European Journal of Chemistry

Ultra-violet spectra studies of photodegradation of PVC films in presence of Fe(III) chelate complex

Article Sidebar

PDF
Published: Dec 31, 2014
DOI: https://doi.org/10.5155/eurjchem.5.4.607-611.1102
Keywords:
PVC, Triazole, UV-light, Fe(III) complex, Photochemistry, Photodegradation
Section
Research Article
Issue
Vol. 5 No. 4 (2014): December 2014
Dates
Received 2014-06-09
Accepted 2014-07-10
Published 2014-12-31


Main Article Content

Emad Yousif
Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, 64021, Iraq
Raghad Haddad
Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, 64021, Iraq
Ameer Abbas Ameer
College of Engineering and Computing, Al-Ghurair University, Dubai, United Arab Emirates
Yip-Foo Win
Department of Chemical Science, Faculty of Science, University Tunku Abdul Rahman, Perak Campus, Jalan University, Bandar Barat, 31900 Kampar, Perak, Malaysia

Abstract

A complex of Fe(III) with 4-amino-5-(pyridyl)-4H-1,2,4-triazole-3-thiol was prepared and evaluated as a photodegradation for rigid poly(vinyl chloride) (PVC). Polyvinyl chloride dissolved with Fe(III) complex in THF solvent to form PVC films of 5% (40 μm) thickness containing different concentrations (0.01, 0.02, 0.03, 0.04 and 0.05 g) of the complex by weight. These different samples were produced by the casting method from the solvent. The photodegradation of films was investigated using UV-visible spectra. The photostabilization activity of these compounds was determined by calculating the photodecomposition rate constant (Kd) for modified PVC films against a blank.


icon graph This Abstract was viewed 1516 times | icon graph Article PDF downloaded 928 times

How to Cite
(1)
Yousif, E.; Haddad, R.; Ameer, A. A.; Win, Y.-F. Ultra-Violet Spectra Studies of Photodegradation of PVC Films in Presence of Fe(III) Chelate Complex. Eur. J. Chem. 2014, 5, 607-611.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Allsopp, M.; Vianello, G. Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH. Weinheim, 2012.

[2]. Yousif, E. Photostabilization of thermoplastic polymers, Lambert Academic Publishing, Germany, 2012.

[3]. Pimentel, R.; Ferraria, A.; Botelho, A. Polym. Test. 2008, 27, 743-751.
http://dx.doi.org/10.1016/j.polymertesting.2008.05.009

[4]. Andrady, A.; Hamid, S.; Hu, X.; Torikai, A. J. Photoch. Photobio. B 1998, 46, 96-103.
http://dx.doi.org/10.1016/S1011-1344(98)00188-2

[5]. Hamid, H. Handbook of Polymer Degradation, Environmental Science and Pollution, Marcel Dekker Inc., New York, 2000.

[6]. Rabek, F. Mechanisms of photophysical and photochemical reactions in polymer: Theory and practical application, John Wiley and Sons, New York, 1987.

[7]. Bottino, A.; Cinquegrani, R.; Di Pasquale, G.; Leonardi, L.; Pollicino, A. Polym. Test. 2003, 12, 405-411.

[8]. Scott, G. Polym. Degrad. Stabil. 2000, 68, 1-7.
http://dx.doi.org/10.1016/S0141-3910(99)00182-2

[9]. Valkoa, L.; Kleinb, E.; Kovarikb, P.; Simonb, P. Eur. Polym. J. 2001, 37, 1123-1133.
http://dx.doi.org/10.1016/S0014-3057(00)00239-1

[10]. Ayako, T.; Hirose, H. Polym. Degrad. Stabil. 1999, 63, 441-452.
http://dx.doi.org/10.1016/S0141-3910(98)00125-6

[11]. Grassie, N.; Scott, G. Polymer Degradation and Stabilization, Cambridge University Press, London, 1985.

[12]. Galdi, A.; Foltis, P.; Shah, A. US patent. Application, 2010, 2010-118415.

[13]. Pospisil, J.; Pilar, J.; Billingham, C.; Marek, A.; Horak, Z.; Nespurek, S. Polym. Degrad. Stabil. 2006, 91, 417-422.
http://dx.doi.org/10.1016/j.polymdegradstab.2005.01.049

[14]. Bojinov, B.; Grabchev, K. Polym. Photochem. Photobiol. 2005, 172, 308-315.
http://dx.doi.org/10.1016/j.jphotochem.2004.12.020

[15]. Goldshtein, J.; Margel, S. Colloid Polym. Sci. 2011, 289, 1863-1874.
http://dx.doi.org/10.1007/s00396-011-2505-x

[16]. Yousif, E.; Salimon, J.; Salih, N. J. Appl. Polym. Sci. 2012, 125, 1922-1927.
http://dx.doi.org/10.1002/app.36307

[17]. Yousif, E.; Salimon, J.; Salih, N. J. Saudi. Chem. Soc. 2011, 16(3), 299-306.

[18]. Yousif, E.; Haddad, R. SpringerPlus 2013, 2, 398-460.
http://dx.doi.org/10.1186/2193-1801-2-398

[19]. Yousif, E.; Haddad, R.; Ahmed, A. Photodegradation and Photostabilization of Polystyrene, Lambert Academic Publishing, Germany, 2013.

[20]. Haddad, R.; Yousif, E.; Ahmed, A. SpringerPlus 2013, 2, 510-516.
http://dx.doi.org/10.1186/2193-1801-2-510

[21]. Yousif, E.; Salih, N.; Salimon, J. J. Appl. Poly. Sci. 2011, 120, 2207-2214.
http://dx.doi.org/10.1002/app.33463

[22]. Yousif, E.; Salimon, J.; Salih, N. Malaysian J. Anal. Sci. 2011, 15(1), 81-92.

[23]. Yousif, E.; Aliwi, S.; Ameer, A.; Ukal, J. Turk. J. Chem. 2009, 33, 339-410.

[24]. Mori, F.; Koyama, M.; Oki, Y. Angew. Makromol. Chem. 1979, 75, 113-122.
http://dx.doi.org/10.1002/apmc.1979.050750108

[25]. Rabie, S.; Ahmed, A.; Sabaa, M.; El-Ghaffar, M. J. Ind. Eng. Chem. 2013, 19, 1869-1878.
http://dx.doi.org/10.1016/j.jiec.2013.02.033

[26]. Cooray, B.; Scott, G. J. Eur. Polym. 1980, 169(16), 177-189.

[27]. Naif, O.; Salih, H. Tikrit J. Pure Sci. 2011, 16(4), 1813-1662.

[28]. Rabek, J.; Sanetra, J. Macromol. 1986, 19, 1679-1684.
http://dx.doi.org/10.1021/ma00160a034

[29]. Yousif, E.; Salimon, J.; Salih, N. Arabian J. Chem. 2014, 7, 306-311.
http://dx.doi.org/10.1016/j.arabjc.2010.11.003

[30]. Rabek, F.; Polymer photodegradation of polymers: Physical characteristic and applications, Springer-Verlag. Berlin, 1996.
http://dx.doi.org/10.1007/978-3-642-80090-0

[31]. Kiatkamjornwong, S.; Sonsuk, M.; Wittayapichet, S.; Prasassarakich, P.; Vejjanukroh, P. Polym. Degrad. Stab. 1999, 66, 323-334.
http://dx.doi.org/10.1016/S0141-3910(99)00082-8

[32]. Abdelbagi, A. Sudan J. Basic Sci. 2008, 15, 39-50.

[33]. Al-Jibouri, M.; Al-Ameri, S.; Al-Jibouri, W.; Al-Souz, M. J. Assoc. Arab Univ. Basic Appl. Sci. 2013, 14, 67-74.

Supporting Agencies

AAl-Nahrain University, Al-Ghurair University and University Tunku Abdul Rahman
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).