European Journal of Chemistry 2013, 4(4), 366-369. doi:10.5155/eurjchem.4.4.366-369.862

Uptake of acid black 210 dye by organo-montmorillonite clay minerals


Cristina Volzone (1,*) , Norma Gallegos (2) , Carlos Cantera (3) , Alberto Greco (4)

(1) Centro de Tecnología de Recursos Minerales y Cerámica (CETMIC), Centro Científico Tecnológico-Consejo Nacional de Investigaciones Científicas y Tecnológicas- La Plata, Comisión de Investigaciones Científicas de la Provincia de Buenos Aires, M. B. Gonnet, 1897, Argentina
(2) Centro de Investigación y Desarrollo en Ciencias Aplicadas (CINDECA), Centro Científico Tecnológico-Consejo Nacional de Investigaciones Científicas y Tecnológicas- La Plata, Facultad de Ingeniería, Universidad Nacional de La Plata, La Plata, 1900, Argentina
(3) Centro de Investigación y Desarrollo del Cuero (CITEC)-Instituto Nacional de Tecnología Industrial, Comisión de Investigaciones Científicas de la Provincia de Buenos Aires, M. B. Gonnet, 1897, Argentina
(4) Centro de Investigación y Desarrollo del Cuero (CITEC)-Instituto Nacional de Tecnología Industrial, Comisión de Investigaciones Científicas de la Provincia de Buenos Aires, M. B. Gonnet, 1897, Argentina
(*) Corresponding Author

Received: 27 Jun 2013, Accepted: 22 Jul 2013, Published: 31 Dec 2013

Abstract


Two clays rich in montmorillonite were modified and used as adsorbents. The clay minerals were modified with hexadecylpyridinium cation (HDP+) in order to obtain organo-montmorillonites, which were used for retaining acid black 210 dye from water solution. This dye is frequently used in tanning industry. The retentions of the anionic dye by organo-montmorillonites were evaluated by using complete UV-visible spectrum, analyzing the concentrations of dye solutions before (50 mg/L) and after the contact with the adsorbent. The solids were characterized by X-ray diffraction (XRD) and infrared analyses (FT-IR). The interlayer spacing of the montmorillonites increased, after organic cation exchange, from 13.0-14.9 Å to 19.0-22.0 Å and allowed the uptake of acid black 210 dye. The most disordered arrangement of HDP in montmorillonite, deduced by XRD and FT-IR analyses, was better for higher retentions of acid black dye.

4_4_366_369

Keywords


Clays; Dyes; Adsorption; IR spectroscopy; X-ray diffraction; UV/Vis spectroscopy

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DOI: 10.5155/eurjchem.4.4.366-369.862

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[1]. Tahani Achouak Chinar, Mohammed Benbouzid
Preparation and characterization of an efficient zeolitic material from a local natural kaolinitic clay and its uses in the elimination of an organic dye
European Journal of Chemistry  7(4), 410, 2016
DOI: 10.5155/eurjchem.7.4.410-415.1486
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How to cite


Volzone, C.; Gallegos, N.; Cantera, C.; Greco, A. Eur. J. Chem. 2013, 4(4), 366-369. doi:10.5155/eurjchem.4.4.366-369.862
Volzone, C.; Gallegos, N.; Cantera, C.; Greco, A. Uptake of acid black 210 dye by organo-montmorillonite clay minerals. Eur. J. Chem. 2013, 4(4), 366-369. doi:10.5155/eurjchem.4.4.366-369.862
Volzone, C., Gallegos, N., Cantera, C., & Greco, A. (2013). Uptake of acid black 210 dye by organo-montmorillonite clay minerals. European Journal of Chemistry, 4(4), 366-369. doi:10.5155/eurjchem.4.4.366-369.862
Volzone, Cristina, Norma Gallegos, Carlos Cantera, & Alberto Greco. "Uptake of acid black 210 dye by organo-montmorillonite clay minerals." European Journal of Chemistry [Online], 4.4 (2013): 366-369. Web. 21 Oct. 2019
Volzone, Cristina, Gallegos, Norma, Cantera, Carlos, AND Greco, Alberto. "Uptake of acid black 210 dye by organo-montmorillonite clay minerals" European Journal of Chemistry [Online], Volume 4 Number 4 (31 December 2013)

DOI Link: https://doi.org/10.5155/eurjchem.4.4.366-369.862

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