European Journal of Chemistry

Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6



Main Article Content

Ikram Dhouib
Philippe Guionneau
Stanislav Pechev
Tahar Mhiri
Zakaria Elaoud

Abstract

Single crystals of the bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X-ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P-1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm-1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C-H…Cl and Van der Waals interaction in order to build cation-anion-cation cohesion. These interactions cause to the formation of a three-dimensional supramolecular architecture.

4_2_117_120

icon graph This Abstract was viewed 1674 times | icon graph Article PDF downloaded 1972 times icon graph Article CIF FILE downloaded 0 times

How to Cite
(1)
Dhouib, I.; Guionneau, P.; Pechev, S.; Mhiri, T.; Elaoud, Z. Crystal Structure and Spectroscopic Study of Bis-Tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6. Eur. J. Chem. 2013, 4, 117-120.

Article Details

Share
Crossref - Scopus - Google - European PMC
References

[1]. Braga, D.; Desiraju, G. R.; Miller, J. S.; Orpen, A. G.; Price, S. L. Cryst. Eng. Commun. 2002, 4, 500-509.
http://dx.doi.org/10.1039/b207466b

[2]. Desiraju, G. R. Angew. Chem. Int. Ed. Engl. 1995, 34, 2311-2327.
http://dx.doi.org/10.1002/anie.199523111

[3]. Desiraju, G. R. J. Mol. Struct. 2003, 656, 5-15.
http://dx.doi.org/10.1016/S0022-2860(03)00354-5

[4]. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1-12.
http://dx.doi.org/10.1002/9780470166499.ch1

[5]. Lacroix, P. G.; Clement, R.; Nakatani, K.; Delaire, J. A.; Zyss, J.; Ledoux, I. Science 1994, 263, 658-660.
http://dx.doi.org/10.1126/science.263.5147.658
PMid:17747659

[6]. De Zea Bermudez, V.; Carlos, L. D.; Duarte, M. C.; Silva, M. M.; Silva, C. J.; Smith, M. J.; Assunc¸ M.; Alcacer, L. J. Alloys Compd. 1998, 21, 275-277.

[7]. Carlos, L. D.; Sa Ferreira, R. A.; De Zea Bermudez, V.; Ribeiro, S. J. L. Adv. Funct. Mater. 2001, 11, 2111-115.
http://dx.doi.org/10.1002/1616-3028(200104)11:2<111::AID-ADFM111>3.0.CO;2-V

[8]. Kato, Y.; Ichii, D.; Ohashi, K.; Kunugita, H.; Ema, K.; Tanaka, K.; Takahashi, T.; Kondo, T. Solid State Commun. 2003, 128, 15-18.
http://dx.doi.org/10.1016/S0038-1098(03)00626-4

[9]. El-Korashy, A.; Brik, M. G. Solid State Commun. 2005, 135, 298-303.
http://dx.doi.org/10.1016/j.ssc.2005.05.010

[10]. Ben Rhaiem, A.; Hlel, F.; Guidara, K.; Gargouri, M. J. Alloys Compd. 2008, 463, 440-445.
http://dx.doi.org/10.1016/j.jallcom.2007.09.032

[11]. Cavellec, M. R.; Albinet, C.; Greneche, J. M.; Ferey, G. J. Mater. Chem. 2001, 11, 3166-3171.
http://dx.doi.org/10.1039/b104495h

[12]. Lach, G.; Laskowski, L.; Kityk, I. V.; Kapustianyk, V.; Rudyk, V.; Shchur, Y.; Tkaczyk, S.; Swiatek, J.; Piasecki, M. J. Non-Crystalline Solid. 2007, 353, 4353-4356.
http://dx.doi.org/10.1016/j.jnoncrysol.2007.01.081

[13]. Roman, P.; Sertucha, J.; Luque, A.; Lezama, L.; Rojo, T. Polyhedron 1996, 15, 1253-1262.
http://dx.doi.org/10.1016/0277-5387(95)00386-X

[14]. Angeloni, A.; Orpen, A. G. Chem. Commun. 2001, 26, 343-344
http://dx.doi.org/10.1039/b009515j

[15]. Guckian, K. M .; Schweitzer, B. A.; Ren, R. X. F.; Sheils, C. J.; Tahmassebi, D. C.; Kool, E. T. J. Am. Chem. Soc. 2000, 122, 2213-2222.
http://dx.doi.org/10.1021/ja9934854
PMid:20865137 PMCid:2943206

[16]. Janiak, C. J. Chem. Soc. Dalton Trans. 2000, 7, 3885-3896
http://dx.doi.org/10.1039/b003010o

[17]. Muller-Dethlefs, K.; Hobza, P. Chem. Rev. 2000, 100, 143-167.
http://dx.doi.org/10.1021/cr9900331
PMid:11749236

[18]. Hiroyuki, H.; Mashiyama, H.; Koshiji, N. Acta Cryst. B. 1989, 45, 467-473.
http://dx.doi.org/10.1107/S0108768189006981

[19]. Muller, E. A.; Cannon, R. J.; Sarjeant, A. N.; Ok, K. M.; Halasyamani, P. S.; Norquist, A. J. Cryst. Growth Des. 2005, 5, 1913-1917.
http://dx.doi.org/10.1021/cg050184z

[20]. Nonius, Kappa CCD Program Software, Nonius BV, Delft, The Netherlands, 1998.

[21]. Farrugia, L. J. J. Appl. Cystallogr. 1999, 32, 837-838.
http://dx.doi.org/10.1107/S0021889899006020

[22]. Sheldrick, G. M. SHELXS-97 Programs for Crystal Solution. University of Gottingen, Germany, 1997.
PMCid:20809

[23]. Sheldrick, G. M. SHELXL-97 Programs for Crystal Structure Refinement. University of Gottingen, Germany, 1997.
PMCid:20809

[24]. Herringer, S. N.; Turnbull, M. M.; Landee, C. P.; Wikaira, J. L. J. Coord. Chem. 2009, 62, 863-875.
http://dx.doi.org/10.1080/00958970802395604

[25]. Luque, A.; Sertucha, J.; Castillo, O.; Roman, P. New. J. Chem. 2001, 25, 1208-1214.
http://dx.doi.org/10.1039/b104085p

[26]. Luque, A.; Sertucha, J.; Lezama, L.; Rojo, T.; Roman, P. J. Chem. Soc. Dalton Trans. 1997, 5, 847-854.
http://dx.doi.org/10.1039/a606429i

[27]. Al-Far, A. R. H.; Haddad, S. F. Acta Cryst. E 2008, 64, 689-690.
http://dx.doi.org/10.1107/S1600536808010647
PMid:21202225 PMCid:2961314

[28]. Haddad, S. F.; AlDamen, M. A.; Willett, R. D. Inorg. Chim. Acta. 2006, 359, 424-432.
http://dx.doi.org/10.1016/j.ica.2005.05.039

[29]. Hafiz, A. A. Iran J. Chem. Soc. 2008, 5, 106-114.

[30]. Gosniowska, M.; Ciunik, Z.; Bator, G.; Jakubas, R.; Baran, J. J. Mol. Struct. 2000, 555, 243-255.
http://dx.doi.org/10.1016/S0022-2860(00)00607-4

[31]. Karbowiak, M.; Hanuza, J.; Janczak, J.; Drozdzynski, J. J. Alloys Compd. 1995, 225, 338-343.
http://dx.doi.org/10.1016/0925-8388(94)07117-9

[32]. Hedderich, H. G.; Blom, C. E. J. Chem. Phys. 1989, 90, 4660-4663.

[33]. Hedderich, H. G.; Blom, C. E. J. Mol. Spectrosc. 1990, 140, 103-106.
http://dx.doi.org/10.1016/0022-2852(90)90009-F

[34]. Kirkwood, A. D.; Bier, K. D.; Thompson, J. K.; Haslett, T. L.; Hubber, A. S.; Moskovits, M. J. Phys. Chem. 1991, 95, 2644-2652.
http://dx.doi.org/10.1021/j100160a006

[35]. Bellamy, L. J. The Infrared Spectra of Complex Molecules, 3rd ed., Vol. I and II, Chapman and Hall, London, 1975, 1980.

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).