European Journal of Chemistry 2012, 3(1), 57-64. doi:10.5155/eurjchem.3.1.57-64.448

Synthesis, structural elucidation and antimicrobial effectiveness of coordination entities of cobalt (II) and nickel (II) derived from 9,17-diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene


Rajiv Kumar (1,*) , Rajni Johar (2) , Anil Krishan Aggarwal (3)

(1) Department of Chemistry, Shivaji College University of Delhi, New Delhi, 110027, India
(2) Department of Chemistry, Guru Govind Singh Indraprashtha University, New Delhi, 110002, India
(3) Department of Chemistry, Shivaji College University of Delhi, New Delhi, 110027, India
(*) Corresponding Author

Received: 24 Apr 2011, Accepted: 17 Jun 2011, Published: 31 Mar 2012

Abstract


9,17-Diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene, macrocycle was synthesized, thereafter formulation and designing strategies applied for the preparation of coordination entities of Co(II) and Ni(II). Coordination behaviour of N2S4 donor macrocycle towards metal ion(s) was assessed by physiochemical measurements and spectral investigations viz. elemental analysis, molar conductance, magnetic susceptibility measurements, infrared, UV-Vis, 1H and 13 C NMR, mass spectroscopy, electron paramagnetic resonance (EPR), cyclic voltammetry and molecular modeling. Side-by-side comparison of the spectral findings exposed different geometrical aspects of macrocycle and coordination entities. Cyclic voltammogram showed fully oxidized and reduced species in one unified experiment. Macrocycle and coordination entities were screened for antimicrobial effectiveness (antifungal properties against Aspergillus-niger).

3_1_57_64_800


Keywords


EPR; Antimicrobial; Molecular modeling; Potential separation; Splitting parameters; Coordination entities

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DOI: 10.5155/eurjchem.3.1.57-64.448

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Citations

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[1]. Sai-Shuai Wen, Jing Wang, Yi-Ming Luo, Hua Yang
Synthesis of functionalized chromones via organocatalysis
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[2]. Alexandra Gaspar, Maria João Matos, Jorge Garrido, Eugenio Uriarte, Fernanda Borges
Chromone: A Valid Scaffold in Medicinal Chemistry
Chemical Reviews  114(9), 4960, 2014
DOI: 10.1021/cr400265z
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How to cite


Kumar, R.; Johar, R.; Aggarwal, A. Eur. J. Chem. 2012, 3(1), 57-64. doi:10.5155/eurjchem.3.1.57-64.448
Kumar, R.; Johar, R.; Aggarwal, A. Synthesis, structural elucidation and antimicrobial effectiveness of coordination entities of cobalt (II) and nickel (II) derived from 9,17-diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene. Eur. J. Chem. 2012, 3(1), 57-64. doi:10.5155/eurjchem.3.1.57-64.448
Kumar, R., Johar, R., & Aggarwal, A. (2012). Synthesis, structural elucidation and antimicrobial effectiveness of coordination entities of cobalt (II) and nickel (II) derived from 9,17-diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene. European Journal of Chemistry, 3(1), 57-64. doi:10.5155/eurjchem.3.1.57-64.448
Kumar, Rajiv, Rajni Johar, & Anil Krishan Aggarwal. "Synthesis, structural elucidation and antimicrobial effectiveness of coordination entities of cobalt (II) and nickel (II) derived from 9,17-diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene." European Journal of Chemistry [Online], 3.1 (2012): 57-64. Web. 24 Jan. 2019
Kumar, Rajiv, Johar, Rajni, AND Aggarwal, Anil. "Synthesis, structural elucidation and antimicrobial effectiveness of coordination entities of cobalt (II) and nickel (II) derived from 9,17-diaza-2,6,11,15-tetrathia-1,7,10,16-(1,2)-tetrabenzenacyclooctadecaphan-8,17-diene" European Journal of Chemistry [Online], Volume 3 Number 1 (31 March 2012)

DOI Link: https://doi.org/10.5155/eurjchem.3.1.57-64.448

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