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oai:ojs.www.eurjchem.com:article/44 2011-04-06T05:26:18Z eurjchem:ART driver

A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure Eshtiagh-Hosseini, Hossein Mahjoobizadeh, Milad Mirzaei, Masoud Fromm, Katharina Crochet, Aurelien Proton transfer compound X-ray crystal structure 2 4 6-Triamino-1 3 5-triazine Citric acid π−π Stacking A new three dimensional proton transfer compound, (tataH)2(citH).2H2O (I) was synthesized from the reaction of citric acid (citH3), and 2,4,6-triamino-1,3,5-triazine (tata). The characterization was performed using elemental analysis, IR spectroscopy, and single crystal X-ray structure determination. The crystal structure of the title compound consists of bis-2,4,6-triamino-1,3,5-triazin-1-ium cations, hydrogen citrate, and lattice water molecules. Intermolecular O-H•••O, N-H•••O, and N-H•••N hydrogen bonding interactions stabilize the crystal structure. The hydrogen bonds distances range from of 1.781 to 2.088 Å. The π-π stacking (centroid-centroid ranges 3.410-3.504 Å) between two aromatic rings of tata moieties can play an essential role in the creation and stabilization of the title crystalline network. Atlanta Publishing House LLC 2010-09-29 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://www.eurjchem.com/index.php/eurjchem/article/view/44 10.5155/eurjchem.1.3.179-181.44 European Journal of Chemistry; Vol. 1 No. 3 (2010): September 2010; 179-181 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/44/PDF