Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Kinetics of the release of antimony trioxide from the backcoated textile preparation
Raed Ahmad Ghanem (1,*)
(1) Department of Chemistry, Faculty of Science, Al Al-Bayt University, Mafraq 25113, Jordan
(*) Corresponding Author
Received: 20 Sep 2014 | Revised: 20 Oct 2014 | Accepted: 25 Oct 2014 | Published: 31 Mar 2015 | Issue Date: March 2015
Abstract
Segregation of antimony trioxide (ATO) from back-coated textiles was studied for two types of textile samples: A (ATO-Hexabromocyclododecane) and B (ATO-Decabromodiphenyl ether). Samples A was found to lose 5.3, 12, 28 and 39 %wt:wt of the amount of ATO originally present due to thermal ageing and UV exposure, respectively. Thermal ageing was performed at 25, 60 and 90 °C compared to 11.0, 17.3, 26.0 and 20.4 % wt:wt of ATO for sample B. The release follows first order kinetics with rate constants of 7.59×10-3, 1.89×10-2, 4.80×10-2 and 2.60×10-2 day-1, respectively, for type A and 9.20×10-3, 2.06×10-2, 4.10×10-2 and 3.83×10-2 day-1 for type B aged at 25, 60, 90 °C and UV exposure, respectively. Migration of ATO from the backcoated textile into simulated biological fluids was also studied for different type of samples under different ageing conditions using Head-over-Heels and contact blotting tests. The presence of biological fluids enhances the migration of ATO.
Announcements
One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and May 31, 2023 (Voucher code: SPONSOR2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF
DOI: 10.5155/eurjchem.6.1.71-77.1158
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 1231 times |
PDF Article downloaded 550 times
Funding information
Al Al-Bayt University, Mafraq 25113, Jordan and Hail University, Hail, Saudi Arabia
References
[1]. Ghanem, R.; Baker, H. J. Hazard. Mat. 2009, 62(1), 249-253
http://dx.doi.org/10.1016/j.jhazmat.2008.05.071
[2]. Ghanem, R.; Delmani, F. J. Anal. Appl. Pyrol. 2012, 98, 79-85
http://dx.doi.org/10.1016/j.jaap.2012.09.001
[3]. Brown, D. J.; Overmeire, L. V.; Goeyens, L.; Denison, M. S.; Clark, G. C. Organohalogen Compd. 2000, 47, 36-39.
[4]. Simonsen, F. A.; Stavnsbjerg, M., Moller, L. M.; Madsen, T. Danish Environmental Protection Agency; Kobenhavn, K. Denmark: Brominated flame retardants: Toxicity and ecotoxicity; Environment project No. 568, 2000.
[5]. Van Esch, G. J. Brominated diphenyl ethers. Environmental Health Criteria, World health Organization, International Programme on Chemical Safety, Geneva, 1994, pp. 162.
[6]. Troitzsch, J. Chimica Oggi/Chemistry Today 1998, 16, 1-19.
[7]. Hedemalm, P.; Eklund, A.; Bloom, R.; Haggstrom, J. Brominated flame retardants-an overview of toxicology and industrial aspects, Electronics and the Environment, ISEE Symposium on Organo AB, Sweden 2000, 203-208
[8]. Gordon, W. G. Environ. Sci. Poll. Res. 2000, 7(1), 37-49
http://dx.doi.org/10.1065/espr199910.002
[9]. The European flame retardants association: http://www.cefic-efra.com/index.php/en/furniture-a-textile/use-of-flame-retardants
[10]. Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Denver (CO), Micromedex., Inc., 1993-1995 Ed.
[11]. Jansson, B.; Asplund, L.; Olsson, M. Chemosphere 1987, 16(10-12), 2343-2349.
http://dx.doi.org/10.1016/0045-6535(87)90291-8
[12]. Sellstrom, U.; Kierkegaard, A.; De-Wit, C.; Jansson, B. Environ. Toxicol. Chem. 1998, 17(6), 1065-1072.
http://dx.doi.org/10.1002/etc.5620170612
[13]. Eljarrat, E.; DeLaCal, A.; Raldua, D.; Duran, C.; Barcelo, D. Environ. Sci. Technol. 2004, 38(9), 2603-2608.
http://dx.doi.org/10.1021/es0301424
[14]. Allchin, C. R.; Morris, S. Organohalogen. Compd. 2003, 61, 41-44.
[15]. Zhang, S.; Horrocks, A. Prog. Polymer Sci. Oxford 2003, 28(11), 1517-1538.
http://dx.doi.org/10.1016/j.progpolymsci.2003.09.001
[16]. Charles, A.; Morgan, W.; Morgan, A., Fire retardancy of polymeric material, 2nd Edition, CRC press, 2012.
[17]. http://www.epa.gov/ttn/atw/hlthef/antimony.html
[18]. U. S. Department of Health and Human Services, Hazardous Substances Data Bank, National Toxicology Information Program, National Library of Medicine, Bethesda, MD, USA, 1993.
[19]. U. S. Department of Health and Human Services, Registry of Toxic Effects of Chemical Substances (RTECS), National Toxicology Information Program, National Library of Medicine, Bethesda, MD, USA, 1993.
[20]. Alimonti, A.; Forte, G.; Spezia, S.; Gatti, A.; Mincione H.; Ronchi A. Rapid. Commun. MASS. SP. 2005, 19, 3131-3138.
[21]. Agency for Toxic Substances and Disease Registry (ATSDR). Toxicological Profile for Antimony, U. S. Public Health Service, U. S. Department of Health and Human Services, Atlanta, GA, 1992-2002.
[22]. Navas-Acien, A.; Silbergeld, E. K.; Sharrett, R.; Calderon-Aranda, E.; Selvin, E.; Guallar, E. Environ. Health. Persp. 2005, 113, 164-169.
http://dx.doi.org/10.1289/ehp.7329
[23]. Tarabar, A. F.; Khan, Y.; Nelson, L. S.; Hoffman, R. S. Vet. Hum. Toxicol 2004, 64, 331-333.
[24]. Ross, G.; Cooper, P.; Adrian, P. Indian J. Occp. Environ. Med. 2009, 13(1), 3-10.
[25]. Baker, H.; Ghanem, R. Eurasian J. Anal. Chem. 2014, 9(1), inpress.
[26]. Ghanem, R. Jordan J. Chem. 2009, 4(2), 171-181.
[27]. Ghanem, R.; Baker, H. Asian J. Chem. 2007, 19(2), 921-928.
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.6.1.71-77.1158
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2015, 6(1), 71-77 | doi: https://doi.org/10.5155/eurjchem.6.1.71-77.1158 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.