European Journal of Chemistry

Kinetics and mechanism of oxidation of n-butylamine and 1,3-propanediamine by potassium ferrate



Main Article Content

Jinhuan Shan
Yafeng Yang
Jinhuan Shan

Abstract

The kinetics of oxidation of n-butylamine and 1,3-propanediamine by home-made potassium ferrate(VI) at different conditions has been studied spectrophotometrically in the temperature range of 283.2-298.2 K. The results show first order dependence on potassium ferrate (VI) and on each reductant. The observed rate constant (kobs) decreases with the increase of [OH-], and the reaction rate has a negative fraction order with respect to [OH-]. A plausible mechanism is proposed and the rate equations derived from the mechanism was shown to fit all the experimental results. The rate constants of the rate-determining step and the thermodynamic activation parameters are calculated.

2_3_342_346_800


icon graph This Abstract was viewed 1206 times | icon graph Article PDF downloaded 675 times

How to Cite
(1)
Shan, J.; Yang, Y.; Shan, J. Kinetics and Mechanism of Oxidation of N-Butylamine and 1,3-Propanediamine by Potassium Ferrate. Eur. J. Chem. 2011, 2, 342-346.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Jiang, J. Q.; Lloyd, B. Water Res. 2002, 36, 1397-1408.
http://dx.doi.org/10.1016/S0043-1354(01)00358-X

[2]. Jiang, J. Q.; Alex, P.; Mike B. J. Eniron. Managem. 2006, 79(2), 215-220.
http://dx.doi.org/10.1016/j.jenvman.2005.06.009
PMid:16182439

[3]. Li, C.; Li, X. Z.; Graham N. Water Res. 2008, 42(1-2), 109-120.
http://dx.doi.org/10.1016/j.watres.2007.07.023
PMid:17681362

[4]. Zhang, J.; Shi, Q. L.; Yang, G. M. Environ. Prot. Chem. Ind. 2000, 20, 44-47.

[5]. Sharma, V. K.; Burnett, C. R.; Yngard, R. A. Environ. Sci. Technol. 2005, 39(10), 3849-3854.
http://dx.doi.org/10.1021/es048196g

[6]. Sharma, V. K. Adv. Environ. Res. 2002, 6(2), 143-156.
http://dx.doi.org/10.1016/S1093-0191(01)00119-8

[7]. Sharma, V. K.; Smith, J. O.; Millero, F. J. Environ. Sci. Technol. 1997, 31, 2486-2491.
http://dx.doi.org/10.1021/es960755z

[8]. James, D. C. Environ. Sci. Technol. 1981, 15, 184â187.

[9]. James, D. C. Trans. Metal Chem. 1986, 11, 116-117.
http://dx.doi.org/10.1007/BF00623768

[10]. James, D. C.; Kelter, P. B. Anal. Chem. 1979, 51(11), 1828â1834.

[11]. Goff, H.; Murmann, R. K. J. Am. Chem. Soc. 1971, 93, 6058-6065.
http://dx.doi.org/10.1021/ja00752a016

[12]. Bielski, B. H. J.; Sharma, V. K. Inorg. Chem. 1991, 30, 4306-4310.
http://dx.doi.org/10.1021/ic00023a005

[13]. Bielski, B. H. J.; Rush, J. D. Free Radical Res. 1995, 22, 571-579.
http://dx.doi.org/10.3109/10715769509150329
PMid:7633578

[14]. Johnson, M. D.; Reed, J. F. Inorg. Chem. 1996, 35, 6795-6799.
http://dx.doi.org/10.1021/ic960480o
PMid:11666845

[15]. Meng, Y.; Xu, Z. S.; Chen, L. G.; Li, Y.; Dong, F. J. Chem. Ind. Eng. 1998, 15(4), 44-48.

[16]. Thompson, G. W.; Ockerman, L. T.; Schreyer, J. M. J. Am. Chem. Soc. 1951, 73, 1379-1381.
http://dx.doi.org/10.1021/ja01147a536

[17]. Dong, W. X. Detection of all kinds of Ions in the Chemical Method, Beijing Normal University Press, Beijing, 1984, pp. 94.

[18]. Han, B. X. Rapid detection method of inorganic ions, People's education press, Beijing, 1979, pp. 10.

[19]. Han, D. G.; Gao, P. L. Foundation of chemical kinetics, Beijing University Press, Beijing, 1987, pp. 212.

[20]. James, D. C.; Kelter, P. B.; Tabatabai, A.; Spichal, D.; Erickson, J.; McLaughlin, C. W. Environ. Impact Health Eff. 1985, 5, 1285â1298.

[21]. Jezowska-Trzebiatowska, B. Catal. Chem. Kinet. 1964, 212-217.

[22]. Shan, J. H.; Liu, T. Y. Acta Chem. Sinica. 1994, 52, 1140-1144.

TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).