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oai:ojs.www.eurjchem.com:article/1544 2017-06-30T04:23:02Z eurjchem:ART driver

Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde Hashemian, Saeedeh Mangeli, Mahbobah Cd complex Trans-complex Octahedral geometry 2-Chlorobenzaldehyde Single crystal structure 4-Pyridin-carbohydrazide Reaction of 4-pyridincarbohydrazide, 2-chlorobenzaldehyde and Cd(II) ion in ethanol resulted the complex trans-[Cd(H2O)4(C13H10N3ClO)2](NO3)2. The title complex was characte-rized by elemental analyses, UV-Vis and IR spectroscopy. The structure of complex also was established by single crystal X-ray diffraction analysis. The [Cd(H2O)4(C13H10N3ClO)2](NO3)2complex has monomeric structure with monoclinic crystal system and space group of P21/n, a = 7.7720(16) Å, b = 17.594(4) Å, c = 11.823(2) Å, β = 97.29(3)° with Z = 2. The cadmium atom in the crystal structure has octahedral geometry by coordination of the two nitrogen atoms of ligand and four oxygen atoms of water molecules. Atlanta Publishing House LLC 2017-06-30 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf text/x-fortran https://www.eurjchem.com/index.php/eurjchem/article/view/1544 10.5155/eurjchem.8.2.101-104.1544 European Journal of Chemistry; Vol. 8 No. 2 (2017): June 2017; 101-104 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/1544/pdf_1544 https://www.eurjchem.com/index.php/eurjchem/article/view/1544/2592