European Journal of Chemistry 2014, 5(2), 209-213 | doi: https://doi.org/10.5155/eurjchem.5.2.209-213.948 | Get rights and content






  OPEN ACCESS | PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Study of the adsorption of Co(II) on the chitosan-hydroxyapatite


Zhiguang Ma (1,*) , Mengchao Liu (2) , Jianghong Li (3) , Yinan Song (4) , Suwen Liu (5)

(1) College of Chemistry and Environmental Science, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Hebei University, Baoding 071002, China
(2) College of Chemistry and Environmental Science, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Hebei University, Baoding 071002, China
(3) College of Chemistry and Environmental Science, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Hebei University, Baoding 071002, China
(4) College of Chemistry and Environmental Science, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Hebei University, Baoding 071002, China
(5) College of Chemistry and Environmental Science, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, Hebei University, Baoding 071002, China
(*) Corresponding Author

Received: 18 Oct 2013 | Revised: 13 Dec 2013 | Accepted: 16 Dec 2013 | Published: 30 Jun 2014 | Issue Date: June 2014

Abstract


The adsorption of cobalt ions (Co2+) from aqueous solution onto chitosan-hydroxyapatite composite is investigated in this study. The effects of adsorption time, initial concentration, temperature, and pH are studied in details. Kinetics and thermodynamics of the adsorption of Co2+ onto the chitosan-hydroxyapatite are also investigated and the adsorption kinetics is found to follow the pseudo-second-order model with an activation energy (Ea) of 10.73 kJ/mol. Thermodynamic studies indicates that the adsorption follows the Langmuir adsorption equation. The value of entropy change (∆Sө) and enthalpy change (∆Hө) are found to be 83.50 and 18.09 kJ/mol, respectively. The Gibbs free energy change (∆Gө) is found to be negative at all fives temperatures, demonstrating that the adsorption process is spontaneous and endothermic.

 


Keywords


Cobalt; Kinetics; Chitosan; Adsorption; Hydroxyapatite; Thermodynamics

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.5.2.209-213.948

Links for Article


| | | | | | |

| | | | | | |

| |

Related Articles




Article Metrics

This Abstract was viewed 811 times | PDF Article downloaded 318 times

Funding information


National Natural Science Foundation of China (Project No: 61001051), the Natural Science Foundation of Hebei Province (Project No: F2011201102)

Citations

/


[1]. Hutaf Mustafa Baker, Raed Ahmad Ghanem
Study on removal behavior and separation efficiency of naturally occurring bentonite for sulfate from water by continuous column and batch methods
European Journal of Chemistry  6(1), 12, 2015
DOI: 10.5155/eurjchem.6.1.12-20.1129
/


References

[1]. Ouyang, H. F. J. Chin. Feed. 1999, 15, 28-29.

[2]. Li, Y. D.; Yuan, Z. H.; Li, H. Q. J. Bull. Chin. Agric. Sci. 2007, 23, 458-461.

[3]. Huang, W. H.; Su, H. D. Trans. Shenyang Ligong Univ. 2008, 27, 87-90.

[4]. Fonseca, M. G.; Oliveira, M. M.; Arakaki, L. N. H.; Espinola, J. G. P.; Airoldi, C. J. Colloid Interf. Sci. 2005, 285, 50-55.
http://dx.doi.org/10.1016/j.jcis.2004.11.031

[5]. Erdem, E.; Karapinar, N.; Donat, R. J. Colloid Interf. Sci. 2004, 280, 309-314.
http://dx.doi.org/10.1016/j.jcis.2004.08.028

[6]. Kara, M.; Yuzer, H.; Sabah, E.; Celik, M. S. Water Res. 2003, 37, 224-232.
http://dx.doi.org/10.1016/S0043-1354(02)00265-8

[7]. Yavuz, O.; Altunkaynak, Y.; Guzel, F. Water Res. 2003, 37, 948-952.
http://dx.doi.org/10.1016/S0043-1354(02)00409-8

[8]. Ma, Z. G.; Liu, S. W.; Zhang, H. L.; Liu, P.; Di, N. Int. J. Chem. 2011, 3, 116-120.
http://dx.doi.org/10.5539/ijc.v3n4p116

[9]. Ma, Z. G.; Di, N.; Zhang, F.; Gu, P. P.; Liu, S. W.; Liu, P. Int J. Chem. 2011, 3, 18-23.

[10]. Li, Q.; Xi, D. L. J. Environ. Prot. Chem. Ind. 2005, 25, 350-352.

[11]. Yang, M. P.; Li, G. B. J. Mater. Prot. 2003, 36, 37-38.

[12]. Chu K. H. J. Hazard. Mater. 2002, 90, 77-95.

[13]. Burke, A.; Yilmaz, E.; Hasirci, N. J. Appl. Polym. Sci. 2002, 84, 1185-1192.
http://dx.doi.org/10.1002/app.10416

[14]. Dhakal, R. P.; Inoue, K.; Yoshizuka, K. Solvent Extr. Ion Exc. 2005, 23, 204-208.

[15]. Liu, H. D.; Li, F. Z.; Zhao, X. Chin. J. Process Eng. 2008, 8, 42-47.

[16]. Li, B. Q.; Hu, Q. L.; Wang, M.; Shen, J. C. Chem. J. Chin. Univ. 2004, 10, 1949-1952.

[17]. Chiou, M. S.; Hsing, Y. L. J. Hazard. Mater. 2002, 93, 233-248.
http://dx.doi.org/10.1016/S0304-3894(02)00030-4

[18]. Qu, R. J.; Sun, C. M.; Wang, M. H. Hydrometallurgy 2009, 100, 65-71.
http://dx.doi.org/10.1016/j.hydromet.2009.10.008

[19]. Wan-Ngah, W. S.; Ghani, S. A.; Kamari, A. Biores. Technol. 2005, 96, 443-450.
http://dx.doi.org/10.1016/j.biortech.2004.05.022

[20]. Smiciklas, I.; Dimovic, I; Plecas, I.; Mitric, M. Water Res. 2006, 40, 2267-2274.
http://dx.doi.org/10.1016/j.watres.2006.04.031

[21]. Huang, Y. R.; Li, Z. J.; Wang, H. F.; Miao, Z. C.; Liu, J. G. Appl. Chem. 2009, 38, 1093-1097.

[22]. Sun, X. L.; Zeng, Q. X.; Feng, C. G. Acta. Phys. Chim. Sin. 2009, 25, 1951-1957.

[23]. Mohan, D.; Pittman, J. C. U. J. Hazard. Mater. 2006, 137, 762-811.
http://dx.doi.org/10.1016/j.jhazmat.2006.06.060

[24]. Sag, Y.; Aktay, Y. Biochem. Eng. J. 2002, 12, 143-153.
http://dx.doi.org/10.1016/S1369-703X(02)00068-2

[25]. Wan-Ngah, W. S.; Ab-Ghani, S.; Kamari, A. Bioresource Technol. 2005, 96, 443-450.
http://dx.doi.org/10.1016/j.biortech.2004.05.022

[26]. Huang, J. H. J. The Light Text. Ind. Fujian. 2005, 7, 15-17.

[27]. Langmuir, I. J. Am. Chem. Soc. 1916, 38, 2221-2295.
http://dx.doi.org/10.1021/ja02268a002

[28]. Vasconcelos, H. L.; Favere, V. T.; Goncalves, N. S.; Laranjeira, C. M. React. Funct. Polym. 2007, 67, 1052-1060.
http://dx.doi.org/10.1016/j.reactfunctpolym.2007.06.009

[29]. Atia A.; Donia A.M.; El-Boraey H.A. Sep. Purif. Technol. 2006, 48, 281-287.
http://dx.doi.org/10.1016/j.seppur.2005.07.034

[30]. Ozcan, A.; Ozcan, A. S.; Tunali, S.; Akar, T.; Kiran, I. J. Hazard. Mater. 2005, 124, 200-208.
http://dx.doi.org/10.1016/j.jhazmat.2005.05.007

[31]. Tang, J. Y.; Li, X.; Ying, H. J. J. Nanjing Univ. Technol. 2006, 28, 79-83.

How to cite


Ma, Z.; Liu, M.; Li, J.; Song, Y.; Liu, S. Eur. J. Chem. 2014, 5(2), 209-213. doi:10.5155/eurjchem.5.2.209-213.948
Ma, Z.; Liu, M.; Li, J.; Song, Y.; Liu, S. Study of the adsorption of Co(II) on the chitosan-hydroxyapatite. Eur. J. Chem. 2014, 5(2), 209-213. doi:10.5155/eurjchem.5.2.209-213.948
Ma, Z., Liu, M., Li, J., Song, Y., & Liu, S. (2014). Study of the adsorption of Co(II) on the chitosan-hydroxyapatite. European Journal of Chemistry, 5(2), 209-213. doi:10.5155/eurjchem.5.2.209-213.948
Ma, Zhiguang, Mengchao Liu, Jianghong Li, Yinan Song, & Suwen Liu. "Study of the adsorption of Co(II) on the chitosan-hydroxyapatite." European Journal of Chemistry [Online], 5.2 (2014): 209-213. Web. 1 Dec. 2020
Ma, Zhiguang, Liu, Mengchao, Li, Jianghong, Song, Yinan, AND Liu, Suwen. "Study of the adsorption of Co(II) on the chitosan-hydroxyapatite" European Journal of Chemistry [Online], Volume 5 Number 2 (30 June 2014)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item


DOI Link: https://doi.org/10.5155/eurjchem.5.2.209-213.948

| | | | | | | |

| | | | | |

Save to Zotero Save to Mendeley



European Journal of Chemistry 2014, 5(2), 209-213 | doi: https://doi.org/10.5155/eurjchem.5.2.209-213.948 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)




© Copyright 2010 - 2020  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2020 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.