European Journal of Chemistry

Synthesis and spectroscopic investigation of a new hexadentate Schiff base ligand with N2O4 donor atoms and related metal complexes

Article Sidebar

PDF
Published: Mar 31, 2015
DOI: https://doi.org/10.5155/eurjchem.6.1.8-11.1127
Keywords:
Zinc complex, Ethanol amine, Schiff base ligand, Cadmium complex, Hexadentate ligand, Macroacyclic ligand
Section
Research Article
Issue
Vol. 6 No. 1 (2015): March 2015
Dates
Received 2014-07-31
Accepted 2014-09-14
Published 2015-03-31


Main Article Content

Reza Golbedaghi
Chemistry Department, Payame Noor University, Tehran, 19395, Iran
Majid Rezaeivala
Department of Chemical Engineering, Hamedan University of Technology, Hamedan,65155, Iran
Leila Albeheshti
Chemistry Department, Payame Noor University, Tehran, 19395, Iran

Abstract

Five new complexes [CdH2L(NO3)]ClO4 (1), [ZnH2L](ClO4)2 (2), [NiH2L](ClO4)2 (3), [CuH2L](ClO4)2 (4) and [CoH2L](ClO4)2 (5) were prepared by reaction of a new Schiff base ligand and different metal ions in 1:1 ratios. The new Schiff base ligand H2L was synthesized by reaction of 2-(4-(2-formylphenoxy)butoxy) benzaldehyde and ethanol amine and characterized with IR, 1H and 13C NMR and elemental analysis. The synthesized complexes were also characterized by IR and elemental analysis in all cases and 1H, 13C NMR and COSY in the case of [CdH2L(NO3)]ClO4 and [ZnH2L](ClO4)2 complexes.


icon graph This Abstract was viewed 1332 times | icon graph Article PDF downloaded 837 times

How to Cite
(1)
Golbedaghi, R.; Rezaeivala, M.; Albeheshti, L. Synthesis and Spectroscopic Investigation of a New Hexadentate Schiff Base Ligand With N2O4 Donor Atoms and Related Metal Complexes. Eur. J. Chem. 2015, 6, 8-11.

Article Details

Share
Links for Article


Crossref - Scopus - Google - European PMC
Crossref
Scopus
Google Scholar
Europe PMC
References

[1]. Bernhardt, P. V.; Lawrence, G. A. Coord. Chem. Rev. 1990, 104, 297-343.
http://dx.doi.org/10.1016/0010-8545(90)80045-U

[2]. Kaden, T. A. Pure Appl. Chem. 1993, 65, 1477-1483.
http://dx.doi.org/10.1351/pac199365071477

[3]. Wainwright, K. P. Coord. Chem. Rev. 1997, 166, 35-90.
http://dx.doi.org/10.1016/S0010-8545(97)00003-9

[4]. Costamagna, J.; Ferraudi, G.; Matsuhiro, B.; Campos-Valette, M.; Canales, J.; Villagran, M.; Vargas, J.; Aguirre, M. J. Coord. Chem. Rev. 2000, 196, 125-164.
http://dx.doi.org/10.1016/S0010-8545(99)00165-4

[5]. Wainwright, K. P. Inorg. Chem. 2001, 5, 293-298.

[6]. Haines, R. I. Rev.Inorg. Chem. 2002, 21, 165-169.

[7]. Frausto da Silva, J. J. R.; Williams, R. J. P. TheBiological Chemistry of the Elements, Oxford University Press, Oxford, 1991.

[8]. Parkin, G. Chem. Rev. 2004, 104, 699-768.
http://dx.doi.org/10.1021/cr0206263

[9]. Waalkes, M. P. J. Inorg. Biochem. 2000, 79, 241-244.
http://dx.doi.org/10.1016/S0162-0134(00)00009-X

[10]. Waalkes, M. P. Mutat. Res. 2003, 533, 107-120.
http://dx.doi.org/10.1016/j.mrfmmm.2003.07.011

[11]. Barszcz, B.; Jablonska-Wawrzycka, A.; Stadnicka, K.; Hodorowicz, S. A. Inorg. Chem. Comm. 2005, 8, 951-954.
http://dx.doi.org/10.1016/j.inoche.2005.07.013

[12]. Golbedaghi, R.; Salehzadeh, S.; Keypour, H.; Blackman, A. G. Polyhedron 2010, 29, 850856.
http://dx.doi.org/10.1016/j.poly.2009.09.027

[13]. Keypour, H.; Salehzadeh, S.; Pritchard, R. G.; Parish, R. V. Polyhedron 2000, 19, 1633-1637.
http://dx.doi.org/10.1016/S0277-5387(00)00444-7

[14]. Salehzadeh, S.; Golbedaghi, R.; Tidmarsh, I. S.; Al-Rasbi, N. K.; Adams, H. Polyhedron 2008, 27, 3549-3556.
http://dx.doi.org/10.1016/j.poly.2008.08.019

[15]. Atkinson, I. M.; Byriel, K. A.; Chia, P. S. K.; Kennard, C. H. L.; Leong, A. J.; Lindoy, L. F.; Lowe, M. P.; Mahendran, S.; Smith, G.; Eei, G. Aust. J. Chem. 1998, 51, 985-991.
http://dx.doi.org/10.1071/C98076

Supporting Agencies

Payame Noor University, Tehran, 19395, Iran
Most read articles by the same author(s)
TrendMD

Dimensions - Altmetric - scite_ - PlumX

Downloads and views

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...
License Terms

License Terms

by-nc

Copyright © 2025 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at https://www.eurjchem.com/index.php/eurjchem/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (https://www.eurjchem.com/index.php/eurjchem/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).