European Journal of Chemistry 2014, 5(4), 635-638 | doi: https://doi.org/10.5155/eurjchem.5.4.635-638.1131 | Get rights and content

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Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes


Ahmad Ali Dehghani-Firouzabadi (1,*) , Fahimeh Motevaseliyan (2)

(1) Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran
(2) Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran
(*) Corresponding Author

Received: 06 Aug 2014 | Accepted: 23 Aug 2014 | Published: 31 Dec 2014 | Issue Date: December 2014

Abstract


Two thioether diamines 2-(2-aminoethylthio)aniline and 2-(3-aminopropylthio)aniline have been prepared employing a new procedure by reaction of 2-aminothiophenol and N-(2-bromoethyl)phthalimide or N-(3-bromopropyl)phthalimide, respectively. Then two new potentially pentadentate (N2O2S) Schiff base ligands derived from direct condensation between two maintained diamines and 2-hydroxybenzaldehyde or 5-bromo-2-hydroxy benzaldehyde were synthesized. Also, Zn(II) and Cd(II) complexes of Schiff base ligands have been prepared. These compounds have been characterized by physico-chemical and spectroscopic methods.


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Keywords


Diamine; Thioether; N2O2S ligands; Pentadentate ligand; Unsymmetric ligand; Schiff base complexes

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DOI: 10.5155/eurjchem.5.4.635-638.1131

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Funding information


Faculty of Chemistry of Yazd University and Ministry of Science, Research and Technology of Iran

Citations

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[1]. Ahmad Ali Dehghani-Firouzabadi, Hadi Kargar, Safie Eslaminejad, Behrouz Notash
Synthesis and characterization of a thioether Schiff base ligand and its metal complexes and crystal structure determination of the nickel(II) complex
Journal of Coordination Chemistry  68(24), 4345, 2015
DOI: 10.1080/00958972.2015.1091925
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[2]. A.A. AlObaid, M. Suleiman, C. Jama, A. Zarrouk, I. Warad
Synthesis, physicochemical, optical, thermal and TD-DFT of (E)-N′-((9-ethyl-9H-carbazol-3-yl)-methylene)-4-methyl-benzene-sulfonohydrazide (ECMMBSH): Naked eye and colorimetric Cu2+ ion chemosensor
Journal of King Saud University - Science  33(8), 101633, 2021
DOI: 10.1016/j.jksus.2021.101633
/

[3]. Amani S. Alturiqi, Abdel-Nasser M.A. Alaghaz, Mohamed E. Zayed, Reda A. Ammar
Synthesis, characterization, biological activity, and corrosion inhibition in acid medium of unsymmetrical tetradentate N2 O2 Schiff base complexes
Journal of the Chinese Chemical Society  65(9), 1060, 2018
DOI: 10.1002/jccs.201800027
/

[4]. Tahere Kondori, Niloufar Akbarzadeh-T, Mahboubeh Fazli, Behrouz Mir, Michal Dušek, Václav Eigner
A novel schiff base ligand and its copper complex: Synthesis, characterization, X-ray crystal structure and biological evaluation
Journal of Molecular Structure  1226, 129395, 2021
DOI: 10.1016/j.molstruc.2020.129395
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[5]. Ahmad Ali Dehghani-Firouzabadi, Samaneh Sepehri, Behrouz Notash
Synthesis and Characterization of Metal Complexes of a New Unsymmetrical Tridentate NNS Schiff Base Ligand: X-ray Crystal Structure Determination of Nickel(II) Complex
Journal of the Chinese Chemical Society  64(9), 1104, 2017
DOI: 10.1002/jccs.201700068
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[6]. Ahmad Ali Dehghani-Firouzabadi, Morteza Sobhani, Behrouz Notash
Synthesis and characterization of metal complexes with NOS unsymmetrical tridentate Schiff base ligand. X-ray crystal structures determination of nickel(II) and copper(II) complexes
Polyhedron  119, 49, 2016
DOI: 10.1016/j.poly.2016.08.021
/

[7]. Ahmad Ali Dehghani-Firouzabadi, Farzaneh Morovati, Behrouz Notash
Metal complexes with thioether containing unsymmetrical N2S donor Schiff base ligand: Crystal and molecular structure of nickel(II) complex
Phosphorus, Sulfur, and Silicon and the Related Elements  195(8), 644, 2020
DOI: 10.1080/10426507.2019.1709458
/

[8]. Qingwen Shan, Juan Zhang, Yajuan Wang, Wenqiang Liu
Synthesis of Schiff base and its application in adsorption desulphurisation of fuel oil
International Journal of Environmental Analytical Chemistry  , 1, 2021
DOI: 10.1080/03067319.2021.1986489
/

[9]. Mahbubeh Fazli, Niloufar Akbarzadeh-T, Hadi Beitollahi, Michal Dušek, Václav Eigner
New Schiff base ligand N-(2-hydroxy-1-naphthylidene)-2-methyl aniline and its nano-sized copper(II) complex: synthesis, characterization, crystal structure and application as an electrochemical sensor of 2-phenylphenol in the presence of 4-chlorophenol
Journal of Materials Science: Materials in Electronics  32(20), 25118, 2021
DOI: 10.1007/s10854-021-06967-3
/

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How to cite


Dehghani-Firouzabadi, A.; Motevaseliyan, F. Eur. J. Chem. 2014, 5(4), 635-638. doi:10.5155/eurjchem.5.4.635-638.1131
Dehghani-Firouzabadi, A.; Motevaseliyan, F. Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes. Eur. J. Chem. 2014, 5(4), 635-638. doi:10.5155/eurjchem.5.4.635-638.1131
Dehghani-Firouzabadi, A., & Motevaseliyan, F. (2014). Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes. European Journal of Chemistry, 5(4), 635-638. doi:10.5155/eurjchem.5.4.635-638.1131
Dehghani-Firouzabadi, Ahmad, & Fahimeh Motevaseliyan. "Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes." European Journal of Chemistry [Online], 5.4 (2014): 635-638. Web. 3 Jun. 2023
Dehghani-Firouzabadi, Ahmad, AND Motevaseliyan, Fahimeh. "Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes" European Journal of Chemistry [Online], Volume 5 Number 4 (31 December 2014)

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European Journal of Chemistry 2014, 5(4), 635-638 | doi: https://doi.org/10.5155/eurjchem.5.4.635-638.1131 | Get rights and content

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