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oai:ojs.www.eurjchem.com:article/1570 2017-06-30T04:23:02Z eurjchem:ART driver

A new oxidative reagent synthesis and its applications: Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC) Aydin, Fatma Dersin, Semih Oxidation T-TMPSDC Alcohol oxidation Silver dichromate Oxidative reagent 2 4 6-Trimethylpyridine Tetrakis-(2,4,6-trimethylpyridine)silver(I) dichromate (T-TMPSDC) was easily synthesized by addition of 2,4,6-trimethylpyridine to an aqueous precipitation of silver dichromate and characterized thoroughly, using spectroscopic and others analytical methods such as FT-IR, 1H NMR, 13C NMR, DTA, SEM-EDS and XRD. When T-TMPSDC was used as an oxidative reagent, it showed selectivity in the oxidation of primary, secondary and benzylic alcohols to their corresponding carbonyl compounds in presence of benzylic carbons and arenes such as tetraline, anthracene and phenanthrene. Atlanta Publishing House LLC 2017-06-30 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://www.eurjchem.com/index.php/eurjchem/article/view/1570 10.5155/eurjchem.8.2.174-178.1570 European Journal of Chemistry; Vol. 8 No. 2 (2017): June 2017; 174-178 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/1570/pdf_1570