European Journal of Chemistry 2018, 9(1), 22-29 | doi: https://doi.org/10.5155/eurjchem.9.1.22-29.1671 | Get rights and content






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Synthesis, characterization and antioxidant activity of Schiff base and its metal complexes with Fe(II), Mn(II), Zn(II), and Ru(II) ions: Catalytic activity of ruthenium(II) complex


Nevin Turan (1,*) orcid , Kenan Buldurun (2) orcid

(1) Department of Chemistry, Faculty of Arts and Sciences, Mus Alparslan University, 49250 Mus, Turkey
(2) Department of Chemistry, Faculty of Arts and Sciences, Mus Alparslan University, 49250 Mus, Turkey
(*) Corresponding Author

Received: 13 Nov 2017 | Revised: 05 Dec 2017 | Accepted: 13 Dec 2017 | Published: 31 Mar 2018 | Issue Date: March 2018

Abstract


The synthesis, spectral, catalytic and antioxidant properties of ethyl-2-(2-hydroxy-3-methoxybenzylideneamino)-6-methyl-4,5,6-tetrahydrobenzo[b]thiophene-3-carboxylate (L) substituted iron(II), manganese(II), zinc(II), and ruthenium(II)-arene chlorides are described for the first time. The ligand and its metal complexes were characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, and spectral (1H NMR, 13C NMR, FT-IR, UV-Vis and Mass) techniques. The FT-IR spectra showed that the ligand can act as bidentate or tridentate. Magnetic moments and electronic spectral studies revealed an octahedral geometry for all the complexes obtained. The thermal behavior of the complexes showed that the water molecules were separated in the first step followed immediately by decomposition of the anions and ligand molecules in the subsequent steps. Ru(II) complex was used as catalysts for the transfer hydrogenation of ketones. At the same time, the effect of various bases such as NaOH, KOH, KOBut and NaOAc as organic base were investigated in the transfer hydrogenation of ketones by 2-propanol as the hydrogen source. The complexes and ligand were tested in vitro for their antioxidant activity. The experimental results showed that Ru(II) complex had more potent antioxidant activities than Zn(II), Fe(II), Mn(II) complexes and parent ligand.


Keywords


Metal complexes; Thiophene ligand; Catalytic properties; Structure elucidation; Antioxidant properties; Transfer hydrogenation

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DOI: 10.5155/eurjchem.9.1.22-29.1671

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Funding information


Mus Alparslan University, 49250 Mus, Turkey.

Citations

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[1]. KENAN BULDURUN, İsmail Özdemir
Ruthenium(II) half-sandwich complexes containing N-substituted 5-nitrobenzimidazole: Synthesis, structures and catalytic transfer hydrogenation of ketones
Düzce Üniversitesi Bilim ve Teknoloji Dergisi  7(2), , 2019
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[2]. Kenan Buldurun, Metin Özdemir
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[3]. Chandana Sarma, Pankaj Kumar Chaurasia, Shashi Lata Bharati
Versatile Catalytic Applications of Manganese(II,III) Schiff Base Complexes (Review)
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[4]. Jagvir Singh, Anuradha, Pradeep Kumar, Mordhwaj, Ravi Kumar
Synthesis and Spectral Studies of Some Bioactive Transition Metal Complexes of [bis-2-(4-Fluorophenyl)prop-2-enaln]ethane-1,2-diamine
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[5]. Kenan Buldurun
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[6]. Kenan Buldurun, Nevin Turan, Ahmet Savcı, Naki Çolak
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[7]. Kenan Buldurun, Nevin Turan, Abdulmelik Aras, Asim Mantarcı, Fikret Turkan, Ercan Bursal
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[8]. Tasneem Ibrahim Hussein, Musa Abduelrahman Ahmed, Ismail Adam Arbab, Awad Salim Ibrahim, Mohamed Al-Bratty, Hassan Ahmed Alhazmi, Asim Najmi
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How to cite


Turan, N.; Buldurun, K. Eur. J. Chem. 2018, 9(1), 22-29. doi:10.5155/eurjchem.9.1.22-29.1671
Turan, N.; Buldurun, K. Synthesis, characterization and antioxidant activity of Schiff base and its metal complexes with Fe(II), Mn(II), Zn(II), and Ru(II) ions: Catalytic activity of ruthenium(II) complex. Eur. J. Chem. 2018, 9(1), 22-29. doi:10.5155/eurjchem.9.1.22-29.1671
Turan, N., & Buldurun, K. (2018). Synthesis, characterization and antioxidant activity of Schiff base and its metal complexes with Fe(II), Mn(II), Zn(II), and Ru(II) ions: Catalytic activity of ruthenium(II) complex. European Journal of Chemistry, 9(1), 22-29. doi:10.5155/eurjchem.9.1.22-29.1671
Turan, Nevin, & Kenan Buldurun. "Synthesis, characterization and antioxidant activity of Schiff base and its metal complexes with Fe(II), Mn(II), Zn(II), and Ru(II) ions: Catalytic activity of ruthenium(II) complex." European Journal of Chemistry [Online], 9.1 (2018): 22-29. Web. 11 Aug. 2020
Turan, Nevin, AND Buldurun, Kenan. "Synthesis, characterization and antioxidant activity of Schiff base and its metal complexes with Fe(II), Mn(II), Zn(II), and Ru(II) ions: Catalytic activity of ruthenium(II) complex" European Journal of Chemistry [Online], Volume 9 Number 1 (31 March 2018)

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