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2013-06-30T03:41:05Z
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Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6
Dhouib, Ikram
Guionneau, Philippe
Pechev, Stanislav
Mhiri, Tahar
Elaoud, Zakaria
Single crystal
Copper(II) complex
Spectroscopic study
Tetrapropylammonium
Hexachlorodicuprate(II)
Crystal structure analysis
Single crystals of the bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl6, were grown by slow evaporation solution technique at room temperature. The compound was characterized by Raman, IR and single crystal X-ray diffraction studies. Crystal data for C12H28Cl3CuN (M = 356.24 g/mol): triclinic, space group P-1 (no. 2), a = 9.3851(2) Å, b = 9.3844(2) Å, c = 11.8837(3) Å, α = 106.3330(11)°, β = 100.0280(12)°, γ = 113.2830(12)°, V = 872.95(3) Å3, Z = 2, T = 293(2) K, μ(MoKα) = 1.693 mm-1, Dcalc = 1.355 g/mm3, 8056 reflections measured (6.64 ≤ 2Θ ≤ 62.02), 5526 unique (Rint = 0.0303) which were used in all calculations. The final R1 was 0.0427 (>2σ(I)) and wR2 was 0.1312 (all data). The atomic arrangement can be described by alternating organic and inorganic layers parallel to the (101) plan, made up of tetrapropylammonium groups and Cu2Cl6 dimers, respectively. In crystal structure, the inorganic layers, built up by Cu2Cl6 dimers, are connected to the organic ones through hydrogen bonding C-H…Cl and Van der Waals interaction in order to build cation-anion-cation cohesion. These interactions cause to the formation of a three-dimensional supramolecular architecture.
Atlanta Publishing House LLC
2013-06-30
info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
application/pdf
chemical/x-cif
https://www.eurjchem.com/index.php/eurjchem/article/view/738
10.5155/eurjchem.4.2.117-120.738
European Journal of Chemistry; Vol. 4 No. 2 (2013): June 2013; 117-120
2153-2257
2153-2249
eng
https://www.eurjchem.com/index.php/eurjchem/article/view/738/PDF
https://www.eurjchem.com/index.php/eurjchem/article/view/738/2547