2026-05-02T16:42:10Z https://www.eurjchem.com/index.php/eurjchem/oai

oai:ojs.www.eurjchem.com:article/2166 2022-06-30T03:25:38Z eurjchem:ART driver

Synthesis, characterization, X-ray crystal structure and Hirshfeld surface analysis of Ni(II) complex of 1,2-bis(pyridin-2-ylmethylene)hydrazine Sahu, Meman Manna, Amit Kumar De, Dinesh Patra, Goutam Kumar Hydrazone Ni(II)triple helix Crystal structure 2-Pyridinaldazine Hirshfield surface analysis 1 2-Bis(Pyridin-2-ylmethylene)hydrazine We report the synthesis, characterization, X-ray crystal structure and Hirshfeld surface analysis of Ni(II) perchlorate complex (1, Ni2L3·4ClO4·2CH3CN) of 1,2-bis(pyridin-2-ylmethylene)hydrazine (L) ligand. The X-ray crystallographic study of complex 1 reveals that in the presence of Ni(II) ions,the ligand L forms a dimeric triple helix with a Ni(II)-Ni(II) distance of 3.794 Å. Crystal data for C40H36Cl4N14Ni2O16: Monoclinic, space group P21/c (no. 14), a = 20.7558(19) Å, b = 13.1937(12) Å, c = 20.0181(18) Å, β = 96.9510(10)°, V = 5441.6(9) Å3, Z = 4, T = 293.15 K, μ(MoKα) = 0.965 mm-1, Dcalc = 1.498 g/cm3, 38075 reflections measured (1.976° ≤ 2Θ ≤ 43.728°), 6557 unique (Rint = 0.0695, Rsigma = 0.0466) which were used in all calculations. The final R1 was 0.0518 (I > 2σ(I)) and wR2 was 0.1270 (all data). The Hirshfeld surface analysis of complex 1 shows that C···H, H···H, N···H and O···H interactions of 10.9, 26.4, 6.7, and 33.4%; respectively, which exposed that the main intermolecular interactions were H···H intermolecular interactions. Atlanta Publishing House LLC 2022-03-31 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf text/plain https://www.eurjchem.com/index.php/eurjchem/article/view/2166 10.5155/eurjchem.13.1.1-7.2166 European Journal of Chemistry; Vol. 13 No. 1 (2022): March 2022; 1-7 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/2166/pdf_2166 https://www.eurjchem.com/index.php/eurjchem/article/view/2166/2724 Copyright (c) 2022 Authors