European Journal of Chemistry 2014, 5(4), 635-638 | doi: https://doi.org/10.5155/eurjchem.5.4.635-638.1131 | Get rights and content

Issue cover





  Open Access OPEN ACCESS | Open Access PEER-REVIEWED | RESEARCH ARTICLE | DOWNLOAD PDF | VIEW FULL-TEXT PDF | TOTAL VIEWS

Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes


Ahmad Ali Dehghani-Firouzabadi (1,*) , Fahimeh Motevaseliyan (2)

(1) Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran
(2) Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran
(*) Corresponding Author

Received: 06 Aug 2014 | Accepted: 23 Aug 2014 | Published: 31 Dec 2014 | Issue Date: December 2014

Abstract


Two thioether diamines 2-(2-aminoethylthio)aniline and 2-(3-aminopropylthio)aniline have been prepared employing a new procedure by reaction of 2-aminothiophenol and N-(2-bromoethyl)phthalimide or N-(3-bromopropyl)phthalimide, respectively. Then two new potentially pentadentate (N2O2S) Schiff base ligands derived from direct condensation between two maintained diamines and 2-hydroxybenzaldehyde or 5-bromo-2-hydroxy benzaldehyde were synthesized. Also, Zn(II) and Cd(II) complexes of Schiff base ligands have been prepared. These compounds have been characterized by physico-chemical and spectroscopic methods.


Keywords


Diamine; Thioether; N2O2S ligands; Pentadentate ligand; Unsymmetric ligand; Schiff base complexes

Full Text:

PDF
PDF    Open Access

DOI: 10.5155/eurjchem.5.4.635-638.1131

Links for Article


| | | | | | |

| | | | | | |

| | |

Related Articles




Article Metrics

icon graph This Abstract was viewed 869 times | icon graph PDF Article downloaded 410 times

Funding information


Faculty of Chemistry of Yazd University and Ministry of Science, Research and Technology of Iran

Citations

/


[1]. Ahmad Ali Dehghani-Firouzabadi, Hadi Kargar, Safie Eslaminejad, Behrouz Notash
Synthesis and characterization of a thioether Schiff base ligand and its metal complexes and crystal structure determination of the nickel(II) complex
Journal of Coordination Chemistry  68(24), 4345, 2015
DOI: 10.1080/00958972.2015.1091925
/


[2]. Amani S. Alturiqi, Abdel-Nasser M.A. Alaghaz, Mohamed E. Zayed, Reda A. Ammar
Synthesis, characterization, biological activity, and corrosion inhibition in acid medium of unsymmetrical tetradentate N2 O2 Schiff base complexes
Journal of the Chinese Chemical Society  65(9), 1060, 2018
DOI: 10.1002/jccs.201800027
/


[3]. Tahere Kondori, Niloufar Akbarzadeh-T, Mahboubeh Fazli, Behrouz Mir, Michal Dušek, Václav Eigner
A novel schiff base ligand and its copper complex: Synthesis, characterization, X-ray crystal structure and biological evaluation
Journal of Molecular Structure  1226, 129395, 2021
DOI: 10.1016/j.molstruc.2020.129395
/


[4]. Ahmad Ali Dehghani-Firouzabadi, Samaneh Sepehri, Behrouz Notash
Synthesis and Characterization of Metal Complexes of a New Unsymmetrical Tridentate NNS Schiff Base Ligand: X-ray Crystal Structure Determination of Nickel(II) Complex
Journal of the Chinese Chemical Society  64(9), 1104, 2017
DOI: 10.1002/jccs.201700068
/


[5]. Ahmad Ali Dehghani-Firouzabadi, Morteza Sobhani, Behrouz Notash
Synthesis and characterization of metal complexes with NOS unsymmetrical tridentate Schiff base ligand. X-ray crystal structures determination of nickel(II) and copper(II) complexes
Polyhedron  119, 49, 2016
DOI: 10.1016/j.poly.2016.08.021
/


[6]. Ahmad Ali Dehghani-Firouzabadi, Farzaneh Morovati, Behrouz Notash
Metal complexes with thioether containing unsymmetrical N2S donor Schiff base ligand: Crystal and molecular structure of nickel(II) complex
Phosphorus, Sulfur, and Silicon and the Related Elements  195(8), 644, 2020
DOI: 10.1080/10426507.2019.1709458
/


References


[1]. Lindoy, L. F. Coord. Chem. Rev. 1969, 4, 41-71.
http://dx.doi.org/10.1016/S0010-8545(00)80092-2

[2]. Sudbrake, C.; Vahrenkamp, H. Eur. J. Inorg. Chem. 2001, 751-754.
http://dx.doi.org/10.1002/1099-0682(200103)2001:3<751::AID-EJIC751>3.0.CO;2-2

[3]. Masdeu-Bulto, A. M.; Dieguez, M.; Martin, E.; Gomez, M. Coord. Chem. Rev. 2003, 242, 159-201.
http://dx.doi.org/10.1016/S0010-8545(03)00106-1

[4]. Taki, M.; Hattori, H.; Osako, T.; Nagatomo, S.; Shiro, M.; Kitagawa, T.; Itoh, S. Inorg. Chim. Acta 2004, 357, 3369-3381.
http://dx.doi.org/10.1016/j.ica.2004.04.008

[5]. Dolega, A. Coord. Chem. Rev. 2010, 254, 916-937.
http://dx.doi.org/10.1016/j.ccr.2009.12.039

[6]. Canovese, L.; Chessa, G.; Visentin, F.; Uguagliati, P. Coord. Chem. Rev. 2004, 248, 945-954.
http://dx.doi.org/10.1016/j.ccr.2004.05.009

[7]. Asadi, M.; Mohammadi, K.; Esmaiezadeh, S.; Etemadi, B.; Fun, H. K. Inorg. Chim. Acta 2009, 362, 4913-4920.
http://dx.doi.org/10.1016/j.ica.2009.07.025

[8]. Chattopadhyay, S.; Ray, M. S.; Chaudhuri, S.; Mukhopadhyay, G.; Bocelli, G.; Cantoni, A.; Ghosh, A. Inorg. Chim. Acta 2006, 359, 1367-1375.
http://dx.doi.org/10.1016/j.ica.2005.12.011

[9]. Matsushita, T.; Shono, T. Polyhedron 1986, 5, 735-743.
http://dx.doi.org/10.1016/S0277-5387(00)84429-0

[10]. Rezaeivala, M.; Keypour, H.; Salehzadeh, S.; Latifi, R.; Chalabian, F.; Katouzian, F. J. Iran Chem. Soc. 2014, 11, 431-440.
http://dx.doi.org/10.1007/s13738-013-0315-4

[11]. Kaasjager, V. E.; Puglisi, L.; Bouwman, E.; Driessen, W. L.; Reedijk, J. Inorg. Chim. Acta 2000, 310, 183-190.
http://dx.doi.org/10.1016/S0020-1693(00)00285-1

[12]. Keypour, H.; Dehghani-Firouzabadi, A. A.; Khavasi, H. R. Polyhedron 2009, 28, 1546-1550.
http://dx.doi.org/10.1016/j.poly.2009.03.028

[13]. Keypour, H.; Dehghani-Firouzabadi, A. A.; Rezaeivala, M.; Goudarziafshar, H. J. Iran Chem. Soc. 2010, 7, 820-824.
http://dx.doi.org/10.1007/BF03246074

[14]. Chiswell, B.; Crawford, J. P.; O'Reilly, E. J. Inorg. Chim. Acta 1980, 40, 223-228.
http://dx.doi.org/10.1016/S0020-1693(00)92009-7

[15]. Costes, J. P. Inorg. Chim. Acta 1987, 130, 17-21.
http://dx.doi.org/10.1016/S0020-1693(00)85922-8

[16]. Harrop, T. C.; Mascharak, P. K. Acc. Chem. Res. 2004, 37, 253-260.
http://dx.doi.org/10.1021/ar0301532

[17]. Kwong, H. L.; Yeung, H. L.; Yeung, C. T.; Lee, W. S.; Lee, C. S.; Wong, W. L. Coord. Chem. Rev. 2007, 251, 2188-2222.
http://dx.doi.org/10.1016/j.ccr.2007.03.010

[18]. Saghatforoush, L. A,; Chalabian, F.; Aminkhani, A.; Karimnezhad, G.; Ershad, S. Eur. J. Med. Chem. 2009, 44, 4490-4495.
http://dx.doi.org/10.1016/j.ejmech.2009.06.015


How to cite


Dehghani-Firouzabadi, A.; Motevaseliyan, F. Eur. J. Chem. 2014, 5(4), 635-638. doi:10.5155/eurjchem.5.4.635-638.1131
Dehghani-Firouzabadi, A.; Motevaseliyan, F. Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes. Eur. J. Chem. 2014, 5(4), 635-638. doi:10.5155/eurjchem.5.4.635-638.1131
Dehghani-Firouzabadi, A., & Motevaseliyan, F. (2014). Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes. European Journal of Chemistry, 5(4), 635-638. doi:10.5155/eurjchem.5.4.635-638.1131
Dehghani-Firouzabadi, Ahmad, & Fahimeh Motevaseliyan. "Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes." European Journal of Chemistry [Online], 5.4 (2014): 635-638. Web. 10 May. 2021
Dehghani-Firouzabadi, Ahmad, AND Motevaseliyan, Fahimeh. "Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes" European Journal of Chemistry [Online], Volume 5 Number 4 (31 December 2014)

The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item



DOI Link: https://doi.org/10.5155/eurjchem.5.4.635-638.1131

CrossRef | Scilit | GrowKudos | Researchgate | Publons | Microsoft | scibey | Scite | Lens | OUCI

WorldCat Paperbuzz Citeas | Dimensions | Semanticscholar | Plumx | Kopernio | Zotero | Mendeley

ZoteroSave to Zotero MendeleySave to Mendeley



European Journal of Chemistry 2014, 5(4), 635-638 | doi: https://doi.org/10.5155/eurjchem.5.4.635-638.1131 | Get rights and content

Refbacks

  • There are currently no refbacks.




Copyright (c)





© Copyright 2010 - 2021  Atlanta Publishing House LLC All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2010-2021 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.