European Journal of Chemistry

Synthesis of intermediate compounds with P-N bond from (thio)carbamates and chlorodioxaphospholanes and -phosphorinanes and their reactivity

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Published: Dec 31, 2013
DOI: https://doi.org/10.5155/eurjchem.4.4.336-342.828
Keywords:
Mass-spectra, Sulfur addition, Phosphorinanes, Arbuzov rearrangement, Chlorodioxaphospholanes, N-Phosphorylated carbamates
Section
Research Article
Issue
Vol. 4 No. 4 (2013): December 2013
Dates
Received 2013-05-13
Accepted 2013-06-03
Published 2013-12-31


Main Article Content

Dmitry Murzin
Department of Chemical Engineering, Åbo Akademi University, Turku, 20500, Finland
Vera Kolesova
Department of Chemistry and Technology of Organic Synthesis, Faculty of Technology of Organic Substances and Pharmaceutical Chemistry, Mendeleev University of Chemical Technology, Moscow, 125047, Russia

Abstract

A variety of 2-(N-alkoxy(thio)carbonyl alkyl(aryl)amino)-1,3,2-dioxaphospholanes and phosphorinanes were prepared from chlorodioxaphospholanes and phosphorinanes. Their structures were determined by IR, Mass and NMR spectroscopy. These compounds were employed in direct reactions with elemental sulphur and methylester of chloroacetic acid giving potentially physiologically active N-phosphorylated carbamates with P(O)-N and P(S)N bonds.

4_4_336_342

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Murzin, D.; Kolesova, V. Synthesis of Intermediate Compounds With P-N Bond from (thio)carbamates and Chlorodioxaphospholanes and -Phosphorinanes and Their Reactivity. Eur. J. Chem. 2013, 4, 336-342.

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