European Journal of Chemistry

Synthesis, characterization and DFT computational studies of new heterocyclic azo compounds

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Faeza Almashal
Abeer Mohamed Jabar
Adil Muala Dhumad

Abstract

New heterocyclic azo compounds were prepared by coupling the diazonium salts with N-(4-methylphenyl)maleimide with various different sulfa compounds. The structure of heterocyclic azo compounds was determined by MS, FT-IR and 1H NMR techniques. The density function theory calculation at the B3LYP method with 6-311G(d,p) basis set is used to investigate the electronic structures of the prepared heterocyclic azo compounds. Mulliken charge distributions and HOMO-LUMO energies of the mentioned compounds have been also computed by same method and basis set.


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Almashal, F.; Jabar, A. M.; Dhumad, A. M. Synthesis, Characterization and DFT Computational Studies of New Heterocyclic Azo Compounds. Eur. J. Chem. 2018, 9, 84-88.

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