and nitrogen and one of oxygen atoms of DEA which close a cycle with the graph-set notation of R22(9). Further dimers are associated by intricate systems of the H-bonds into 1D- and 3D-network structures in crystals of DEA·OABA and DEA·PABA, respectively. H-bonding which generates these dimers may be considered as a synthon specific for yielding of salts between DEA and mono-substituted aromatic benzoic acids.


Keywords


Synthon; Organic salt; Diethanolamine; Aminobenzoic acid; X-ray crystallography; Molecular recognition

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DOI: 10.5155/eurjchem.9.2.121-125.1712

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[1]. Lilia Croitor, Mihaela F. Petric, Elisabeta I. Szerb, Gabriela Vlase, Paulina N. Bourosh, Yurii M. Chumakov, Manuela E. Crisan
The role of 4-nitrobenzoic acid polymorphs in the crystallization process of organic acid–base multicomponent systems
CrystEngComm  21(40), 6038, 2019
DOI: 10.1039/C9CE01239G
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How to cite


Ibragimov, A.; Zakirov, B.; Ibragimov, B.; Ashurov, J. Eur. J. Chem. 2018, 9(2), 121-125. doi:10.5155/eurjchem.9.2.121-125.1712
Ibragimov, A.; Zakirov, B.; Ibragimov, B.; Ashurov, J. X-ray structures of organic salts between diethanolamine and ortho- and para-isomers of aminobenzoic acid: A specific synthon responsible for an association of the components. Eur. J. Chem. 2018, 9(2), 121-125. doi:10.5155/eurjchem.9.2.121-125.1712
Ibragimov, A., Zakirov, B., Ibragimov, B., & Ashurov, J. (2018). X-ray structures of organic salts between diethanolamine and ortho- and para-isomers of aminobenzoic acid: A specific synthon responsible for an association of the components. European Journal of Chemistry, 9(2), 121-125. doi:10.5155/eurjchem.9.2.121-125.1712
Ibragimov, Aziz, Bakhtiyar Sabirkhanovich Zakirov, Bakhtiyar Tulyaganovich Ibragimov, & Jamshid Mengnorovich Ashurov. "X-ray structures of organic salts between diethanolamine and ortho- and para-isomers of aminobenzoic acid: A specific synthon responsible for an association of the components." European Journal of Chemistry [Online], 9.2 (2018): 121-125. Web. 26 Feb. 2020
Ibragimov, Aziz, Zakirov, Bakhtiyar, Ibragimov, Bakhtiyar, AND Ashurov, Jamshid. "X-ray structures of organic salts between diethanolamine and ortho- and para-isomers of aminobenzoic acid: A specific synthon responsible for an association of the components" European Journal of Chemistry [Online], Volume 9 Number 2 (30 June 2018)

DOI Link: https://doi.org/10.5155/eurjchem.9.2.121-125.1712

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