European Journal of Chemistry 2015, 6(1), 8-11 | doi: https://doi.org/10.5155/eurjchem.6.1.8-11.1127 | Get rights and content

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Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes


Reza Golbedaghi (1,*) , Majid Rezaeivala (2) , Leila Albeheshti (3)

(1) Chemistry Department, Payame Noor University, Tehran, 19395, Iran
(2) Department of Chemical Engineering, Hamedan University of Technology, Hamedan,65155, Iran
(3) Chemistry Department, Payame Noor University, Tehran, 19395, Iran
(*) Corresponding Author

Received: 31 Jul 2014 | Revised: 04 Sep 2014 | Accepted: 14 Sep 2014 | Published: 31 Mar 2015 | Issue Date: March 2015

Abstract


Five new complexes [CdH2L(NO3)]ClO4 (1), [ZnH2L](ClO4)2 (2), [NiH2L](ClO4)2 (3), [CuH2L](ClO4)2 (4) and [CoH2L](ClO4)2 (5) were prepared by reaction of a new Schiff base ligand and different metal ions in 1:1 ratios. The new Schiff base ligand H2L was synthesized by reaction of 2-(4-(2-formylphenoxy)butoxy) benzaldehyde and ethanol amine and characterized with IR, 1H and 13C NMR and elemental analysis. The synthesized complexes were also characterized by IR and elemental analysis in all cases and 1H, 13C NMR and COSY in the case of [CdH2L(NO3)]ClO4 and [ZnH2L](ClO4)2 complexes.


Keywords


Zinc complex; Ethanol amine; Schiff base ligand; Cadmium complex; Hexadentate ligand; Macroacyclic ligand

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DOI: 10.5155/eurjchem.6.1.8-11.1127

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Funding information


Payame Noor University, Tehran, 19395, Iran

References


[1]. Bernhardt, P. V.; Lawrence, G. A. Coord. Chem. Rev. 1990, 104, 297-343.
http://dx.doi.org/10.1016/0010-8545(90)80045-U

[2]. Kaden, T. A. Pure Appl. Chem. 1993, 65, 1477-1483.
http://dx.doi.org/10.1351/pac199365071477

[3]. Wainwright, K. P. Coord. Chem. Rev. 1997, 166, 35-90.
http://dx.doi.org/10.1016/S0010-8545(97)00003-9

[4]. Costamagna, J.; Ferraudi, G.; Matsuhiro, B.; Campos-Valette, M.; Canales, J.; Villagran, M.; Vargas, J.; Aguirre, M. J. Coord. Chem. Rev. 2000, 196, 125-164.
http://dx.doi.org/10.1016/S0010-8545(99)00165-4

[5]. Wainwright, K. P. Inorg. Chem. 2001, 5, 293-298.

[6]. Haines, R. I. Rev.Inorg. Chem. 2002, 21, 165-169.

[7]. Frausto da Silva, J. J. R.; Williams, R. J. P. TheBiological Chemistry of the Elements, Oxford University Press, Oxford, 1991.

[8]. Parkin, G. Chem. Rev. 2004, 104, 699-768.
http://dx.doi.org/10.1021/cr0206263

[9]. Waalkes, M. P. J. Inorg. Biochem. 2000, 79, 241-244.
http://dx.doi.org/10.1016/S0162-0134(00)00009-X

[10]. Waalkes, M. P. Mutat. Res. 2003, 533, 107-120.
http://dx.doi.org/10.1016/j.mrfmmm.2003.07.011

[11]. Barszcz, B.; Jablonska-Wawrzycka, A.; Stadnicka, K.; Hodorowicz, S. A. Inorg. Chem. Comm. 2005, 8, 951-954.
http://dx.doi.org/10.1016/j.inoche.2005.07.013

[12]. Golbedaghi, R.; Salehzadeh, S.; Keypour, H.; Blackman, A. G. Polyhedron 2010, 29, 850856.
http://dx.doi.org/10.1016/j.poly.2009.09.027

[13]. Keypour, H.; Salehzadeh, S.; Pritchard, R. G.; Parish, R. V. Polyhedron 2000, 19, 1633-1637.
http://dx.doi.org/10.1016/S0277-5387(00)00444-7

[14]. Salehzadeh, S.; Golbedaghi, R.; Tidmarsh, I. S.; Al-Rasbi, N. K.; Adams, H. Polyhedron 2008, 27, 3549-3556.
http://dx.doi.org/10.1016/j.poly.2008.08.019

[15]. Atkinson, I. M.; Byriel, K. A.; Chia, P. S. K.; Kennard, C. H. L.; Leong, A. J.; Lindoy, L. F.; Lowe, M. P.; Mahendran, S.; Smith, G.; Eei, G. Aust. J. Chem. 1998, 51, 985-991.
http://dx.doi.org/10.1071/C98076


How to cite


Golbedaghi, R.; Rezaeivala, M.; Albeheshti, L. Eur. J. Chem. 2015, 6(1), 8-11. doi:10.5155/eurjchem.6.1.8-11.1127
Golbedaghi, R.; Rezaeivala, M.; Albeheshti, L. Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes. Eur. J. Chem. 2015, 6(1), 8-11. doi:10.5155/eurjchem.6.1.8-11.1127
Golbedaghi, R., Rezaeivala, M., & Albeheshti, L. (2015). Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes. European Journal of Chemistry, 6(1), 8-11. doi:10.5155/eurjchem.6.1.8-11.1127
Golbedaghi, Reza, Majid Rezaeivala, & Leila Albeheshti. "Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes." European Journal of Chemistry [Online], 6.1 (2015): 8-11. Web. 25 Sep. 2021
Golbedaghi, Reza, Rezaeivala, Majid, AND Albeheshti, Leila. "Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes" European Journal of Chemistry [Online], Volume 6 Number 1 (31 March 2015)

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