European Journal of Chemistry 2015, 6(3), 314-318 | doi: https://doi.org/10.5155/eurjchem.6.3.314-318.1276 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis, characterization and ionic conductivity of MgAl2O4


Abdelhakim Elmhamdi (1) , Kais Nahdi (2,*)

(1) Laboratoire d'Application de la Chimie aux Ressources et Substances Naturelles et à l'Environnement (LACReSNE), Faculté des Sciences de Bizerte, Université de Carthage, 7021 Bizerte, Tunisie
(2) Laboratoire d'Application de la Chimie aux Ressources et Substances Naturelles et à l'Environnement (LACReSNE), Faculté des Sciences de Bizerte, Université de Carthage, 7021 Bizerte, Tunisie
(*) Corresponding Author

Received: 01 Jun 2015 | Accepted: 28 Jun 2015 | Published: 30 Sep 2015 | Issue Date: September 2015

Abstract


Magnesium aluminate nanoparticles have been synthesized by a citrate sol-gel route. X-ray diffraction and IR spectroscopy study confirmed the formation of MgAl2O4 cubic spinel structure without presence of any secondary phase. Crystallite size of the synthesized nanoparticles was found to be equal to 24 nm. The ac conductivity of MgAl2O4 was studied using complex impedance spectroscopy technique in the frequency range from 5 Hz to 13 MHz and temperature range from 673 to 798 K. The temperature and frequency dependence of ac conductivity were highlighted and the activation energies of, respectively, ac conduction and relaxation processes were also calculated.


Keywords


MgAl2O4; Jonscher law; Citrate sol-gel; Ac conductivity; Activation energy; Impedance spectroscopy

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.6.3.314-318.1276

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 638 times | PDF Article downloaded 289 times


Citations

/


[1]. Bülent Aktaş, Süleyman Tekeli
Ionic conductivity of MgAl2O4-doped 8YSZ ceramics
Arabian Journal of Geosciences  12(15), , 2019
DOI: 10.1007/s12517-019-4657-9
/


References

[1]. Sickafus, K. E.; Wills, J. M. J. Am. Ceram. Soc. 1999, 82(12), 3279-3292.
http://dx.doi.org/10.1111/j.1151-2916.1999.tb02241.x

[2]. Wyckoff, R. W. G. Wiley Interscience, New York, 1964.

[3]. Yamakawa, A.; Hashiba, M.; Nurishi, Y. J. Mater. Sci. 1989, 24, 1491-1498.
http://dx.doi.org/10.1007/BF02397091

[4]. Ganesh, I.; Srinivas, B.; Johnson, R.; Saha, B. P.; Mahajan, Y. R. Br. Ceram. Trans. 2002, 101, 247-254.
http://dx.doi.org/10.1179/096797802225004063

[5]. Ganesh, I.; Johnson, R.; Rao, G. V. N.; Mahajan, Y. R.; Madavendra, S. S.; Reddy, B. M. Ceram. Int. 2005, 31, 67-74.
http://dx.doi.org/10.1016/j.ceramint.2004.03.036

[6]. Adak, A. K.; Saha, S. K.; Pramanik, P. J. Mater. Sci. Lett. 1997, 16, 234-235.
http://dx.doi.org/10.1023/A:1018512025919

[7]. Ganesh, I.; Bhattacharjee, S.; Saha, B. P.; Johnson, R.; Rajeshwari, K.; Sengupta, R.; Ramanarao, M. V.; Mahajan, Y. R. Ceram. Int. 2002, 28(3), 245-253.
http://dx.doi.org/10.1016/S0272-8842(01)00086-4

[8]. Bhaduri, S.; Bhaduri, S. B. Ceram. Int. 2002, 28(2), 153-158.
http://dx.doi.org/10.1016/S0272-8842(01)00071-2

[9]. Ji-Guang Lee, T. I.; Lee, J. H.; Mori, T. J. Am. Ceram. Soc. 2000, 83(11), 2866-2868.

[10]. Baudin, C.; Martinez, R.; Pena, P. J. Am. Ceram. Soc. 1995, 78, 1857-1862.
http://dx.doi.org/10.1111/j.1151-2916.1995.tb08900.x

[11]. Ryshekewitch, E. Oxide Ceramics, Academic Press, New York 1960, pp. 257.

[12]. Kriegel, W. W.; Palmer III, H.; Choi, D. M. Spec. Ceram. 1964, 3, 167-186.

[13]. Bakker, W. T.; Lindsay, L. G. Am. Ceram. Soc. Bull. 1967, 46, 1094-1097.

[14]. Bailey, J. T.; Russell, R. Am. Ceram. Soc. Bull. 1968, 47, 1025-1029.

[15]. Hamono, K.; Kanzaki, S. J. Ceram. Soc. Jpn. 1977, 85, 225-230.

[16]. Kostic, E.; Momcilovic, L. Ceramurgia Int. 1977, 3, 57-60.
http://dx.doi.org/10.1016/0390-5519(77)90030-8

[17]. Teoreanu, I.; Ciocea, N. Interceram. 1987, 4, 19-21.

[18]. Park, H. C.; Lee, Y. B.; Oh, K. D.; Riley, F. L. J. Mater. Sci. Lett. 1997, 16, 1841-1844.
http://dx.doi.org/10.1023/A:1018585105949

[19]. Sarkar, R.; Das, S. K.; Banerjee, G. Ceram. Int. 1999, 25, 485-489.
http://dx.doi.org/10.1016/S0272-8842(98)00065-0

[20]. Sarkar, R.; Banerjee, G. J. Eur. Ceram. Soc. 1999, 19, 2893-2900.
http://dx.doi.org/10.1016/S0955-2219(99)00078-3

[21]. Zografou, C.; Reynen, P.; Van Mallinckrodt, D. Interceram. 1983, 38, 37-39.

[22]. Zografou, C.; Reynen, P.; Van Mallinckrodt, D. Interceram. 1983, 38, 40-43.

[23]. Serry, M. A.; Hammad, S. M.; Zawrah, M. F. Br. Ceram. Trans. 1998, 97, 275-282.

[24]. Domanski, D.; Urretavizcaya, G.; Castro, F. J.; Gennan, F. C. J. Am. Ceram. Soc. 2004, 87, 2020-2024.
http://dx.doi.org/10.1111/j.1151-2916.2004.tb06354.x

[25]. Angappan, S.; Berchmans, L. J.; Augustin, C. O. Mater. Lett. 2004, 58, 2283-2289.
http://dx.doi.org/10.1016/j.matlet.2004.01.033

[26]. Chen, S. K.; Cheng, M. Y.; Lin, S. J. J. Am. Ceram. Soc. 2002, 85, 540-544.
http://dx.doi.org/10.1111/j.1151-2916.2002.tb00130.x

[27]. Ghosh, A.; Das, S. K.; Biswas, J. R.; Tripathi, H. S.; Banerjee, G. Ceram. Int. 2000, 26, 605-608.
http://dx.doi.org/10.1016/S0272-8842(99)00104-2

[28]. Ganes, I.; Bhattacharjee, S.; Saha, B. P.; Johnson, R.; Mahajan, Y. R. Ceram. Int. 2001, 27, 773-779.
http://dx.doi.org/10.1016/S0272-8842(01)00029-3

[29]. Li, J. G.; Ikegami, T.; Lee, J. H.; Mori, T. J. Am. Ceram. Soc. 2000, 83, 2866-2868.
http://dx.doi.org/10.1111/j.1151-2916.2000.tb01648.x

[30]. Yang, N.; Chang, L. Mater. Lett. 1992, 15, 84-88.
http://dx.doi.org/10.1016/0167-577X(92)90017-E

[31]. Behera, S. K.; Barpanda, P.; Pratihar, S. K.; Bhattacharyya, S. Mater. Lett. 2004, 58, 1451-1455.
http://dx.doi.org/10.1016/j.matlet.2003.10.004

[32]. Zhang, H.; Jia, X.; Liu, Z.; Li, Z. Mater. Lett. 2004, 58, 1625-1628.

[33]. Debsikdar, J. C. J. Mater. Sci. 1985, 20, 4454-4458.
http://dx.doi.org/10.1007/BF00559334

[34]. Naskar, M. K.; Chatterjee, M. J. Am. Ceram. Soc. 2005, 88, 38-44.
http://dx.doi.org/10.1111/j.1551-2916.2004.00019.x

[35]. Guo, J.; Lou, H.; Zhao, H.; Wang, X.; Zheng, X. Mater. Lett. 2004, 58, 1920-1923.
http://dx.doi.org/10.1016/j.matlet.2003.12.013

[36]. Bratton, R. J. Ceram. Bull. 1969, 48(8), 759-762.

[37]. Ayman, A. A.; Mahmud, R. A.; Teymur, M. I. Casp. J. Appl. Sci. Res. 2013, 2(2), 85-90.

[38]. Kakooei, S.; Rouchi, J.; Mohammad, E.; Alimanesh, M.; Dehzangi, A. Casp. J. Appl. Sci. Res. 2012, 1(13), 16-22.

[39]. Pacurariu, C.; Lazau, I.; Ecsedi, Z.; Lazau, R.; Barvinschi, P.; Marginean, G. J. Eur. Ceram. Soc. 2007, 27, 707-710.
http://dx.doi.org/10.1016/j.jeurceramsoc.2006.04.050

[40]. Saberi, A.; Golestani-Fard, F.; Sarpoolaky, H.; Willert-Porada, M.; Gerdes, T.; Simon, R. J. Alloy. Compd. 2008, 462, 142-146.
http://dx.doi.org/10.1016/j.jallcom.2007.07.101

[41]. Marakkar, P. V. K.; Subrata, D. Ceram. Int. 2013, 39, 7891-7894.
http://dx.doi.org/10.1016/j.ceramint.2013.03.050

[42]. Alvar, E. N.; Rezaei, M.; Alvar, H. N. Powder Technol. 2010, 198, 275-278.
http://dx.doi.org/10.1016/j.powtec.2009.11.019

[43]. Gualtiero, G.; Giampiero, M.; Enrico, T. J. Am. Ceram. Soc. 1993, 76, 743-750
http://dx.doi.org/10.1111/j.1151-2916.1993.tb03669.x

[44]. Kurien, S.; Sebastian, S.; Mathew, J.; George, K. C. Indian J. Pure Appl. Phys. 2004, 42, 926-933.

[45]. Iqbal, M. J.; Ismail, B. J. J. Alloys Compd. 2009, 472, 434-440.
http://dx.doi.org/10.1016/j.jallcom.2008.04.079

[46]. Saha, S.; Das, B.; Mazumder, N.; Bharati, A.; Chattopadhyay, K. K. J. Sol-Gel Sci. Technol. 2012, 61, 518-526.
http://dx.doi.org/10.1007/s10971-011-2654-x

[47]. Padmaraj, O.; Venkateswarlu, M.; Satyanarayana, N. Ceram. Int. 2015, 41, 3178-3185.
http://dx.doi.org/10.1016/j.ceramint.2014.10.169

[48]. Massoud, K.; Sami, C.; Abdelwahab, I.; Adel, M.; Chaabane, C. Ceram. Inter. 2013, 39, 3873–3879
http://dx.doi.org/10.1016/j.ceramint.2012.10.230

[49]. Pacurariu, C.; Lazau, I.; Ecsedi, Z.; Lazau, R.; Barvinschi, P.; Marginean, G. J. Eur. Ceram. Soc. 2007, 27, 707-710.
http://dx.doi.org/10.1016/j.jeurceramsoc.2006.04.050

[50]. Molak, A.; Paluch, M.; Pawlus, S.; Klimontko, J.; Ujma, Z.; Gruszka, I. J. Phys. D Appl. Phys. 2005, 38, 1450-1460.
http://dx.doi.org/10.1088/0022-3727/38/9/019

[51]. Jonscher, A. K. Nature 1977, 267, 673-679.
http://dx.doi.org/10.1038/267673a0

[52]. Funke, K. J. Non-Cryst. Solids 1994, 1215, 172-174.

[53]. Ngai, K. L.; Tsang, K. Y. Phys. Rev. E 1999, 60, 4511-4517.
http://dx.doi.org/10.1103/PhysRevE.60.4511

How to cite


Elmhamdi, A.; Nahdi, K. Eur. J. Chem. 2015, 6(3), 314-318. doi:10.5155/eurjchem.6.3.314-318.1276
Elmhamdi, A.; Nahdi, K. Synthesis, characterization and ionic conductivity of MgAl2O4. Eur. J. Chem. 2015, 6(3), 314-318. doi:10.5155/eurjchem.6.3.314-318.1276
Elmhamdi, A., & Nahdi, K. (2015). Synthesis, characterization and ionic conductivity of MgAl2O4. European Journal of Chemistry, 6(3), 314-318. doi:10.5155/eurjchem.6.3.314-318.1276
Elmhamdi, Abdelhakim, & Kais Nahdi. "Synthesis, characterization and ionic conductivity of MgAl2O4." European Journal of Chemistry [Online], 6.3 (2015): 314-318. Web. 13 Aug. 2020
Elmhamdi, Abdelhakim, AND Nahdi, Kais. "Synthesis, characterization and ionic conductivity of MgAl2O4" European Journal of Chemistry [Online], Volume 6 Number 3 (30 September 2015)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.6.3.314-318.1276

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2015, 6(3), 314-318 | doi: https://doi.org/10.5155/eurjchem.6.3.314-318.1276 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.

hatay escort hatay escort corlu escort corum escort burgaz escort giresun escort aydin escort ordu escort erzincan escort hatay escort sivas escort rize escort edirne escort aksaray escort kibris escort isparta escort erzurum escort tekirdag escort usak escort urfa escort kastamonu escort kibris escort manisa escort giresun escort urfa escort nevsehir escort sivas escort yalova escort ordu escort hatay escort yalova escort amasya escort kayseri escort ordu escort maras escort canakkale escort yalova escort balikesir escort manisa escort urfa escort mugla escort trabzon escort bolu escort corlu escort diyarbakir escort isparta escort kutahya escort elazig escort erzurum escort sakarya escort afyon escort kutahya escort konya escort agri escort cesme escort sinop escort sivas escort konya escort kibris escort adapazari escort luleburgaz escort adana escort kibris escort rize escort sakarya escort alanya escort isparta escort burdur escort konya escort bitlis escort canakkale escort sivas escort amasya escort mus escort aydin escort van escort yalova escort kastamonu escort mardin escort bolu escort afyon escort sakarya escort isparta escort tokat escort trakya escort bayburt escort urfa escort mardin escort