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oai:ojs.www.eurjchem.com:article/1265 2015-09-30T05:16:04Z eurjchem:ART driver

Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II) Gumus, Ilkay Solmaz, Ummuhan Celik, Omer Binzet, Gun Balcı, Gulten Kavak Arslan, Hakan Thiourea Synthesis Cis-configuration Benzoyl thiourea Platinum complex X-ray single crystal diffraction cis-Bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II), cis-[Pt(L-O,S)2], was synthesized and characterized by elemental analyses, FT-IR and NMR techniques. The obtained metal complex was also characterized by a single crystal X-ray diffraction study. Molecule formula of the title compound is C24H28F2N4O2PtS2: tetragonal, space group I41/a, a = 19.7530(4) Å, b = 19.7530(4) Å, c = 13.7137(3) Å, V = 5350.83(19) Å3, Z = 8, Dcalc = 1.742 g/mm3, 22890 reflections measured (3.62 ≤ 2Θ ≤ 52.72), 2733 (Rint = 0.0272), which were used in all calculations. A square-planar coordination geometry is formed around the Pt atom by two S atoms and two O atoms of the N-(diethylcarbamothioyl)-4-fluorobenzamide ligand which are a cis configuration. Atlanta Publishing House LLC 2015-09-30 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf text/plain https://www.eurjchem.com/index.php/eurjchem/article/view/1265 10.5155/eurjchem.6.3.237-241.1265 European Journal of Chemistry; Vol. 6 No. 3 (2015): September 2015; 237-241 2153-2257 2153-2249 eng https://www.eurjchem.com/index.php/eurjchem/article/view/1265/pdf_1265 https://www.eurjchem.com/index.php/eurjchem/article/view/1265/2567