European Journal of Chemistry 2010, 1(4), 312-318 | doi: https://doi.org/10.5155/eurjchem.1.4.312-318.105 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution


Abd El-Aziz Fouda (1) , Ahmed Al-Sarawy (2) , Emad El-Katori (3,*)

(1) Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, EG-35516, Egypt
(2) Department of Mathematical and Physical Science, Faculty of Engineering, Mansoura University, Mansoura, EG-35516, Egypt
(3) Department of Chemistry, Faculty of Science, King Khalid University, Abha, SA-61413, Saudi Arabia
(*) Corresponding Author

Received: 10 May 2010 | Accepted: 30 Sep 2010 | Published: 22 Dec 2010 | Issue Date: December 2010

Abstract


5-phenylazo-2-thioxo-thiazolidin-4-one and four of its derivatives have been investigated as corrosion inhibitors for C-steel in 1 M sulphuric acid solution using weight-loss and galvanostatic polarization techniques. The efficiency of the inhibitors increases with increase in inhibitor concentration but decreases with a rise in temperature. The conjoint effect of the thiazole derivatives and KBr, KSCN and KI has also been studied. The apparent activation energy (Ea*) and other thermodynamic parameters (ΔS*, ΔH* and ΔG*ads) for the corrosion process have also been calculated. The galvanostatic polarization data indicated that, the inhibitors were of mixed-type, but the cathode is more polarized than the anode. The slopes of the cathodic and anodic Tafel lines (ßc and ßa) are approximately constant and independent of the inhibitor concentration. The adsorption of these compounds on C-steel surface has been found to obey the Temkin's adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.

1_4_312_318_800


Keywords


Corrosion inhibitors; C-steel; Weight loss; Synergistic effect; Polarization; Thiazole derivatives

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.1.4.312-318.105

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 965 times | PDF Article downloaded 506 times


Citations

/


[1]. Emad E. El-Katori, A.S. Fouda, Rahma R. Mohamed
The Synergistic Impact of the Aqueous Valerian Extract and Zinc Ions for the Corrosion Protection of Mild Steel in Acidic Environment
Zeitschrift für Physikalische Chemie  233(12), 1713, 2019
DOI: 10.1515/zpch-2019-1377
/


[2]. T. K. Chaitra, K. N. Mohana, H. C. Tandon
Study of New Thiazole Based Pyridine Derivatives as Potential Corrosion Inhibitors for Mild Steel: Theoretical and Experimental Approach
International Journal of Corrosion  2016, 1, 2016
DOI: 10.1155/2016/9532809
/


[3]. A.S. Fouda, A.M. El-Defrawy, M.W. El-Sherbeni
Lornoxicam & Tenoxicam Drugs as Green Corrosion Inhibitors for Carbon Steel in 1 M H2SO4Solution
Journal of Electrochemical Science and Technology  4(2), 47, 2013
DOI: 10.5229/JECST.2013.4.2.47
/


[4]. S. G. Sagdinc, Y. S. Kara
Theoretical elucidation on corrosion inhibition efficiency of 11-cyano undecanoic acid phenylamide derivatives: DFT study
Protection of Metals and Physical Chemistry of Surfaces  50(1), 111, 2014
DOI: 10.1134/S2070205114010201
/


[5]. Ashish Kumar Singh, Bhawna Chugh, Sanjeeve Thakur, Balaram Pani, Hassane Lgaz, Ill-Min Chung, Shweta Pal, Rajiv Prakash
Green approach of synthesis of thiazolyl imines and their impeding behavior against corrosion of mild steel in acid medium
Colloids and Surfaces A: Physicochemical and Engineering Aspects  599, 124824, 2020
DOI: 10.1016/j.colsurfa.2020.124824
/


[6]. A. S. Fouda, F. Sh. Mohamed, M. W. El-Sherbeni
Corrosion Inhibition of Aluminum–Silicon Alloy in Hydrochloric Acid Solutions Using Carbamidic Thioanhydride Derivatives
Journal of Bio- and Tribo-Corrosion  2(2), , 2016
DOI: 10.1007/s40735-016-0039-y
/


[7]. Chikkur B. Pradeep Kumar, Kikkeri N. Mohana
The Effect of Achyranthes aspera Extracts on Mild Steel Corrosion in Industrial Water Medium
ISRN Corrosion  2013, 1, 2013
DOI: 10.1155/2013/261847
/


[8]. Mahmoud N. El-Haddad, A. S. Fouda, H. A. Mostafa
Corrosion Inhibition of Carbon Steel by New Thiophene Azo Dye Derivatives in Acidic Solution
Journal of Materials Engineering and Performance  22(8), 2277, 2013
DOI: 10.1007/s11665-013-0508-0
/


[9]. Ivan Hameed R. Tomi, Ali. H. R. Al-Daraji, Sherien A. Aziz
Synthesis, Characterization, and Study the Inhibitory Effect of Thiazole and Thiadiazole Derivatives Toward the Corrosion of Copper in Acidic Media
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry  45(4), 605, 2015
DOI: 10.1080/15533174.2013.841226
/


[10]. Emad E. El-Katori, Saedah Al-Mhyawi
Assessment of the Bassia muricata extract as a green corrosion inhibitor for aluminum in acidic solution
Green Chemistry Letters and Reviews  12(1), 31, 2019
DOI: 10.1080/17518253.2019.1569728
/


References

[1]. Huilong, W.; Jiashen, Z.; Jing, L. Anti-Corros. Meth. M. 2002, 49(2), 127-132.

[2]. Saeed, T.; Ali, S. A.; Rahman, S. U. Anti-Corros. Meth. M. 2003, 50(3), 201-207.

[3]. Atia, A. A.; Saleh, M. M. J. Appl. Electrochem. 2003, 33(2), 171-177.
doi:10.1023/A:1024083117949

[4]. Tamilselvi, S.; Rajeswari, S. Anti-Corros. Meth. M. 2003, 50(3), 223-231.

[5]. Keera, S. T. Anti-Corros. Meth. M. 2003, 50(4), 280-285.

[6]. Wang, H. L., Liu, R. B.; Xin, J. Corros. Sci. 2004, 46(10), 2455-2466.
doi:10.1016/j.corsci.2004.01.023

[7]. Fouda, A. S.; Mostafa, H. A.; El-Taib-Heakel, F.; Elewady, G. Y. Corros. Sci. 2005, 47(8), 1988-2004.
doi:10.1016/j.corsci.2004.09.008

[8]. Migahed, M. A.; Mohamed, H. M.; Al-Sabagh, A. M. Mater. Chem. Phys. 2003, 80(1), 169-175.
doi:10.1016/S0254-0584(02)00456-X

[9]. Soror, T. Y.; El-Ziady, M. A. Mater. Chem. Phys. 2003, 77 (3), 697-703.
doi:10.1016/S0254-0584(02)00129-3

[10]. Lebrini, M.; Lagrenee, H.; Vezin, H.; Gengembre, L.; Bentiss, F. Corros. Sci. 2005, 47(2), 485-505.
doi:10.1016/j.corsci.2004.06.001

[11]. Mubarak, A. T. J. Sol. Chem. 2004, 33(2), 149-155.
doi:10.1023/B:JOSL.0000030282.00934.91

[12]. El-Bindary, A. A.; El-Sonbati, A. Z.; El-Mosalamy, E. H.; El-Santawy, E. M. Spectrochim. Acta Part A 2001, 57(12), 2359-2365.
doi:10.1016/S1386-1425(01)00422-X

[13]. Fouda, A. S.; El-Kaabi, S. S.; Mohamed, A. K. Corros. Prevent Contr. 1990, 37(6), 164-165.

[14]. Otieno-Alego, V.; Hope, G. A.; Flitt, H. J.; Cash, G. A.; Schweinsberg, D. P. Corros. Sci. 1992, 33(11), 1719-1734.
doi:10.1016/0010-938X(92)90004-M

[15]. Hoar, T. P.; Holliday, R. D. J. Appl. Chem. 1953, 3(11), 502-513.

[16]. El-Awady, Y. A.; Ahmed, A. I. J. Ind. Chem. 1985, 24A, 601-606.

[17]. Al-Neami, K. K.; Mohamed, A. K.; Kenawy, I. M.; Fouda, A. S. Monatsh Chem. 1995, 126, 369-376.
doi:10.1007/BF00813198

[18]. Haladky, K.; Collow, L.; Dawson, J. Br. Corros. J. 1980, 15, 20-21.

[19]. Caliskan, N.; Bilgic, S. Appl. Surf. Sci. 2000, 153, 128-133.
doi:10.1016/S0169-4332(99)00338-4

[20]. Khamis, E.; El-Ashry, E. S. H.; Ibrahim, A. K. Br. Corrosion J. 2000, 35(2), 150-154.
doi:10.1179/000705900101501191

[21]. Fouda, A. S.; Al-Sarawy, A. A.; El-Katori, E. E. Desalination, 2006, 201, 1–13.
doi:10.1016/j.desal.2006.03.519

[22]. Hammett, L. P. Physical Organic Chemistry, McGraw-Hill Book Co., N.Y., 1940

[23]. Donahue, F. M.; Nobe, K. J. Electrochem. Soc. 1965, 112(3), 886-891.
doi:10.1149/1.2423723

[24]. Smialowska, Z. S.; Kaminski, M. Corros. Sci. J. 1973, 13(1), 1-10.
doi:10.1016/0010-938X(73)90045-0

How to cite


Fouda, A.; Al-Sarawy, A.; El-Katori, E. Eur. J. Chem. 2010, 1(4), 312-318. doi:10.5155/eurjchem.1.4.312-318.105
Fouda, A.; Al-Sarawy, A.; El-Katori, E. Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution. Eur. J. Chem. 2010, 1(4), 312-318. doi:10.5155/eurjchem.1.4.312-318.105
Fouda, A., Al-Sarawy, A., & El-Katori, E. (2010). Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution. European Journal of Chemistry, 1(4), 312-318. doi:10.5155/eurjchem.1.4.312-318.105
Fouda, Abd, Ahmed Al-Sarawy, & Emad El-Katori. "Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution." European Journal of Chemistry [Online], 1.4 (2010): 312-318. Web. 14 Jul. 2020
Fouda, Abd, Al-Sarawy, Ahmed, AND El-Katori, Emad. "Thiazole derivatives as corrosion inhibitors for C-steel in sulphuric acid solution" European Journal of Chemistry [Online], Volume 1 Number 4 (22 December 2010)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.1.4.312-318.105

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2010, 1(4), 312-318 | doi: https://doi.org/10.5155/eurjchem.1.4.312-318.105 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort