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oai:ojs.www.eurjchem.com:article/828 2013-12-31T06:16:57Z eurjchem:ART driver

Synthesis of intermediate compounds with P-N bond from (thio)carbamates and chlorodioxaphospholanes and -phosphorinanes and their reactivity Murzin, Dmitry Kolesova, Vera Mass-spectra Sulfur addition Phosphorinanes Arbuzov rearrangement Chlorodioxaphospholanes N-Phosphorylated carbamates A variety of 2-(N-alkoxy(thio)carbonyl alkyl(aryl)amino)-1,3,2-dioxaphospholanes and phosphorinanes were prepared from chlorodioxaphospholanes and phosphorinanes. Their structures were determined by IR, Mass and NMR spectroscopy. These compounds were employed in direct reactions with elemental sulphur and methylester of chloroacetic acid giving potentially physiologically active N-phosphorylated carbamates with P(O)-N and P(S)N bonds. Atlanta Publishing House LLC 2013-12-31 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf https://www.eurjchem.com/index.php/eurjchem/article/view/828 10.5155/eurjchem.4.4.336-342.828 European Journal of Chemistry; Vol. 4 No. 4 (2013): December 2013; 336-342 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/828/PDF