European Journal of Chemistry

Physicochemical studies and biological activity of mixed ligand complexes involving bivalent transition metals with a novel Schiff base and glycine as a representative amino acid

Article Sidebar

PDF
Published: Jun 30, 2014
DOI: https://doi.org/10.5155/eurjchem.5.2.328-333.1025
Keywords:
Glycine, Schiff base, Amino acid, Electronic spectra, Antibacterial activity, Mixed-ligand complexes
Section
Research Article
Issue
Vol. 5 No. 2 (2014): June 2014
Dates
Received 2014-01-29
Accepted 2014-02-12
Published 2014-06-30


Main Article Content

Abeer Taha Abedel Karim
Department of Chemistry, Faculty of Science, Cairo University, Cairo, 12613 Egypt
Ahmed Abdou El-Sherif
Department of Chemistry, Faculty of Arts and Science, Northern Borders University, Rafha, 156, Kingdom of Saudi Arabia

Abstract

The mixed-ligand complexes of Co(II), Ni(II), Mn(II) and Zn(II) with 2-aminomethyl thiophenyl-4-bromosalicylaldehyde Schiff base (ATS) and glycine as a representative example of amino acids have been achieved. These complexes namely [Ni(ATS)(Gly)] (1), [Co(ATS)(Gly)].H2O (2) [Mn(ATS)(Gly)].2H2O (3), and [Zn(ATS)(Gly)] (4) were characterized by elemental, molar conductance, infrared, magnetic moment, and electronic spectra. ATS behaves as mononegatively charged bidentate ligand with coordination through azomethine nitrogen and phenolate oxygen groups while glycine acts as monobasic bidentate ligand is coordinated via amino and ionized carboxylate group after deprotonation. The low molar conductance values suggest the non-electrolytic nature of these complexes. The magnetic and spectral data indicates a square planar geometry for Ni(II) complex, tetrahedral geometry for Zn(II) and octahedral geometry for both Mn(II) and Co(II) complexes. The isolated chelates have been screened for their antimicrobial activity.


icon graph This Abstract was viewed 2200 times | icon graph Article PDF downloaded 892 times

How to Cite
(1)
Karim, A. T. A.; El-Sherif, A. A. Physicochemical Studies and Biological Activity of Mixed Ligand Complexes Involving Bivalent Transition Metals With a Novel Schiff Base and Glycine As a Representative Amino Acid. Eur. J. Chem. 2014, 5, 328-333.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Zimmermann, K. H. An Introduction to Protein Informatics, Kluwer Academic Publishers, London, 2003.
http://dx.doi.org/10.1007/978-1-4419-9210-9

[2]. Klement, R.; Stock, F.; Elias, H.; Paulus, H.; Pelikan, P.; Valko, M.; Mazur, M. Polyhedron 1999, 18, 3617-3628.
http://dx.doi.org/10.1016/S0277-5387(99)00291-0

[3]. Marchettic, F.; Pettinari, C.; Pettinari, R.; Cingolani, A.; Leanesi, D.; Lorenotti, A. Polyhedron 1999, 18, 3041-3050.
http://dx.doi.org/10.1016/S0277-5387(99)00230-2

[4]. Zhang, C.; Sun, J.; Kong, X.; Zhao, C. J. Coord. Chem. 2000, 50, 353-361.
http://dx.doi.org/10.1080/00958970008054940

[5]. Ramappa, P. G. J. Indian Chem. Soc. 1999, 76, 235-238.

[6]. Amirnasr, M.; Schenk, K. J.; Gorji, A.; Vafazadeh, R. Polyhedron 2001, 20, 695-702.
http://dx.doi.org/10.1016/S0378-3758(01)00095-7

[7]. Cmi, R.; Moore, S. J.; Marzilli, L. G. Inorg. Chem. 1998, 37, 6890-6897.
http://dx.doi.org/10.1021/ic980666i

[8]. Polson, S. M.; Cini, R.; Pifferi, C.; Marzilli, L. G. Inorg. Chem. 1997, 36, 314-322.
http://dx.doi.org/10.1021/ic961105z

[9]. Hirota, S.; Kosugi, E.; Marzilli, L. G.; Yamauchi, O. Inorg. Chim. Acta 1998, 275, 90-97.
http://dx.doi.org/10.1016/S0020-1693(97)06112-4

[10]. Martell, A. E.; Sawyer, D. T. Oxygen Complexes and Oxygen Activation by Transition Metals, Plenum Press, New York, 1988.
http://dx.doi.org/10.1007/978-1-4613-0955-0

[11]. Henson, N. J.; Hay, P. J.; Redondo, A. Inorg. Chem. 1999, 38, 1618-1626.
http://dx.doi.org/10.1021/ic9813056

[12]. Gurian, P. L.; Cheatham, L. K.; Ziller, J. W.; Barron, A. R. J. Chem. Soc. Dalton Trans. 1991, 1449-1456.
http://dx.doi.org/10.1039/dt9910001449

[13]. Labisbal, E.; Garcia-Vazquez, J. A.; Romero, J.; Picos, S.; Sousa, A. Polyhedron 1995, 14, 663-670.
http://dx.doi.org/10.1016/0277-5387(94)00292-M

[14]. Zolezzi, S.; Decinti, A.; Spodine, E. Polyhedron 1999, 18, 897-904.
http://dx.doi.org/10.1016/S0277-5387(98)00376-3

[15]. Pasini, A.; Demartin, F.; Piovesana, O.; Chiari, B.; Cinti, A.; Crispu, O. J. Chem. Soc. Dalton Trans. 2000, 3467-3472.
http://dx.doi.org/10.1039/b003825n

[16]. Sangeetha, N. R.; Pal, S. Polyhedron 2000, 19, 1593-1600.
http://dx.doi.org/10.1016/S0277-5387(00)00433-2

[17]. Jouad, E. l.; Riou, A.; Allain, M.; Khan, M. A.; Bouet, G. M. Polyhedron 2001, 20, 67-74.
http://dx.doi.org/10.1016/S0277-5387(00)00598-2

[18]. Nath, M.; Pokharia, S.; Yadav, R. Coord. Chem. Rev. 2001, 215, 99-107.
http://dx.doi.org/10.1016/S0010-8545(00)00404-5

[19]. Sharghi, H.; Nasser, M. A. Bull. Chem. Soc. (Jpn) 2003, 76, 137-142.
http://dx.doi.org/10.1246/bcsj.76.137

[20]. Gao, W. T.; Zheng, Z. Molecules 2001, 7, 511-516.
http://dx.doi.org/10.3390/70700511

[21]. Canpolat, E.; Kaya, M. J. Coord. Chem. 2004, 57, 127-134.

[22]. Fan, Y.; Bi, C.; Li, J. Synth. React. Inorg. Met. Org. Chem. 2003, 33, 137-145.
http://dx.doi.org/10.1081/SIM-120016878

[23]. Canpolat, E.; Kaya, M.; Yazici, A. Spectrosc. Lett. 2005, 38, 35-45.
http://dx.doi.org/10.1081/SL-200044740

[24]. Konstantinivi, S. S.; Radovanovi, B. C.; Caki, Z.; Vasic, V. J. Ser. Chem. Soc. 2003, 68, 641-648.
http://dx.doi.org/10.2298/JSC0309641K

[25]. Jeragh, B.; Al-Wahaib, D.; El-Sherif, A. A.; El-Dissouky, A. J. Chem. Eng. Data 2007, 52, 1609-1614.
http://dx.doi.org/10.1021/je600586e

[26]. El-Sherif, A. A. J. Solution Chem. 2006, 35, 1287-1301.
http://dx.doi.org/10.1007/s10953-006-9062-9

[27]. Mohamed, M. M. A.; El-Sherif, A. A. J. Solution Chem. 2010, 39, 639-653.
http://dx.doi.org/10.1007/s10953-010-9535-8

[28]. El-Sherif, A. A.; Shoukry, M. M. J. Coord. Chem. 2005, 58(16), 1401-1415.
http://dx.doi.org/10.1080/00958970500055435

[29]. El-Sherif, A. A.; Shoukry, M. M. Spectrochim. Acta A 2007, 66, 691-700.
http://dx.doi.org/10.1016/j.saa.2006.04.013

[30]. El-Sherif, A. A.; Shoukry, M. M. Inorg. Chim. Acta 2007, 360, 473-487.
http://dx.doi.org/10.1016/j.ica.2006.07.108

[31]. El-Sherif, A. A.; Eldebss, T. M. Spectrochim. Acta A 2011, 79, 1803-1814.
http://dx.doi.org/10.1016/j.saa.2011.05.062

[32]. Pfaller, M. A.; Burmeister, L.; Bartlett, M. A.; Rinaldi, M. G. J. Clin. Microbiol. 1988, 26, 1437-1441.

[33]. Liebowitz, L. D.; Ashbee, H. R.; Evans, E. G. V.; Chong, Y.; Mallatova, N.; Zaidi, M.; Gibbs, D. Microbiol. Infet. Dis. 2001, 24, 27-33.
http://dx.doi.org/10.1016/S0732-8893(01)00243-7

[34]. Bauer, A. W.; Kirby, W. M.; Sherris, C.; Turck, M. J. Am. Clin. Path. 1996, 45, 493-499.

[35]. El-Sherif, A. A.; Shehata, M. R.; Shoukry, M. M.; Barakat, M. H. J. Spectrochim. Acta A 2012, 96, 889-897.
http://dx.doi.org/10.1016/j.saa.2012.07.047

[36]. Kulkarni, A.; Patil, S. A.; Badami, P. S. Eur. J. Med. Chem. 2009, 44, 2904-2912.
http://dx.doi.org/10.1016/j.ejmech.2008.12.012

[37]. Sarkar, S.; Dey, K. Spectrochim. Acta A 2005, 62, 383-393.
http://dx.doi.org/10.1016/j.saa.2005.01.005

[38]. West, D. X.; Nassar, A. A. Trans. Met. Chem. 1998, 23, 321-326.
http://dx.doi.org/10.1023/A:1006957325074

[39]. Bagihalli, G. B.; Avaji, P. G.; Patil, S. A.; Badami, P. S. Eur. J. Med. Chem. 2008, 43, 2639-2649.
http://dx.doi.org/10.1016/j.ejmech.2008.02.013

[40]. Gronowitz, S.; Katritsky, A. R.; Reavill, R. E. J. Am. Chem. Soc. 1964, 86, 3881-3882.
http://dx.doi.org/10.1021/ja01072a062

[41]. El-Sherif, A. A.; Aljahdali, M. S.; Hilal, R. H. Eur. J. Chem. 2013, 4(4), 370-378.
http://dx.doi.org/10.5155/eurjchem.4.4.370-378.803

[42]. Nakamoto, K.; Infrared Raman Spectra of Inorganic and Coordination Compounds, Third ed., John Wiley and Sons, New York, 1992.

[43]. Decon, G. B.; Philips, R. J. Coord. Rev. 1980, 33, 227-250.
http://dx.doi.org/10.1016/S0010-8545(00)80455-5

[44]. Aljahdali, M. S. Spectrochim. Acta A 2013, 112, 364-376
http://dx.doi.org/10.1016/j.saa.2013.03.057

[45]. El-Sherif, A. A.; Shoukry, M. M.; Abobakr, L. O. J. Spectrochim. Acta A 2013, 112, 290-300
http://dx.doi.org/10.1016/j.saa.2013.04.023

[46]. Stefov, V.; Petrusevski, V. M.; Soptrajanov, B. J. Mol. Struct. 1993, 293, 97-100.
http://dx.doi.org/10.1016/0022-2860(93)80024-P

[47]. Aljahdali, M.; El-Sherif, A. A. Inorg. Chim. Acta 2013, 407, 58-68.
http://dx.doi.org/10.1016/j.ica.2013.06.040

[48]. Aljahdali, M. S. Eur. J. Chem. 2013, 4(4), 434-443.
http://dx.doi.org/10.5155/eurjchem.4.4.434-443.838

[49]. El-Sherif, A. A.; Shoukry, M. M.; Abd-Elgawad, M. M. A. J. Spectrochim. Acta A 2012, 98, 307-321.
http://dx.doi.org/10.1016/j.saa.2012.08.034

[50]. Dingle, R. Inorg. Chem. 1971, 10, 1141-1144.
http://dx.doi.org/10.1021/ic50100a007

[51]. Shrivastav, A.; Kishore, N.; Singh, S. M. Biometals 2003, 16(2), 311-320.
http://dx.doi.org/10.1023/A:1020611428001

[52]. Khalil, S. M. E.; El-Shafiy, H. F. O. Synth. React. Inorg. Met. Org. Chem. 2000, 30, 1817-1826.
http://dx.doi.org/10.1080/00945710009351871

[53]. Schlapp, R.; Penney, W. G. Phys. Rev. 1932, 42, 666-686.
http://dx.doi.org/10.1103/PhysRev.42.666

[54]. Figgis, B. N.; Nyhlom, R. S. J. Chem. Soc. 1958, 4190-4200.
http://dx.doi.org/10.1039/jr9580004190

[55]. Salib, K. A. R.; Saleh, A. A.; Abu El-Wafa, S.; El-Shafiy, H. F. O. J. Coord. Chem. 2003, 56(4), 283-291.
http://dx.doi.org/10.1080/0095897031000069021

[56]. El-Sherif, A. A. J. Solution Chem. 2010, 39, 1562-1581.
http://dx.doi.org/10.1007/s10953-010-9593-y

[57]. Bailar, J. C.; Emeleus, H. J.; Nyhlom, R.; Trotmon-Dickenson, A. F., Comprehensive Inorg. Chem., Pergamon Press, New York 1975, 3, pp. 1048, 1049, 1089, 1093, 1153.

[58]. Mishra, R. C.; Mohapatra, B. K.; Panda, D. J. Indian Chem. Soc. 1983, 60, 782-790.

[59]. Sanmartin, J.; Bermejo, M. R.; Deibe, A. M. G.; Maneiro, M.; Lage, C.; Filho, A. J. C. Polyhedron 2000, 19, 185-192.
http://dx.doi.org/10.1016/S0277-5387(99)00341-1

[60]. Krzyminiewska, V. P.; Litkowska, H.; Paryzek, W. R. Monatsh. Chem. 1999, 130, 243-249.

[61]. Melnik, M.; Gyoryova, K.; Skorsepa, J.; Holloway, C. E. J. Coord. Chem. 1995, 35, 179-185.
http://dx.doi.org/10.1080/00958979508024038

[62]. British Pharmacopia, Her Majesty's Stationery Office, London, UK, 1998, p. 1040.

[63]. Cakir, S.; Bicer, E.; Odabasoglu, M.; Albayrak, C. J. Braz. Chem. Soc. 2005, 4, 711-717.
http://dx.doi.org/10.1590/S0103-50532005000500005

[64]. Koch, A. L. Clin. Microbiol. Rev. 2003, 16, 673-678.
http://dx.doi.org/10.1128/CMR.16.4.673-687.2003

[65]. Chohan, Z. H.; Scozzafava, A.; Supran, C. T. J. Enzym Inhib. Med. Ch. 2003, 17, 261-269.
http://dx.doi.org/10.1080/1475636021000006261

[66]. Chohan, Z. H.; Khan, K. M.; Supuran, C. T. Appl. Organomet. Chem. 2004, 18, 305-310.
http://dx.doi.org/10.1002/aoc.620

Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).