European Journal of Chemistry

Synthesis, structure and hydrogen sorption properties of a pyrazine-bridged copper(I) nitrate metal-organic framework

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Emmanuel Ngwang Nfor
Andrew David Burrows
Bridget Ndoye Ndosiri
Luke Lawrence Keenan
Offiong Efanga Offiong

Abstract

A new copper(I) pyrazine-bridged coordination polymer [Cu2(pyz)3(NO3)2]·2DMF] (pyz = pyrazine) (1) has been synthesized and characterized by FT-IR, TG/DTG, DSC and single crystal X-ray diffraction techniques. The X-ray crystallographic result reveals a two-dimensional network structure containing hexagonal pores. Thermal analysis of compound 1 reveals it is stable to 380 °C, and gas sorption studies showed that it adsorbs 1.04 wt% hydrogen at 1 atm and 77 K. Compound 1 crystallizes in a triclinic system, space group P-1 (no. 2), a = 7.9550(2) Å, b = 7.9810(2) Å, c = 11.0660(3) Å, α = 76.328(1)°, β = 71.115(1)°, γ = 84.577(1)°, = 645.79(3) Å3, Z = 2, T = 150(2) K, μ(MoKα) = 1.709 mm-1, Dcalc = 1.639 g/cm3, 11111 reflections measured (7° ≤ 2Θ ≤ 54.96°), 2951 unique (Rint = 0.0539) which were used in all calculations. The final R1 was 0.0346 (>2σ(I)) and wR2 was 0.0727 (all data).


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Nfor, E. N.; Burrows, A. D.; Ndosiri, B. N.; Keenan, L. L.; Offiong, O. E. Synthesis, Structure and Hydrogen Sorption Properties of a Pyrazine-Bridged copper(I) Nitrate Metal-Organic Framework. Eur. J. Chem. 2019, 10, 195-200.

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