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oai:ojs.www.eurjchem.com:article/1282 2015-09-30T05:16:04Z eurjchem:ART driver

Solvatochromic absorption and fluorescence studies of adenine, thymine and uracil thio-derived acyclonucleosides Hammud, Hassan Hasan El-Dakdouki, Mohammad Hasan Sonji, Nada Mohamd Bouhadir, Kamal Hani Absorption Nucleobases Fluorescence Solvatochromism Multiple regression analysis Thio-derived acyclonucleosides Adenine, thymine and uracil thio-derived acyclonucleosides were synthesized and characterized by UV-Vis, FT-IR, 1H and 13C NMR spectroscopic techniques. The photophysical properties of the derivatives were evaluated in solvents with diverse polarities and at various pH values. The solvent dependent absorbance and emission spectral shifts were analysed using physical parameters of the selected solvents. The regression and correlation coefficients were calculated using multiple regression techniques. The fitting coefficients gave an estimate of the contribution of each interaction to the total spectral shift in various solutions. Multiple linear regression studies, Kamlet-Taft equation and stokes shift correlation with orientation polarizability provide valuable information concerning spectroscopic characteristics of the studied molecules. Atlanta Publishing House LLC 2015-09-30 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://www.eurjchem.com/index.php/eurjchem/article/view/1282 10.5155/eurjchem.6.3.325-336.1282 European Journal of Chemistry; Vol. 6 No. 3 (2015): September 2015; 325-336 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/1282/pdf_1282