European Journal of Chemistry 2017, 8(2), 101-104 | doi: https://doi.org/10.5155/eurjchem.8.2.101-104.1544 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde


Saeedeh Hashemian (1,*) , Mahbobah Mangeli (2)

(1) Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
(2) Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
(*) Corresponding Author

Received: 15 Jan 2017 | Revised: 02 Mar 2017 | Accepted: 02 Mar 2017 | Published: 30 Jun 2017 | Issue Date: June 2017

Abstract


Reaction of 4-pyridincarbohydrazide, 2-chlorobenzaldehyde and Cd(II) ion in ethanol resulted the complex trans-[Cd(H2O)4(C13H10N3ClO)2](NO3)2. The title complex was characte-rized by elemental analyses, UV-Vis and IR spectroscopy. The structure of complex also was established by single crystal X-ray diffraction analysis. The [Cd(H2O)4(C13H10N3ClO)2](NO3)2complex has monomeric structure with monoclinic crystal system and space group of P21/n, a = 7.7720(16) Å, b = 17.594(4) Å, c = 11.823(2) Å, β = 97.29(3)° with Z = 2. The cadmium atom in the crystal structure has octahedral geometry by coordination of the two nitrogen atoms of ligand and four oxygen atoms of water molecules.


Keywords


Cd complex; Trans-complex; Octahedral geometry; 2-Chlorobenzaldehyde; Single crystal structure; 4-Pyridin-carbohydrazide

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.8.2.101-104.1544

Links for Article


| | | | | | |

| | | | | | |

Related Articles




Article Metrics

This Abstract was viewed 658 times | PDF Article downloaded 176 times

Funding information


Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran

References

[1]. Sah, P. P.; Peoples, S. A. J. Am. Pharm. Assoc. Am. Pharm. Assoc. 1954, 43(9), 513-524.
https://doi.org/10.1002/jps.3030430902

[2]. Singh, B.; Narang, K. K.; Srivastava, R. Synth. React. Inorg. Met. Org. Chem. 2002, 32(9), 1419-1577.

[3]. Naran, K. K.; Singh, V. P. Syn. React. Inorg. Met. Org. Chem. 1997, 27, 721-725.
https://doi.org/10.1080/00945719708000222

[4]. Cesur, Z.; Buyuktimkin, S.; Buyuktimkin, N.; Derbentli, S. Archiv der Pharmazie 1990, 323, 141-144.
https://doi.org/10.1002/ardp.19903230304

[5]. Bottari, B.; Maccari, R.; Monforte, F.; Ottana, R.; Rotondo, E.; Vigorita, M. G. Bioorg. Med. Chem. Lett. 2000, 10, 657-660.
https://doi.org/10.1016/S0960-894X(00)00058-5

[6]. Pahlavani, L.; Kargar, H.; Sepehri, R.; Zahedan, N. J. Res. Med. Sci. 2015, 17(7), 7-10.

[7]. Rodrigues, F. A. R.; Oliveira-Augusto, C. A.; Cavalcanti, B. C.; Pessoa, C.; Pinheiro, A. C.; Souza, M. V. N. Sci. Pharm. 2014, 82(1), 21-28.
https://doi.org/10.3797/scipharm.1307-25

[8]. Khan, M. S. Y.; Chawla, M. A. Indian J. Chem. B 2004, 43, 1302-1305.

[9]. Liu, L; Alam, M. S.; Lee, D. U. Bull. Korean Chem. Soc. 2012, 33(10), 3361-3367.
https://doi.org/10.5012/bkcs.2012.33.10.3361

[10]. Mohan, M. G.; Chandra, M. P.; Jha, L. N. K. Inorg. Chim. Acta 1988, 151, 61-68.
https://doi.org/10.1016/S0020-1693(00)83485-4

[11]. Sinh, R. B.; Jain, P. Talanta 1982, 29, 77-84.
https://doi.org/10.1016/0039-9140(82)80024-6

[12]. Kriza, I.; Oprea, O.; Stanica, N. Revista de Chimie Bucharest Orig. Edi. 2010, 61(8), 733-739.

[13]. Mitu, L.; Ilis, M.; Raman, N.; Imran, M.; Ravichandran, S. E-J. Chem. 2012, 9(1), 365-372.

[14]. Fu, Z.; Gao, S.; Liu, S. Acta Crystallog. C 2007, 63, m459-m461.
https://doi.org/10.1107/S0108270107044010

[15]. Jian, G.; Xian-Hui, A.; Tong-Tao, X.; Yi-Cui, J.; Da-Qi, W. Syn. React. Inorg. Met. Org. Chem. 2006, 36(10), 753-757.
https://doi.org/10.1080/15533170601028264

[16]. Ming-Liang, L.; Qiong, Y. Acta Crystallog. C. 2013, 69, 17-20.

[17]. Sheldrick, G. M. SHELX-97, Program for the Solution and Refinement of Crystal Structures; University of Göttingen: Germany, 1997.

[18]. Kriza, A.; Ababei, L.; Stanica, N.; Rau, I. Rev. Chim. (Bucuresti) 2009, 60(8), 774-777.

[19]. Kriza, A.; Pricop, L.; Meghean, A. J. Indian Chem. Soc. 2001, 78, 448-452.

Supporting information


The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Hashemian, S.; Mangeli, M. Eur. J. Chem. 2017, 8(2), 101-104. doi:10.5155/eurjchem.8.2.101-104.1544
Hashemian, S.; Mangeli, M. Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde. Eur. J. Chem. 2017, 8(2), 101-104. doi:10.5155/eurjchem.8.2.101-104.1544
Hashemian, S., & Mangeli, M. (2017). Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde. European Journal of Chemistry, 8(2), 101-104. doi:10.5155/eurjchem.8.2.101-104.1544
Hashemian, Saeedeh, & Mahbobah Mangeli. "Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde." European Journal of Chemistry [Online], 8.2 (2017): 101-104. Web. 19 Sep. 2020
Hashemian, Saeedeh, AND Mangeli, Mahbobah. "Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde" European Journal of Chemistry [Online], Volume 8 Number 2 (30 June 2017)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.8.2.101-104.1544

| | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2017, 8(2), 101-104 | doi: https://doi.org/10.5155/eurjchem.8.2.101-104.1544 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.