European Journal of Chemistry 2020, 11(3), 250-254 | doi: https://doi.org/10.5155/eurjchem.11.3.250-254.2014 | Get rights and content






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Direct synthesis and crystal structure of a novel tetranuclear Co2IIIFe2III Schiff base complex


Eduard Nikolaevich Chygorin (1) orcid , Vladimir Nikolayevich Kokozay (2) orcid , Iryna Vasylivna Omelchenko (3) orcid , Julia Anatoliyivna Rusanova (4,*) orcid

(1) Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska str., Kyiv, 01601, Ukraine
(2) Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska str., Kyiv, 01601, Ukraine
(3) Scientific and Technological Center, Institute for Single Crystals, National Academy of Sciences of Ukraine, 60 Nauky ave., Kharkiv, 61072, Ukraine
(4) Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska str., Kyiv, 01601, Ukraine
(*) Corresponding Author

Received: 02 Aug 2020 | Revised: 25 Aug 2020 | Accepted: 26 Aug 2020 | Published: 30 Sep 2020 | Issue Date: September 2020

Abstract


The title compound, tetra(µ-2-3-(2-oxybenzylideneamino)-1-hydroxypropan-2-olato)-4-nitrophenolatedi-cobalt(III)-di-iron(III) dimethylsulfoxidehexasolvate, crystallizes in the monoclinic space group P21/c and represent the first example of heterometallic CoIII-FeIII complex with 3-((5-nitro-2-hydroxybenzylidene)amino)propane-1,2-diol/2-(((2,3-dihydroxy propyl)iminio)methyl)-4-nitrophenolate) - a hydroxyl rich Schiff base ligand which was obtained in situ. Crystal data for C52H74Cl2Co2Fe2N8O26S6 (= 1720.01 g/mol): monoclinic, space group P21/c (no. 14), a = 16.353(3) Å, b = 15.234(2) Å, c = 15.201(3) Å, β = 113.99(2)°, = 3460.0(12) Å3, Z = 2, T = 173(2) K, μ(MoKα) = 1.225 mm-1, Dcalc = 1.651 g/cm3, 14130 reflections measured (5.7° ≤ 2Θ ≤ 57.266°), 7748 unique (Rint = 0.1051, Rsigma = 0.2148) which were used in all calculations. The final R1 was 0.0914 (I > 2σ(I)) and wR2 was 0.2279 (all data). The metal ions have distorted octahedral coordination geometry and are joined in a tetranuclear {Co2Fe2(µ-O)6} core by O-bridging atoms from the ligand. There are numerous intermolecular interactions occurring between the components of the crystal: π-hole interaction between NO2···NO2 groups of the ligands, short S···S, O···O and C··· C interactions and weak and strong hydrogen bonds.


Keywords


Iron; Cobalt; Schiff base; Direct synthesis; Crystal structure; Heterometallic complexes

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DOI: 10.5155/eurjchem.11.3.250-254.2014

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Funding information


The Ministry of Education and Science of Ukraine (Project No. 19BF037–05), Ukraine.

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The Supplementary Material for this article can be found online at: Supplementary files

How to cite


Chygorin, E.; Kokozay, V.; Omelchenko, I.; Rusanova, J. Eur. J. Chem. 2020, 11(3), 250-254. doi:10.5155/eurjchem.11.3.250-254.2014
Chygorin, E.; Kokozay, V.; Omelchenko, I.; Rusanova, J. Direct synthesis and crystal structure of a novel tetranuclear Co2IIIFe2III Schiff base complex. Eur. J. Chem. 2020, 11(3), 250-254. doi:10.5155/eurjchem.11.3.250-254.2014
Chygorin, E., Kokozay, V., Omelchenko, I., & Rusanova, J. (2020). Direct synthesis and crystal structure of a novel tetranuclear Co2IIIFe2III Schiff base complex. European Journal of Chemistry, 11(3), 250-254. doi:10.5155/eurjchem.11.3.250-254.2014
Chygorin, Eduard, Vladimir Nikolayevich Kokozay, Iryna Vasylivna Omelchenko, & Julia Anatoliyivna Rusanova. "Direct synthesis and crystal structure of a novel tetranuclear Co2IIIFe2III Schiff base complex." European Journal of Chemistry [Online], 11.3 (2020): 250-254. Web. 28 Nov. 2020
Chygorin, Eduard, Kokozay, Vladimir, Omelchenko, Iryna, AND Rusanova, Julia. "Direct synthesis and crystal structure of a novel tetranuclear Co2IIIFe2III Schiff base complex" European Journal of Chemistry [Online], Volume 11 Number 3 (30 September 2020)

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DOI Link: https://doi.org/10.5155/eurjchem.11.3.250-254.2014

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