Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Highly sensitive spectrophotometric method for the determination of vanadium in environmental, biological, food and soil samples using orthoaminophenol
Tasnima Zannat (1)
, Mohammad Jamaluddin Ahmed (2,*) (1) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong, 4331, Bangladesh
(2) Laboratory of Analytical Chemistry, Department of Chemistry, University of Chittagong, Chittagong, 4331, Bangladesh
(*) Corresponding Author
Received: 12 Nov 2014 | Accepted: 14 Feb 2015 | Published: 30 Jun 2015 | Issue Date: June 2015
Abstract
A simple, ultra-sensitive and highly selective non-extractive spectrophotometric method for the determination of trace amount of vanadium(V) using orthoamino phenol (OAP) has been developed. OAP reacts in highly acidic (0.005-0.015 mol/L H2SO4) and aqueous media with vanadium(V) to give a chocolate color chelate which has an absorption maximum at 405 nm. The reaction was instantaneous and absorbance remains stable for over 72 h. The average molar absorption co-efficient and Sandell’s sensitivity were found to be 6.7×105 L/mol.cm and 10 ng/cm2 of vanadium(V), respectively. Linear calibration graphs were obtained for 0.02-50.00 mg/L having detection limit 1 µg/L and quantification limit of the reaction were found to be 10 µg/L and RSD 0-2%. The stoichiometric composition of the chelate is 1:3 (Vanadium(V):OAP, v:v). Large excess of over 60 cations, anions and complexing agents (Like tartrate, EDTA, oxalate, chloride, phosphate, thiourea, SCN- etc.) do not interfere in the vanadium determination. The method was successfully used in the determination of vanadium in several standard reference materials (Alloys and steels) as well as in some environmental waters(Potable and polluted), biological samples (Human blood and urine), food samples, soil samples, solution containing both vanadium(IV) and vanadium(V) and complex synthetic mixtures. The results of the proposed method for biological analyses were found to be in excellent agreement with those obtained by AAS. The method has high precision and accuracy (s = ±0.01 for 0.5 µg/mL).
Announcements
One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF
DOI: 10.5155/eurjchem.6.2.141-150.1193
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 1292 times |
PDF Article downloaded 534 times
Funding information
Analytical Chemistry Division, Bangladesh Council of Science and Industrial Research Laboratories, Dhaka, Bangladesh
Citations
[1]. Mohammed Jamaluddin Ahmed, Faisal Hossain, Esham Mahmood
A Highly Selective and Simple Spectrophotometric Method for the Determination of Zinc at Nano-trace Levels in Some Environmental, Biological, Food, and Pharmaceutical Samples Using 2-hydroxynaphthaldehydebenzoylhydrazone
European Journal of Chemistry 11(2), 160, 2020
DOI: 10.5155/eurjchem.11.2.160-167.1987
[2]. Shaifa Abrarin, Mohammed Jamaluddin Ahmed
A highly sensitive and selective spectrophotometric method for the determination of vanadium at nanotrace levels in some environmental, biological, soil, food, and pharmaceutical samples using salicylaldehyde-benzoylhydrazone
European Journal of Chemistry 11(4), 385, 2020
DOI: 10.5155/eurjchem.11.4.385-395.2030
[3]. Muhammad Jamaluddin Ahmed, Muhammad Jihan Uddin, Muhammad Emdadul Hoque
Development of a new highly sensitive and selective spectrophotometric method for the determination of selenium at nano-trace levels in various complex matrices using salicylaldehyde-orthoaminophenol
European Journal of Chemistry 12(4), 469, 2021
DOI: 10.5155/eurjchem.12.4.469-481.2137
[4]. Elaheh Nourbala Tafti, Shayesteh Dadfarnia, Ali Mohammad Haji Shabani, Zahra Dehghani Firouzabadi
Determination of vanadium species in water, vegetables, and fruit samples using supramolecular solvent microextraction combined with electrothermal atomic absorption spectrometry
Journal of the Iranian Chemical Society 15(8), 1899, 2018
DOI: 10.1007/s13738-018-1387-y
References
[1]. Yadav, D. K.; Lokhande, R. S.; Pitale, S. M.; Janwadkar, S. P.; Navarkar, P. S.; Rana, P. K. World J. Anal. Chem. 2014, 2(1), 10-14.
[2]. Clayton, G. D.; Clayton, F. E. Pathy's Industrial Hygine and Toxicology, 3rd edition, Vol. 24, Wiley, New York, 1981, pp. 2013.
[3]. Herley, L. S. Trace Element Analytical Chemistry in Medicine and Biology etc., Pratter and ScharmelP. (eds), Vol. 3, Walter de Gruyter (eds), Berlin, 1984, pp. 375.
[4]. Mracova, M.; Jirova, D.; Janci, H.; Lener, J. Sci. Total Environ. 1993, 16, 633-633.
[5]. Venugopal, B.; Luckey, T. D. Metal Toxicity in Mammals-2, Plenum Press, New York, 1979, pp. 220.
[6]. Langard, S.; Norseth, T. Handbook on the Toxicology of Metals, Friberg L.; Nordberg G. P.; Vouk V. B. (eds), Elsevier, Amsterdam, 1986.
[7]. Key, M. M.; Henschel, A. F.; Butter, J.; Ligo, R. N.; Tebershed, I. R. Occupational Diseases : A Guide to their recognition, US Department of Health, Education and Welfare, U. S. Govt. Printing, Washington, D. C. June, 1977.
[8]. Shamberger, R. J.; Gunsch, M. S.; Willis, C. P.; Mcormack, I. J. Trace substances in Environmental Health XII, 1986, 27(1-2), pp. 1-9.
[9]. Vijaya, K. R. K.; Yamini, P.; Kishore, K. R.; Venkateswarlu, P. Inter. J. Chem. Eng. Appl. Sci. 2012, 2(1), 1-5.
[10]. Kadyan, P. S.; Singh, D.; Sonia, V. Der Pharma Chemica 2012, 4(4), 1577-1581.
[11]. Yadamari, T.; Yakkala, K.; Gurijala, R. N. J. Encapsul. Adsorp. Sci. 2014, 4, 53-61.
http://dx.doi.org/10.4236/jeas.2014.42006
[12]. Rana, P.; Lokhande, R.; Pitale, S.; Janwadkar, S.; Yadav, D.; Sonopant, D.; Apte, V. S.; Mehta, M. H. Commerce Int. J. Chem. Tech. Res. 2014, 6(4), 2295-2299.
[13]. Narayana, B.; Sunil, K. Eurasian J. Anal. Chem. 2009, 4(2), 141-151.
[14]. Srilalitha, V.; Raghavendra, A.; Seshagiri, V.; Ravindranath, L. K. Analele Universita Niidin Bucuresti-Chimie (Serienou a), 2010, 19(2), 69-76.
[15]. Shishehbore, M.; Jokar, R. Anal. Methods 2011, 3, 2815-2821.
http://dx.doi.org/10.1039/c1ay05369h
[16]. Ahmed, M. J.; Banu, S. Talanta 1999, 48(5), 1085-1094.
http://dx.doi.org/10.1016/S0039-9140(98)00329-4
[17]. Jeffery, G. H.; Bassett, J.; Mendham, J.; Denney, R. C. eds. Vogel's Textbook of Quantitative Analysis, 5th ed. Bath Press Ltd. London, 1994, pp. 404-405.
[18]. Pal, B. K.; Chowdhury, B. Mikrochim. Acta 1984, 2, 121-131.
http://dx.doi.org/10.1007/BF01237266
[19]. Busev, A. I.; Tiptsova, V. G.; Ivanov, V. M. (eds), Analytical Chemistry of Rare elements, Mir Publishers, Moscow, 1981, pp. 386-390.
[20]. Sandell, E. B. Colorimetric Determination of Traces of Metals, 3rd edition, Interscience, New York, 1965, pp. 269-285.
[21]. Ojeda, C. B.; Torres, A. G.; Rojas, F. S.; Pavon, J. M. C. Analyst 1987, 112, 1499-1502.
http://dx.doi.org/10.1039/an9871201499
[22]. Greenberg, R. R.; Kingston, H. M. Anal. Chem. 1983, 55, 1160-1166.
http://dx.doi.org/10.1021/ac00258a041
[23]. You, J. A.; Jones, A. L. Ind. Eng. Chem. Anal. Ed. 1944, 16, 11-16.
[24]. Parker, G. A. Analytical Chemistry of Molybdenum, Springer Verlag, Berlin, 1983.
http://dx.doi.org/10.1007/978-3-642-68992-5
[25]. Sun, C.; Yang, J. Y.; Tzeng, S. R. Analyst 1999, 124, 421-425.
http://dx.doi.org/10.1039/a809596e
[26]. Greenberg, A. E.; Clesceri, L. S.; Trussell, R. R. (eds), Standard Methods for the Examination of Water and Waste Water, 18th ed., American Public Health Association, Washington DC, 1992, pp. 3-53-65.
[27]. Ali, A. M.; Mori, Y.; Sawada, K. Anal. Sci. 2006, 22(9), 1169-1172.
http://dx.doi.org/10.2116/analsci.22.1169
[28]. Fifield, F. W.; Haines, P. J. (eds), Environmental Chemistry, 2nd edition, Blackwell Science, London, 2000, pp. 420-425.
[29]. Stahr, H. M. Analytical Methods in Toxicology, 3rd edition, John Wiley and Sons, New York, 1991, pp. 75-85.
[30]. Hesse, P. R. A Text Book of Soil Chemical Analysis, Chemical Publishing Co. Inc. New York, 1972, pp. 332-356.
[31]. Abbaspur, A.; Moosabi, S. M. M.; Mirzajani, R. Iranian J. Sci. Tech, Trans A3 2007, 31, 43-50.
[32]. Ahmed, M. J.; Roy, U. K. Turk. J. Chem. 2009, 33, 709-726.
[33]. Ahmed, M. J.; Mamun M. A. Talanta 2001, 55(1), 43-55.
http://dx.doi.org/10.1016/S0039-9140(01)00389-7
[34]. Ahmed, M. J.; Hoque, M. R.; Khan, A. S. M. S. H.; Bhattacharjee, S. C. Eurasian J. Anal. Chem. 2010, 5(1), 1-15.
[35]. Ahmed, M. J.; Hossan, K. J. J. Iranian Chem. Soc. 2008, 5(4), 677-688.
http://dx.doi.org/10.1007/BF03246149
[36]. Ahmed, M. J.; Zannat, T. Pakistan J. Anal. Environ. Chem. 2012, 13(1), 22-35.
[37]. Ahmed, M. J.; Jannat, T.; Saifuddin, M.; Bhattacharjee, S. C. Green Pages-The Global Directory for Environmental Technology, 2010, http://www.eco-web.com/med/index.html, ID:100412.
[38]. Soomro, R.; Ahmed, M. J.; Memon, N. Turk. J. Chem. 2011, 35, 155-170.
[39]. Ahmed, M. J.; Uddin, M. N. Chemosphere 2007, 67(10), 2020-2027.
http://dx.doi.org/10.1016/j.chemosphere.2006.11.020
[40]. Ahmed, M. J.; Nasiruddin, M.; Zannat, T.; Sultana, S. Anal. Methods 2014, 6, 2282-2293.
http://dx.doi.org/10.1039/c3ay42113a
[41]. Zannat, T.; Ahmed, M. J. Eur. J. Chem. 2014, 5(1), 101-110.
http://dx.doi.org/10.5155/eurjchem.5.1.101-110.882
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.6.2.141-150.1193
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2015, 6(2), 141-150 | doi: https://doi.org/10.5155/eurjchem.6.2.141-150.1193 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.