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Vanadyl(acetylacetonate)2 mediated hydrolytic splitting of 1,3,5-triazine in a solution of toluene at 130 °C: The crystal structure of its axial formamide adduct Arslan, Evrim Bernal, Ivan Lalancette, Roger Triazines Formamide X-ray diffraction Metal basic adduct Magnetic properties Vanadyl acetylacetonates A toluene reaction of vanadyl bis(acetylacetonate) with 1,3,5-triazine produces a symmetrical three-fold hydrolytic cleavage of the triazine, and these three formamide moieties are found in the crystal structure. One of the resulting formamides attaches itself to the sixth (axial) position of the vanadyl complex, producing materials in which the remaining two formamides are trapped in the resulting lattice. Those crystals belong in space group Pca21, Z = 4 and the final R-factor = 0.030 for 3213 data collected at 100 K. Atlanta Publishing House LLC 2022-06-30 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf text/plain application/pdf https://www.eurjchem.com/index.php/eurjchem/article/view/2278 10.5155/eurjchem.13.2.168-171.2278 European Journal of Chemistry; Vol. 13 No. 2 (2022): June 2022; 168-171 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/2278/pdf_2278 https://www.eurjchem.com/index.php/eurjchem/article/view/2278/2720 https://www.eurjchem.com/index.php/eurjchem/article/view/2278/2723 Copyright (c) 2022 Authors