European Journal of Chemistry

Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes

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Published: Mar 31, 2015
DOI: https://doi.org/10.5155/eurjchem.6.1.8-11.1127
Keywords:
Zinc complex, Ethanol amine, Schiff base ligand, Cadmium complex, Hexadentate ligand, Macroacyclic ligand
Section
Research Article
Issue
Vol. 6 No. 1 (2015): March 2015
Dates
Received 2014-07-31
Accepted 2014-09-14
Published 2015-03-31


Main Article Content

Reza Golbedaghi
Chemistry Department, Payame Noor University, Tehran, 19395, Iran
Majid Rezaeivala
Department of Chemical Engineering, Hamedan University of Technology, Hamedan,65155, Iran
Leila Albeheshti
Chemistry Department, Payame Noor University, Tehran, 19395, Iran

Abstract

Five new complexes [CdH2L(NO3)]ClO4 (1), [ZnH2L](ClO4)2 (2), [NiH2L](ClO4)2 (3), [CuH2L](ClO4)2 (4) and [CoH2L](ClO4)2 (5) were prepared by reaction of a new Schiff base ligand and different metal ions in 1:1 ratios. The new Schiff base ligand H2L was synthesized by reaction of 2-(4-(2-formylphenoxy)butoxy) benzaldehyde and ethanol amine and characterized with IR, 1H and 13C NMR and elemental analysis. The synthesized complexes were also characterized by IR and elemental analysis in all cases and 1H, 13C NMR and COSY in the case of [CdH2L(NO3)]ClO4 and [ZnH2L](ClO4)2 complexes.


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Golbedaghi, R.; Rezaeivala, M.; Albeheshti, L. Synthesis and Spectroscopic Investigation of a New Hexadentate Schiff Base Ligand With N2O4 Donor Atoms and Related Metal Complexes. Eur. J. Chem. 2015, 6, 8-11.

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Payame Noor University, Tehran, 19395, Iran
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