European Journal of Chemistry

Alum [KAl(SO4)2•12H2O] catalyzed microwave assisted synthesis of 5-arylidine-2-(methylthio)-thiazolone derivatives in water

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Published: Dec 31, 2015
DOI: https://doi.org/10.5155/eurjchem.6.4.410-416.1312
Keywords:
Alum, Water, Aldehyde, Rhodanine, Triethyl amine, Microwave-assisted synthesis
Section
Research Article
Issue
Vol. 6 No. 4 (2015): December 2015
Dates
Received 2015-08-22
Accepted 2015-09-19
Published 2015-12-31


Main Article Content

Santosh Jadhav
Department of Chemistry, Vivekanand College, Aurangabad, MS, 431001, India
Mahesh Shioorkar
Department of Chemistry, Vivekanand College, Aurangabad, MS, 431001, India
Omprakash Chavan
Department of Chemistry, Barwale College, Jalna, MS, 431203, India
Aniket Sarkate
Department of Chemical Technology, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, MS, 431001, India
Devanand Shinde
Department of Chemical Technology, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, MS, 431001, India
Rajendra Pardeshi
Department of Chemistry, Sant Ramdas College, Ghansawangi, Jalna, MS, 431203, India

Abstract

An efficient and environmentally benign method has been developed for the synthesis of 5-arylidine-2-(methylthio)-thiazolones derivatives using Alum [KAl(SO4)2·12H2O] catalyst and triethyl amine in water under microwave irradiation. This green transformation generated one C-S and one C-C bond, condensation and S-methylation. Notable advantages for the present protocol include, short reaction time, cleaner reaction profile and easy isolation of product by microwave irradiation technique using green catalyst and solvent.


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Jadhav, S.; Shioorkar, M.; Chavan, O.; Sarkate, A.; Shinde, D.; Pardeshi, R. Alum [KAl(SO4)2•12H2O] Catalyzed Microwave Assisted Synthesis of 5-Arylidine-2-(methylthio)-Thiazolone Derivatives in Water. Eur. J. Chem. 2015, 6, 410-416.

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Principal and Head, Department of Chemistry, Sant Ramdas College, Ghansawangi, Dist. Jalna affiliated to Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, 431004 (MS), India
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