European Journal of Chemistry 2016, 7(4), 436-441 | doi: https://doi.org/10.5155/eurjchem.7.4.436-441.1445 | Get rights and content

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Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases


Hayat Hamza Abbas (1,*)

(1) Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq
(*) Corresponding Author

Received: 08 May 2016 | Accepted: 15 Oct 2016 | Published: 31 Dec 2016 | Issue Date: December 2016

Abstract


Complexes of Cu(II), Co(II) and Mn(II) with two Schiff base ligands {[(2-carboxyphenyl)imino]methyl} phenol (HLA) and {[(2-hydroxyphenyl)imino]methyl} phenol (HLB) were synthesized and characterized by FT-IR, UV-Visible, 1H NMR spectroscopy and elemental analysis. All the synthesized complexes have been evaluated for their thermal degradation studies using TG-DTA analytical methods in static air. Thermodynamic and kinetic parameters were evaluated from the TG-DTA curves using Arrhenius equation.


Keywords


Salicylaldehyde; Phenol Schiff base; Schiff base ligands; Thermogravimetry; Transition metal complexes; Thermodynamic parameters

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DOI: 10.5155/eurjchem.7.4.436-441.1445

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Funding information


Department of Chemistry, College of Science, University of Basra, Basra, 61004, Iraq.

Citations

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[1]. Gajanan Dongare, Anand Aswar
Synthesis, spectral characterization, thermo-kinetic and biological studies of some complexes derived from tridentate hydrazone Schiff base
Journal of Saudi Chemical Society  25(10), 101325, 2021
DOI: 10.1016/j.jscs.2021.101325
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References


[1]. Yamada, S. Coord. Chem. Rev. 1999, 190, 537-555.
http://dx.doi.org/10.1016/S0010-8545(99)00099-5

[2]. Demetgul, C.; Karakaplan, M.; Serin, S.; Digrak, M. J. Coord. Chem. 2009, 62, 3544-3551.
http://dx.doi.org/10.1080/00958970903082192

[3]. Singh, M. K.; Kar, N. K.; Lal, R. A. Asthana. J. Coord. Chem. 2009, 62, 2893-2902.
http://dx.doi.org/10.1080/00958970902939822

[4]. Raman, N.; Johnson, R. S.; Sakthirel, A. J. Coord. Chem. 2009, 62, 691-709.
http://dx.doi.org/10.1080/00958970802326179

[5]. Garanovskii, A. D.; Vasilchenko, I. S.; Garsnovskii, D. A.; Kharisov, B. I. J. Coord. Chem. 2009, 62, 151-204.
http://dx.doi.org/10.1080/00958970802398178

[6]. Patra, A.; Sarkar, S.; Chakraborty, M. G. B.; Chattopadhyay, P. J. Coord. Chem. 2010, 63, 1913-1920.
http://dx.doi.org/10.1080/00958972.2010.495985

[7]. Maurla, R. C.; Patel, P.; Rajput, S. Synth. React. Inorg. Met.-Org. Chem. 2003, 33, 817-836.

[8]. Alarcon, S. H.; Olivieri, A. C.; Nordon, A.; Harris, R. K. J. Chem. Soc. Perkin Trans 1996, 2, 2293-2296.
http://dx.doi.org/10.1039/P29960002293

[9]. Mohamed, G. G.; Omar, M. M.; Hindy, A. M. Turk. J. Chem. 2009, 30, 361-382.

[10]. Tatar, L.; Ulku, D.; Atakol, O. Acta. Cryst. 1999, 55, 508-510.
http://dx.doi.org/10.1107/S0108767398013841

[11]. Vanwyk, J. L.; Mapolie, S. F.; Iennartson, A.; Hakansson, M.; Jagner S. Inorg. Chem. Acta. 2008, 361(7), 2094-2100.
http://dx.doi.org/10.1016/j.ica.2007.10.031

[12]. Vafazadeh, R.; Hayeri, V.; Willis, A. C. Polyhedron 2010, 29, 1810-1814.
http://dx.doi.org/10.1016/j.poly.2010.02.030

[13]. Rehman, W.; Saman, F.; Ahmed, I. Russ. J. Inorg. Chem. 2008, 34(9), 678-682.

[14]. Ramesh, R. Inorg. Chem. Commun. 2004, 7, 274-276.
http://dx.doi.org/10.1016/j.inoche.2003.11.020

[15]. Lean, K.; Pat U. S. Chem. Abstract 1956, 50, 6519.

[16]. Chaakraborty, B.; Banerjee, S. J. Coord. Chem. 2013, 20(66), 3619-3628.
http://dx.doi.org/10.1080/00958972.2013.848979

[17]. Ebara, N. Bull. Chem. Soc. Jpn. 1961, 34, 1151-1158.
http://dx.doi.org/10.1246/bcsj.34.1151

[18]. Wang, M.; Lee, G. H.; Dong, T. Y. J. Chin. Chem. Soc. 2002, 49, 825-832.
http://dx.doi.org/10.1002/jccs.200200118

[19]. Jian-Ning, L.; Bo-Wan, W.; Zhang, B.; Yong-Chum, L. Turk.J. Chem. 2006, 30, 41-48.

[20]. Eman, T. S.; AL-Karkhi, I. H. E-Journal Chem. 2012, 9, 1543-1549.

[21]. Sunitha, S.; Aravindakshan, K. K. Int. J. Pharm. Biomed. Sci. 2011, 2(4), 108-113.

[22]. Krishnapriya, K. R.; Kanda, S. M. Polyhedron 2005, 24(1), 113-120.
http://dx.doi.org/10.1016/j.poly.2004.10.010

[23]. Das, G.; Shukala, R.; Mandal, S. Inorg. Chem. 1997, 36, 323-329.
http://dx.doi.org/10.1021/ic9510371

[24]. Nejati, K.; Rezvani, Z. New J. Chem. 2003, 27, 1665-1669.
http://dx.doi.org/10.1039/b305278h

[25]. Xishi, T.; Xiahong, Y.; Qiang, C.; Minyu, T. Molecules 2003, 8, 439-440.
http://dx.doi.org/10.3390/80500439

[26]. Mishra, A. P.; Mishra, R. K.; Shrivastava, S. K. J. Serb. Chem. Soc. 2009, 74, 523-535.
http://dx.doi.org/10.2298/JSC0905523M

[27]. Garnovski, A. D.; Ninorozhkin, A. L.; Minkin, V. I. Rev. 1993, 126(1), 1-69.

[28]. Wang, G.; Chang, J. C. Synth. Inorg. Met.-Org. Chem. 1994, 24, 1091-1097.

[29]. Nakamoto, K. Infrared and Raman spectra of Inorganic and coordination Compounds, 5th Edition, Part A, John Wiley & Sons, Mishawaka, 1998.

[30]. Vafazadeh, R.; Gorji, A.; Ansari, S.; Willis, A.C. Acta Chim. Slovenica 2012, 59(4), 897-903.

[31]. Nakamoto, K. Infrared and Raman spectra of Inorganic and coordination Compounds, 4th Edition, John Wiley & Sons, New York, 1986.

[32]. Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
http://dx.doi.org/10.1016/S0010-8545(00)80455-5

[33]. Samal, S.; Acharya, S.; Dey, R. K.; Ray, A. R. Talanta 2002, 57, 1075-1083.
http://dx.doi.org/10.1016/S0039-9140(02)00144-3

[34]. Samal, S.; Mohapatra, N. K.; Acharya, S.; Dey, K. React. Funct. Polym. 1999, 42, 37-52.
http://dx.doi.org/10.1016/S1381-5148(98)00055-8

[35]. Ikram, M.; Rehman, S.; Baker, S. R. Thermochim. Acta 2013, 555, 72-80.
http://dx.doi.org/10.1016/j.tca.2012.12.023

[36]. Kaya, l.; Oksuzgulmez, S.; Guzel, H. Bull. Chem. Soc. Ethiop. 2008, 22(2), 237-246.

[37]. Cazacum, M.; Marcu, M.; Vald, A.; Rusu, G. I.; Avadanei, M. J. Organometal. Chem. 2004, 689, 3005-3015.
http://dx.doi.org/10.1016/j.jorganchem.2004.05.051

[38]. Hayat, H. A.; Roza, A. S.; Afrodet, A. S. Global J. Pure Appl. Chem. Res. 2015, 22(2), 14-23.

[39]. Mallikarjun, K. G. E-Journal Chem. 2004, 1(2), 105-109.

[40]. Vlaev, L.; Nedelchev, N.; Gyurova, K.; Zagorcheva, M. J. Anal. Appl. Pyrolysis 2008, 81, 253-262.
http://dx.doi.org/10.1016/j.jaap.2007.12.003

[41]. Chourasia, P.; Suryesh, K. K.; Mishra, A. P. Proc. Indian Acad. Sci. 1993, 105, 173-189.


How to cite


Abbas, H. Eur. J. Chem. 2016, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, H. Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases. Eur. J. Chem. 2016, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, H. (2016). Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases. European Journal of Chemistry, 7(4), 436-441. doi:10.5155/eurjchem.7.4.436-441.1445
Abbas, Hayat. "Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases." European Journal of Chemistry [Online], 7.4 (2016): 436-441. Web. 7 Dec. 2021
Abbas, Hayat. "Synthesis, characterization, kinetic and thermodynamic parameters evaluation from TG-DTA analysis of Cu(II), Co(II) and Mn(II) complexes with two phenol Schiff bases" European Journal of Chemistry [Online], Volume 7 Number 4 (31 December 2016)

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