European Journal of Chemistry 2015, 6(2), 169-173 | doi: https://doi.org/10.5155/eurjchem.6.2.169-173.1228 | Get rights and content






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Study on the host-guest interactions during caffeine encapsulation into zeolite


Zvezdelina Lyubenova Yaneva (1) , Manuela Stoyanova Staleva (2) , Nedyalka Valkanova Georgieva (3,*)

(1) Chemistry Unit, Department of Pharmacology, Animal Physiology and Physiological Chemistry, Faculty of Veterinary Medicine, Trakia University, Students Campus, 6000 Stara Zagora, Bulgaria
(2) University “Prof. d-r Assen Zlatarov”, 1 Prof. Yakim Yakimov Str., 8000 Bourgas, Bulgaria
(3) Chemistry Unit, Department of Pharmacology, Animal Physiology and Physiological Chemistry, Faculty of Veterinary Medicine, Trakia University, Students Campus, 6000 Stara Zagora, Bulgaria
(*) Corresponding Author

Received: 26 Nov 2014 | Revised: 06 Jan 2015 | Accepted: 10 Jan 2015 | Published: 30 Jun 2015 | Issue Date: June 2015

Abstract


The objective of this study was to investigate the equilibrium and kinetics behavior, sorption mechanism and host-guest interactions during caffeine (CAF) encapsulation in natural zeolite. The chemical, spectral and morphological properties of the newly obtained drug-carrier system were analyzed. Zeolite surface chemistry and morphology were characterized by determination of pH of zero charge, FT-IR and digital microscopy analyses. Equilibrium and kinetic sorption experiments and modeling were conducted to assess zeolite potential. Satisfactory extend of CAF encapsulation in the zeolite matrix (E 36.4%) was obtained. The probable host-quest interactions include Van der Waals interactions, H-bonds and chemical interactions between CAF functional groups and zeolite silanol groups, as well as parallel intraparticle diffusion of drug molecules in the mesopores of the mineral particles. The analyses of the experimental results indicated that natural zeolite could be successfully applied for encapsulating CAF.


Keywords


Caffeine; Kinetics; Sorption; Equilibrium; Drug-delivery; Natural zeolite

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DOI: 10.5155/eurjchem.6.2.169-173.1228

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Funding information


Project No. 4 OUP, Trakia University, Stara Zagora, Bulgaria

Citations

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[1]. Yu-Ta Chung, Chih-Kai Wang, Kai-Sung Wang, Sin-Yi Huang, Shih-Hsien Chang
Facile modification of graphite sheet by novel electrochemical exfoliation/oxidant method and its adsorption of caffeine from water
Journal of the Taiwan Institute of Chemical Engineers  80, 747, 2017
DOI: 10.1016/j.jtice.2017.09.012
/


[2]. Zvezdelina Yaneva, Nedyalka Georgieva, Manuela Staleva
Development of d,l-α-tocopherol acetate/zeolite carrier system: equilibrium study
Monatshefte für Chemie - Chemical Monthly  147(7), 1167, 2016
DOI: 10.1007/s00706-016-1714-x
/


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How to cite


Yaneva, Z.; Staleva, M.; Georgieva, N. Eur. J. Chem. 2015, 6(2), 169-173. doi:10.5155/eurjchem.6.2.169-173.1228
Yaneva, Z.; Staleva, M.; Georgieva, N. Study on the host-guest interactions during caffeine encapsulation into zeolite. Eur. J. Chem. 2015, 6(2), 169-173. doi:10.5155/eurjchem.6.2.169-173.1228
Yaneva, Z., Staleva, M., & Georgieva, N. (2015). Study on the host-guest interactions during caffeine encapsulation into zeolite. European Journal of Chemistry, 6(2), 169-173. doi:10.5155/eurjchem.6.2.169-173.1228
Yaneva, Zvezdelina, Manuela Stoyanova Staleva, & Nedyalka Valkanova Georgieva. "Study on the host-guest interactions during caffeine encapsulation into zeolite." European Journal of Chemistry [Online], 6.2 (2015): 169-173. Web. 2 Jun. 2020
Yaneva, Zvezdelina, Staleva, Manuela, AND Georgieva, Nedyalka. "Study on the host-guest interactions during caffeine encapsulation into zeolite" European Journal of Chemistry [Online], Volume 6 Number 2 (30 June 2015)

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DOI Link: https://doi.org/10.5155/eurjchem.6.2.169-173.1228

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