European Journal of Chemistry

Spectrophotometric study of complexation between a series of salophens and some transition metal ions in DMF solvent



Main Article Content

Ardeshir Shokrollahi
Mehrourang Ghaedi
Sara Alipour
Ali Hossein Kianfar

Abstract

The complexation behaviour of some salophen,s derivatives with few transition and heavy metal cations in N,N'-dimethyl formamid as nonaqueous solvent at 25 oC and 0.05 M tetra ethylammonium perchlorate to investigate the effect of structure were studied by spectrophotometric method. The formation of complexes between ligands and metal ions of the types ML, ML2 or M2L was observed. The overall stability constants of such complexes were evaluated by computer refinement of absorption-mole ratio data using the KINFIT program.

2_3_324_330_800


icon graph This Abstract was viewed 1587 times | icon graph Article PDF downloaded 666 times

How to Cite
(1)
Shokrollahi, A.; Ghaedi, M.; Alipour, S.; Kianfar, A. H. Spectrophotometric Study of Complexation Between a Series of Salophens and Some Transition Metal Ions in DMF Solvent. Eur. J. Chem. 2011, 2, 324-330.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Tuzen, M. K.; Saygi, O.; Karaman, I.; Soylak, M. Food Chem. Toxicol. 2010, 48, 41-46.
http://dx.doi.org/10.1016/j.fct.2009.09.012
PMid:19766692

[2]. Uluozlu, O. D.; Tuzen, M.; Mendil, D.; Soylak, M. Food Chem. Toxicol, 2010, 48, 1393-1398.
http://dx.doi.org/10.1016/j.fct.2010.03.007
PMid:20226225

[3]. Tuzen, M.; Citak, D.; Mendil, D.; Soylak, M. Talanta, 2009, 78, 52-56.
http://dx.doi.org/10.1016/j.talanta.2008.10.035
PMid:19174202

[4]. Nishinaga, A.; Yamada, T.; Fujisawa, H.; Ishizaki, K. J. Mol. Catal. 1988, 48, 249-264.
http://dx.doi.org/10.1016/0304-5102(88)85009-0

[5]. Chakraborty, H.; Paul, N.; Rahman, M. L. Trans. Met. Chem. 1994, 19, 524-526.
http://dx.doi.org/10.1007/BF00136366

[6]. Sreekala, R.; Yusuff, K.; Mohammed, K. Catal (Pap Natl Symp), 1994, 507-510; Chem. Abstr., 1999, 130, 115551.

[7]. Bhardwaj, C. N.; Singh, V. R. Indian J. Chem. 1994, 33A, 423-425.

[8]. Bharamagouclar, T. D.; Pujar, M. A.; Alagawadi, A. R. Curr. Sci. 1987, 56, 889-890.

[9]. Dash, B.; Mahapatra, P. K.; Panda, D.; Patnaik, J. M. J. Indian Chem. Soc. 1984, 61, 1061-1064.

[10]. Pandeya, S. N.; Sriram, D.; Nath, G.; De, C. E.; Farmaco. 1999, 54, 624-628.
http://dx.doi.org/10.1016/S0014-827X(99)00075-0

[11]. Mirzabdullaev, A. B.; Aslanova, D. K.; Ershov, F. I. Prep. Induktory Interferona (Imst Biol Org Khim, Tashkent USSR) 1981, 129-344; Chem Abstr, 1984, 99, 22191.

[12]. Huneck, S.; Schreiber, K.; Grimmecke, H. D. J. Plant Growth Regul. 1984, 3, 75-84.
http://dx.doi.org/10.1007/BF02041993

[13]. Hadjipavlu, L.; Dimitra, J.; Geronikaki, A. Drug Des. Discovery 1998, 15, 199-206.
PMid:9689502

[14]. Luo, X.; Zhao, J.; Ling, Y.; Liu, Z. Chem. Res. Chinese Univ. 2002, 18, 287-289.

[15]. Parashar, R. K.; Sharma, R. C.; Mohan, G. Biol. Trace Elem. Res. 1989, 23, 145-150.
http://dx.doi.org/10.1007/BF02917185
PMid:2484421

[16]. Singh, R.; Gupta, N.; Fahmi, N. Indian J. Chem. 1999, 38A, 1150-1158.

[17]. Befta, Unsymmetrical 1:2 chromium complex dyes, Fabio (to Ciba Geigy AG), Eur. Pat. Appl. 1985, 103, 161871.

[18]. Fakhari, A. R.; Khorrami, A. R.; Naeimi, H. Talanta 2005, 66, 813-817.
http://dx.doi.org/10.1016/j.talanta.2004.12.043
PMid:18970057

[19]. Gupta, V. K.; Goyal, R. N.; Sharma, R. A. Talanta 2009, 78, 484-490.
http://dx.doi.org/10.1016/j.talanta.2008.11.039
PMid:19203613

[20]. Gupta, V. K.; Goyal, R. N.; Jain, A. K.; Sharma, R. A. Electrochim. Acta 2009, 54, 3218-3224.
http://dx.doi.org/10.1016/j.electacta.2008.11.020

[21]. Gupta, V. K.; Singh, A. K.; Pal, M. K. Anal. Chim. Acta 2008, 624, 223-231.
http://dx.doi.org/10.1016/j.aca.2008.06.054
PMid:18706328

[22]. Fathi, S. A. M.; Parinejad, M.; Yaftian, M. R. Sep. Purif. Technol. 2008, 64, 1-7.
http://dx.doi.org/10.1016/j.seppur.2008.09.003

[23]. Yoshikawa, M.; Mori, Y.; Tanigaki, M.; Egcuhi, W. Bull. Chem. Soc. Jpn. 1990, 63, 304-306.
http://dx.doi.org/10.1246/bcsj.63.304

[24]. Gupta, V. K.; Pal, M. K.; Singh, A. K. Anal. Chim. Acta 2009, 631, 161-169
http://dx.doi.org/10.1016/j.aca.2008.10.033

[25]. Shokrolahi, A.; Ghaedi, M.; Shabani, R.; Montazerozohori, M.; Chehreh, F.; Soylak, M.; Alipour, S. Food Chem. Toxicol. 2010, 48, 482-489.
http://dx.doi.org/10.1016/j.fct.2009.10.040
PMid:19883718

[26]. Dehghan Abkenar,Sh.; Hosseini,M.; Salavati-Niasari, M. Asian J. Chem. 2008, 20, 4291-4300.

[27]. Dye, J. L.; Nicely, V. A. J. Chem. Edu. 1971, 48, 443-448.
http://dx.doi.org/10.1021/ed048p443

[28]. Safavi, A.; Rastegarzadeh, S. Anal. Sci. 1999, 15, 173-175.
http://dx.doi.org/10.2116/analsci.15.173

[29]. Martell, A. E.; Motekaitis, R. J. Determination and Use of Stability Constants, VCH,'Publishers, New York, 1992, pp. 143.

[30]. Moghimi, A.; Shokrollahi, A.; Shamsipur, M.; Aghabozorg, H.; Ranjbar, M. J. Mol. Struct 2004, 701, 49-56.
http://dx.doi.org/10.1016/j.molstruc.2004.03.007

[31]. Moghimi, A.; Alizadeh, R.; Shokrollahi, A.; Aghabozorg, H.; Shamsipur, M.; Shockravi, A. Inorg. Chem. 2003, 42, 1616-1624.
http://dx.doi.org/10.1021/ic025725d
PMid:12611530

[32]. Aghajani, Z.; Aghabozorg, H.; Sadr-Khanlou, E.; Shokrollahi, A.; Derki, S; Shamsipur, M. J. Iran. Chem. Soc. 2009, 6, 373-385

[33]. Shokrollahi, A.; Ghaedi, M.; Rajabi, H.R.; Niband, M.S. Spectrochim. Acta Part A 2008, 71, 655-662.
http://dx.doi.org/10.1016/j.saa.2008.01.021
PMid:18329953

[34]. Aghabozorg, H.; Manteghi, F.; Ghadermazi, M.; Mirzaei, M.; Salimi, A.R.; Shokrollahi, A.; Derki, S.; Eshtiagh-Hosseini, H. J. Mol. Struct. 2009, 919, 381-388.
http://dx.doi.org/10.1016/j.molstruc.2008.10.019

[35]. Shokrollahi, A.; Ghaedi, M.; Montazerozohori, M.; Kianfar, A. H.; Ghaedi, H.; Khanjari, N.; Noshadi, S.; Joybar, S., E-J. Chem. 2011, 8, 495-506.

[36]. Sarvestani, A.H.; Mohebbi, S. J. Chem. Res. 2006, 4, 257-260.

[37]. Kolthoff, I. M. J. Am. Chem. Soc. 1957, 79, 1-7.
http://dx.doi.org/10.1021/ja01558a001

[38]. Popov, A. I, J. M. Lehn, In coordination chemistry of macrocyclic compounds, Melson G.A. Ed.; Plenum press, New york, 1985.

[39]. Strasser, B. O.; Popov, A. I. J. Am. Chem. Soc. 1985, 107, 7921-7924.
http://dx.doi.org/10.1021/ja00312a020

[40]. Popov, A. I. Pure Appl. Chem. 1979, 51, 101-105.
http://dx.doi.org/10.1351/pac197951010101

[41]. Ben-Saber, S. M.; Maihub, A. A.; Hudere, S. S.; El-Ajaily, M. M. J. Microchem. J. 2005, 81, 191-194.
http://dx.doi.org/10.1016/j.microc.2005.03.001

[42]. Han, H.; Ruan, W. J.; Zhao, X. J.; Hu, G. H.; Zhu, Z. A. Synth. React. Inorg. Met.-Org. Chem. 2003, 33, 1011-1023.

[43]. Sakiyan, I.; Logoglu, E.; Arslan, S.; Sari, N.; Sakiyan, N. BioMetals 2004, 17, 115-120.
http://dx.doi.org/10.1023/B:BIOM.0000018380.34793.df

[44]. Khalil, M. E.; Bashir K. A, J. Coord. Chem. 2002, 55, 681-696.
http://dx.doi.org/10.1080/00958970290027552

[45]. Mederos, A.; Dominguez, S.; Hernandez-Molina, R.; Sanchiz J.; Brito, F. Coord. Chem. Rev. 1999, 193, 857-911.
http://dx.doi.org/10.1016/S0010-8545(99)00050-8

[46]. Irving, H; Williams, R. J. P. J. Chem. Soc. 1953, 3192-3210.
http://dx.doi.org/10.1039/jr9530003192

[47]. Asadi, M.; Aein Jamshid, Kh.; Kyanfar, A. H. Inorg. Chim. Acta 2006, 360, 1725-1730.
http://dx.doi.org/10.1016/j.ica.2006.09.013

[48]. Asadi, M.; Aein Jamshid, Kh.; Kyanfar, A. H. Transition Met. Chem. 2007, 32, 822-827.
http://dx.doi.org/10.1007/s11243-007-0272-9

[49]. Asadi, M.; Aein Jamshid, Kh.; Kyanfar, A. H.; Synth. React. Inorg. Met.-Org. Chem. 2007, 37, 77-83.

[50]. Sarvestani, A. H.; Salimi, A.; Mohebbi, S.; Hallaj R. J. Chem. Res. 2005, 3, 190-193.

[51]. Jager, E. G.; Schuhmann, K.; Gorls, H. Inorg. Chim. Acta 1997, 255, 295-305.
http://dx.doi.org/10.1016/S0020-1693(96)05377-7

[52]. Santos, M. A.; Gaspar, M.; Amorim, M. T. Inorg. Chim. Acta 1999, 284, 20-29.
http://dx.doi.org/10.1016/S0020-1693(98)00267-9

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).