European Journal of Chemistry 2010, 1(1), 15-19. doi:https://doi.org/10.5155/eurjchem.1.1.15-19.6

Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition


Davood Azarifar (1,*) , Kaveh Khosravi (2)

(1) Department of Chemistry, Bu-Ali Sina University, Hamedan, IR-65178, Iran
(2) Department of Chemistry, Bu-Ali Sina University, Hamedan, IR-65178, Iran
(*) Corresponding Author

Received: 24 Mar 2010, Accepted: 24 Mar 2010, Published: 31 Mar 2010

Abstract


Application of trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as an efficient and high-oxygen content reagent in selective oxidation of sulfides into sulfoxides has been successfully explored. The reactions proceeded under mild and catalyst-free conditions in dichloromethane at room temperature to provide the sulfoxides in excellent yields without any significant over-oxidation to sulfones.

1_1_15_19_800


Keywords


Sulfides; Sulfoxides; Sulfoxidation; Catalyst-Free Condition

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DOI: 10.5155/eurjchem.1.1.15-19.6

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Citations

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Energetic Materials Trends in 5- and 6-Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents
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[2]. Kaveh Khosravi, Samira Kazemi
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[3]. Erika Méndez-Albores, Miguel A. González-Fuentes, Martín M. Dávila-Jiménez, Felipe J. González
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[4]. Kaveh Khosravi
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How to cite


Azarifar, D.; Khosravi, K. Eur. J. Chem. 2010, 1(1), 15-19. doi:https://doi.org/10.5155/eurjchem.1.1.15-19.6
Azarifar, D.; Khosravi, K. Eur. J. Chem. Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition. 2010, 1(1), 15-19. doi:https://doi.org/10.5155/eurjchem.1.1.15-19.6
Azarifar, D., & Khosravi, K. (2010). Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition. European Journal of Chemistry, 1(1), 15-19. doi:https://doi.org/10.5155/eurjchem.1.1.15-19.6
Azarifar, Davood, & Kaveh Khosravi. "Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition." European Journal of Chemistry [Online], 1.1 (2010): 15-19. Web. 21 Apr. 2018
Azarifar, Davood, AND Khosravi, Kaveh. "Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as a novel and efficient reagent for selective sulfoxidation of sulfides under catalyst-free condition" European Journal of Chemistry [Online], Volume 1 Number 1 (31 March 2010)

DOI: https://doi.org/10.5155/eurjchem.1.1.15-19.6

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