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Synthesis and recognition properties of colorimetric anion chemosensor bearing 2,4-dinitrophenylhydrazone and indene-1,3-dione moieties
Fatma Aydın (1,*)
(1) Çanakkale Onsekiz Mart University, Department of Chemistry, 17100, Çanakkale, Turkey
(*) Corresponding Author
Received: 06 Feb 2014 | Accepted: 02 Mar 2014 | Published: 30 Jun 2014 | Issue Date: June 2014
Abstract
A new receptor named, 2-(2-(2,4-dinitrophenyl)hydrazono)2H-indene-1,3-dione, used as a colorimetric sensor based on 2,4-dinitrophenylhydrazone derivative of ninhydrin was synthesized by simple step with good yields and characterized by IR and 1H, 13C NMR and MS spectroscopic techniques. The anion recognition properties were studied by UV-Vis spectroscopic technique. The results showed that the receptor had a higher affinity to F-, CN-, H2PO4-, CH3COO- and OH-, but showed no evident binding with Cl-, Br- and I-. Binding of the reseptor to anions such as CN-, AcO-, F-, H2PO4- and OH-exhibited an obvious color change from greenish yellow to purplish blue, which was possible to observe by the naked eye.
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DOI: 10.5155/eurjchem.5.2.370-373.1032
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Funding information
Çanakkale Onsekiz Mart University Research Fund (Project No: BAP-2010-57), Çanakkale Onsekiz Mart University, Çanakkale, Turkey
Citations
[1]. Vetriarasu Venkatesan, S. K. Ashok Kumar, Suban K. Sahoo
Spectrophotometric and RGB performances of a new tetraphenylcyclopenta-derived Schiff base for the quantification of cyanide ions
Analytical Methods 11(8), 1137, 2019
DOI: 10.1039/C8AY02401D
[2]. P. Karuppusamy, S. Sarveswari
A 4-phenyl thiophene appended 2,4-dinitrophenylhydrazone as a colorimetric chemosensor for selective detection of cyanide ion and its application for real-life samples
Journal of Molecular Structure 1248, 131494, 2022
DOI: 10.1016/j.molstruc.2021.131494
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DOI Link: https://doi.org/10.5155/eurjchem.5.2.370-373.1032
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European Journal of Chemistry 2014, 5(2), 370-373 | doi: https://doi.org/10.5155/eurjchem.5.2.370-373.1032 | Get rights and content
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