European Journal of Chemistry 2013, 4(3), 255-259 | doi: https://doi.org/10.5155/eurjchem.4.3.255-259.833 | Get rights and content






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New lanthanide complexes of 1,1`-bis[(2-thienylmethylidene)hydrazono-1-ethyl]-ferrocene and 1,1`-bis(2,3-dihydro-2-methylbenzo[d]thiazol-2-yl)ferrocene: Synthesis, characterization and antimicrobial properties


Wael Hussein Hegazy (1,*)

(1) Department of Chemistry, Faculty of Science, Suez University, Suez, 43533, Egypt
(*) Corresponding Author

Received: 18 May 2013 | Revised: 11 Jun 2013 | Accepted: 14 Jun 2013 | Published: 30 Sep 2013 | Issue Date: September 2013

Abstract


In this paper; synthesis, characterization and biocidal properties of new prepared Sc(III), Y(III), La(III) and Ce(III) complexes with the two ferrocenyl ligands of 1,1`-bis[(2-thienylmethylidene)hydrazono-1-ethyl]ferrocene and 1,1`-bis(2,3-dihydro-2-methylbenzo[d] thiazol-2-yl)ferrocene are reported. These organometallic compounds are potential ligands for lanthanide metal ions. The composition of these complexes is discussed on the basis of elemental analysis, IR, NMR, magnetic moments, electronic absorption spectra and conductivity measurements. In vitro antimicrobial activity of the prepared complexes was screened. All complexes showed remarkable antibiotic activity. Scandium complexes are very effective towards Salmonella spp. Sc-L2 complex found to have inhibition activity against B. subtilis more than the standard drugs.

4_3_255_259

Keywords


Antibiotics; Complexes; Lanthanoids; Ferrocenyl ligands; Bioinorganic chemistry; Organometallic compounds

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DOI: 10.5155/eurjchem.4.3.255-259.833

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Funding information


Microbial Genetics Department, National Research Center, Giza, Egypt

Citations

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[1]. Wael Hussein Hegazy
Spectroscopic and electrochemical investigations and antibacterial activity of binuclear Pd(II) and Pt(IV) complexes of newly synthesized tridentate heterocyclic compounds
European Journal of Chemistry  5(3), 415, 2014
DOI: 10.5155/eurjchem.5.3.415-418.1045
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References

[1]. Henderson, W.; Alley, S. R. Inorg. Chim. Acta 2001, 322, 106-112.
http://dx.doi.org/10.1016/S0020-1693(01)00584-9

[2]. Hantson, J. T.; Falzacappa, M. V.; Crovella, S.; Metzler-Nolte, N. J. Organomet. Chem. 2005, 690, 4564-4572.
http://dx.doi.org/10.1016/j.jorganchem.2005.07.007

[3]. Daher, W.; Biot, C.; Fandeur, T.; Jouin, H.; Pelinski, L.; Viscogliosi, E.; Fraisse, L.; Pradines, B.; Brocard, J.; Khalife, J.; Dive, D. Malar. J. 2006, 5, 11-17.
http://dx.doi.org/10.1186/1475-2875-5-11
PMid:16464254 PMCid:PMC1395321

[4]. Chohan, Z. H. Appl. Organomet. Chem. 2006, 20, 112-116.
http://dx.doi.org/10.1002/aoc.1018

[5]. Fouda, M. F.; Abd-Elzaher, M. M.; Abdelsamaia, R. A.; Labib, A. A. Appl. Organomet. Chem. 2007, 21, 613-625.
http://dx.doi.org/10.1002/aoc.1202

[6]. Biot, C.; Pradines, B.; Sergeant, M-H.; Gut, J.; Rosenthal, P. J.; Chibale, K. Bioorg. Med. Chem. Lett. 2007, 17, 6434-6438.
http://dx.doi.org/10.1016/j.bmcl.2007.10.003
PMid:17949976

[7]. Michard, Q.; Jaouen, G.; Vessieres, A.; Bernard, B. A. J. Inorg. Biochem. 2008, 102, 1980-1985.
http://dx.doi.org/10.1016/j.jinorgbio.2008.07.014
PMid:18783831

[8]. Suresh, Babu, A. R.; Raghunathan, R. Tetrahedron Lett. 2008, 49, 4487-4490.

[9]. Gasser, G.; Carr, J. D.; Coles, S. J.; Green, S. J.; Hursthouse, M. B.; Cafferkey, S. M.; Stoeckli-Evans, H.; Tucker, J. J. Organomet. Chem. 2010, 695, 249-255.
http://dx.doi.org/10.1016/j.jorganchem.2009.10.004

[10]. Gasser, G.; Mari, C.; Burkart, M.; Green, S. J.; Ribas, J.; Stoeckli-Evans, H.; Tucker, J. New J. Chem. 2012, 36, 1819-1827.
http://dx.doi.org/10.1039/c2nj40177k

[11]. Yuan, Y. F.; Cardinaels, T.; Lunstroot, K.; Van Hecke, K., Van Meervelt, L.; Gorller-Walrand, C.; Binnemans, K.; Nockemann, P. Inorg. Chem. 2007, 46, 5302-5309.
http://dx.doi.org/10.1021/ic070303v
PMid:17542576

[12]. Abd-Elzaher, M. M.; Moustafa, S. A.; Labib, A. A.; Ali, M. M. Monatsh. Chem. 2010, 141, 387-383.
http://dx.doi.org/10.1007/s00706-010-0268-6

[13]. Abd-Elzaher, M. M.; Moustafa, S. A.; Labib, A. A.; Mousa, H. A.; Ali, M. M.; Mahmoud, A. E. Appl. Organomet. Chem. 2012, 26, 230-236.
http://dx.doi.org/10.1002/aoc.2844

[14]. Abd-Elzaher, M. M. Appl. Organomet. Chem. 2004, 18, 149-155.
http://dx.doi.org/10.1002/aoc.608

[15]. Abd-Elzaher, M. M.; Hegazy, W. H.; Gaafar, A. Appl. Organomet. Chem. 2005, 19, 911-916.
http://dx.doi.org/10.1002/aoc.927

[16]. Abd-Elzaher, M. M.; Ali, I. A. Appl. Organomet. Chem. 2006, 20, 107-111.
http://dx.doi.org/10.1002/aoc.1016

[17]. Hegazy, W. H.; Al-Motawaa, I. H. Bioinorg. Chem. Appl. 2011, 531946, 1-10.
http://dx.doi.org/10.1155/2011/531946
PMid:21799665 PMCid:PMC3135049

[18]. Rosenblum, M.; Woodward, R. B. Am. Chem. Soc. 1958, 80, 5443-5449.
http://dx.doi.org/10.1021/ja01553a032

[19]. Abd-Elzaher, M. M; Moustafa, S. A.; Mousa, H. A.; Labib, A. A. Monatsh. Chem. 2012, 143, 909-915.
http://dx.doi.org/10.1007/s00706-011-0685-1

[20]. Addison, C. C.; Logan, N. Adv. Inorg. Chem. Radiochem. 1964, 6, 95-114.

[21]. Chohan, Z. H.; Praveen, M. Appl. Organometal. Chem. 2001, 15, 617-625.
http://dx.doi.org/10.1002/aoc.179

[22]. Sharba, A.; Al-Bayati, R.; Aouad, M.; Rezki, N. Molecules 2005, 10, 1161-1168.
http://dx.doi.org/10.3390/10091161
PMid:18007382

[23]. Abd-Elzaher, M. M. J. Chinese Chem. Soc. 2004, 51, 499-504.

[24]. Lever, A. B. P.; Mantiovani, E.; Ramaswamy, B. S. Can. J. Chem. 1971, 49, 1957-1964.
http://dx.doi.org/10.1139/v71-315

[25]. Szczurek, T.; Schlesingerm M. in: Jezowska-Trzebiatowska, B.; Legendziewicz, J.; Strek, W. (Eds.), Rare Earth Spectroscopy, World Scientific, Singapore, 1985.

[26]. Aull, B. F.; Jenssen, H. P. Phys. Rev. B 1986, 34, 6640-6646.
http://dx.doi.org/10.1103/PhysRevB.34.6640

How to cite


Hegazy, W. Eur. J. Chem. 2013, 4(3), 255-259. doi:10.5155/eurjchem.4.3.255-259.833
Hegazy, W. New lanthanide complexes of 1,1`-bis[(2-thienylmethylidene)hydrazono-1-ethyl]-ferrocene and 1,1`-bis(2,3-dihydro-2-methylbenzo[d]thiazol-2-yl)ferrocene: Synthesis, characterization and antimicrobial properties. Eur. J. Chem. 2013, 4(3), 255-259. doi:10.5155/eurjchem.4.3.255-259.833
Hegazy, W. (2013). New lanthanide complexes of 1,1`-bis[(2-thienylmethylidene)hydrazono-1-ethyl]-ferrocene and 1,1`-bis(2,3-dihydro-2-methylbenzo[d]thiazol-2-yl)ferrocene: Synthesis, characterization and antimicrobial properties. European Journal of Chemistry, 4(3), 255-259. doi:10.5155/eurjchem.4.3.255-259.833
Hegazy, Wael. "New lanthanide complexes of 1,1`-bis[(2-thienylmethylidene)hydrazono-1-ethyl]-ferrocene and 1,1`-bis(2,3-dihydro-2-methylbenzo[d]thiazol-2-yl)ferrocene: Synthesis, characterization and antimicrobial properties." European Journal of Chemistry [Online], 4.3 (2013): 255-259. Web. 25 Nov. 2020
Hegazy, Wael. "New lanthanide complexes of 1,1`-bis[(2-thienylmethylidene)hydrazono-1-ethyl]-ferrocene and 1,1`-bis(2,3-dihydro-2-methylbenzo[d]thiazol-2-yl)ferrocene: Synthesis, characterization and antimicrobial properties" European Journal of Chemistry [Online], Volume 4 Number 3 (30 September 2013)

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DOI Link: https://doi.org/10.5155/eurjchem.4.3.255-259.833

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