European Journal of Chemistry 2014, 5(4), 607-611 | doi: https://doi.org/10.5155/eurjchem.5.4.607-611.1102 | Get rights and content

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Ultra-violet spectra studies of photodegradation of PVC films in presence of Fe(III) chelate complex


Emad Yousif (1) , Raghad Haddad (2) , Ameer Abbas Ameer (3,*) , Yip-Foo Win (4)

(1) Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, 64021, Iraq
(2) Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, 64021, Iraq
(3) College of Engineering and Computing, Al-Ghurair University, Dubai, United Arab Emirates
(4) Department of Chemical Science, Faculty of Science, University Tunku Abdul Rahman, Perak Campus, Jalan University, Bandar Barat, 31900 Kampar, Perak, Malaysia
(*) Corresponding Author

Received: 09 Jun 2014 | Revised: 07 Jul 2014 | Accepted: 10 Jul 2014 | Published: 31 Dec 2014 | Issue Date: December 2014

Abstract


A complex of Fe(III) with 4-amino-5-(pyridyl)-4H-1,2,4-triazole-3-thiol was prepared and evaluated as a photodegradation for rigid poly(vinyl chloride) (PVC). Polyvinyl chloride dissolved with Fe(III) complex in THF solvent to form PVC films of 5% (40 μm) thickness containing different concentrations (0.01, 0.02, 0.03, 0.04 and 0.05 g) of the complex by weight. These different samples were produced by the casting method from the solvent. The photodegradation of films was investigated using UV-visible spectra. The photostabilization activity of these compounds was determined by calculating the photodecomposition rate constant (Kd) for modified PVC films against a blank.


Keywords


PVC; Triazole; UV-light; Fe(III) complex; Photochemistry; Photodegradation

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DOI: 10.5155/eurjchem.5.4.607-611.1102

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Funding information


AAl-Nahrain University, Al-Ghurair University and University Tunku Abdul Rahman

Citations

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DOI: 10.1016/j.jece.2020.104364
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[2]. R. V. Linko, N. A. Polyanskaya, M. A. Ryabov, V. S. Sergienko, P. V. Strashnov, V. V. Davydov, G. M. Drogova
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Russian Journal of Coordination Chemistry  45(1), 1, 2019
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[3]. Ibragimdjan Аbdugafurov Azizovich, Fazliddin Qirgizov Bakhtiyarovich, Ilhom Оrtikov Sobirovich
Synthesis of 1,2,3-triazole derivatives based on propargyl ester of a saturated single-basic carbonic acid and para-azidobenzoic acid
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DOI: 10.5155/eurjchem.12.1.13-17.2035
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[4]. Emad Yousif, Ali Hasan, Gamal El-Hiti
Spectroscopic, Physical and Topography of Photochemical Process of PVC Films in the Presence of Schiff Base Metal Complexes
Polymers  8(6), 204, 2016
DOI: 10.3390/polym8060204
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How to cite


Yousif, E.; Haddad, R.; Ameer, A.; Win, Y. Eur. J. Chem. 2014, 5(4), 607-611. doi:10.5155/eurjchem.5.4.607-611.1102
Yousif, E.; Haddad, R.; Ameer, A.; Win, Y. Ultra-violet spectra studies of photodegradation of PVC films in presence of Fe(III) chelate complex. Eur. J. Chem. 2014, 5(4), 607-611. doi:10.5155/eurjchem.5.4.607-611.1102
Yousif, E., Haddad, R., Ameer, A., & Win, Y. (2014). Ultra-violet spectra studies of photodegradation of PVC films in presence of Fe(III) chelate complex. European Journal of Chemistry, 5(4), 607-611. doi:10.5155/eurjchem.5.4.607-611.1102
Yousif, Emad, Raghad Haddad, Ameer Abbas Ameer, & Yip-Foo Win. "Ultra-violet spectra studies of photodegradation of PVC films in presence of Fe(III) chelate complex." European Journal of Chemistry [Online], 5.4 (2014): 607-611. Web. 22 Oct. 2021
Yousif, Emad, Haddad, Raghad, Ameer, Ameer, AND Win, Yip-Foo. "Ultra-violet spectra studies of photodegradation of PVC films in presence of Fe(III) chelate complex" European Journal of Chemistry [Online], Volume 5 Number 4 (31 December 2014)

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