European Journal of Chemistry

Synthesis and characterization of four new unsymmetrical potentially pentadentate Schiff base ligands and related Zn(II) and Cd(II) complexes

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Published: Dec 31, 2014
DOI: https://doi.org/10.5155/eurjchem.5.4.635-638.1131
Keywords:
Diamine, Thioether, N2O2S ligands, Pentadentate ligand, Unsymmetric ligand, Schiff base complexes
Section
Research Article
Issue
Vol. 5 No. 4 (2014): December 2014
Dates
Received 2014-08-06
Accepted 2014-08-23
Published 2014-12-31


Main Article Content

Ahmad Ali Dehghani-Firouzabadi
Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran
Fahimeh Motevaseliyan
Department of Chemistry, Faculty of Science, Yazd University, 89195-741 Yazd, Iran

Abstract

Two thioether diamines 2-(2-aminoethylthio)aniline and 2-(3-aminopropylthio)aniline have been prepared employing a new procedure by reaction of 2-aminothiophenol and N-(2-bromoethyl)phthalimide or N-(3-bromopropyl)phthalimide, respectively. Then two new potentially pentadentate (N2O2S) Schiff base ligands derived from direct condensation between two maintained diamines and 2-hydroxybenzaldehyde or 5-bromo-2-hydroxy benzaldehyde were synthesized. Also, Zn(II) and Cd(II) complexes of Schiff base ligands have been prepared. These compounds have been characterized by physico-chemical and spectroscopic methods.


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Dehghani-Firouzabadi, A. A.; Motevaseliyan, F. Synthesis and Characterization of Four New Unsymmetrical Potentially Pentadentate Schiff Base Ligands and Related Zn(II) and Cd(II) Complexes. Eur. J. Chem. 2014, 5, 635-638.

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References

[1]. Lindoy, L. F. Coord. Chem. Rev. 1969, 4, 41-71.
http://dx.doi.org/10.1016/S0010-8545(00)80092-2

[2]. Sudbrake, C.; Vahrenkamp, H. Eur. J. Inorg. Chem. 2001, 751-754.
http://dx.doi.org/10.1002/1099-0682(200103)2001:3<751::AID-EJIC751>3.0.CO;2-2

[3]. Masdeu-Bulto, A. M.; Dieguez, M.; Martin, E.; Gomez, M. Coord. Chem. Rev. 2003, 242, 159-201.
http://dx.doi.org/10.1016/S0010-8545(03)00106-1

[4]. Taki, M.; Hattori, H.; Osako, T.; Nagatomo, S.; Shiro, M.; Kitagawa, T.; Itoh, S. Inorg. Chim. Acta 2004, 357, 3369-3381.
http://dx.doi.org/10.1016/j.ica.2004.04.008

[5]. Dolega, A. Coord. Chem. Rev. 2010, 254, 916-937.
http://dx.doi.org/10.1016/j.ccr.2009.12.039

[6]. Canovese, L.; Chessa, G.; Visentin, F.; Uguagliati, P. Coord. Chem. Rev. 2004, 248, 945-954.
http://dx.doi.org/10.1016/j.ccr.2004.05.009

[7]. Asadi, M.; Mohammadi, K.; Esmaiezadeh, S.; Etemadi, B.; Fun, H. K. Inorg. Chim. Acta 2009, 362, 4913-4920.
http://dx.doi.org/10.1016/j.ica.2009.07.025

[8]. Chattopadhyay, S.; Ray, M. S.; Chaudhuri, S.; Mukhopadhyay, G.; Bocelli, G.; Cantoni, A.; Ghosh, A. Inorg. Chim. Acta 2006, 359, 1367-1375.
http://dx.doi.org/10.1016/j.ica.2005.12.011

[9]. Matsushita, T.; Shono, T. Polyhedron 1986, 5, 735-743.
http://dx.doi.org/10.1016/S0277-5387(00)84429-0

[10]. Rezaeivala, M.; Keypour, H.; Salehzadeh, S.; Latifi, R.; Chalabian, F.; Katouzian, F. J. Iran Chem. Soc. 2014, 11, 431-440.
http://dx.doi.org/10.1007/s13738-013-0315-4

[11]. Kaasjager, V. E.; Puglisi, L.; Bouwman, E.; Driessen, W. L.; Reedijk, J. Inorg. Chim. Acta 2000, 310, 183-190.
http://dx.doi.org/10.1016/S0020-1693(00)00285-1

[12]. Keypour, H.; Dehghani-Firouzabadi, A. A.; Khavasi, H. R. Polyhedron 2009, 28, 1546-1550.
http://dx.doi.org/10.1016/j.poly.2009.03.028

[13]. Keypour, H.; Dehghani-Firouzabadi, A. A.; Rezaeivala, M.; Goudarziafshar, H. J. Iran Chem. Soc. 2010, 7, 820-824.
http://dx.doi.org/10.1007/BF03246074

[14]. Chiswell, B.; Crawford, J. P.; O'Reilly, E. J. Inorg. Chim. Acta 1980, 40, 223-228.
http://dx.doi.org/10.1016/S0020-1693(00)92009-7

[15]. Costes, J. P. Inorg. Chim. Acta 1987, 130, 17-21.
http://dx.doi.org/10.1016/S0020-1693(00)85922-8

[16]. Harrop, T. C.; Mascharak, P. K. Acc. Chem. Res. 2004, 37, 253-260.
http://dx.doi.org/10.1021/ar0301532

[17]. Kwong, H. L.; Yeung, H. L.; Yeung, C. T.; Lee, W. S.; Lee, C. S.; Wong, W. L. Coord. Chem. Rev. 2007, 251, 2188-2222.
http://dx.doi.org/10.1016/j.ccr.2007.03.010

[18]. Saghatforoush, L. A,; Chalabian, F.; Aminkhani, A.; Karimnezhad, G.; Ershad, S. Eur. J. Med. Chem. 2009, 44, 4490-4495.
http://dx.doi.org/10.1016/j.ejmech.2009.06.015

Supporting Agencies

Faculty of Chemistry of Yazd University and Ministry of Science, Research and Technology of Iran
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