European Journal of Chemistry 2016, 7(1), 49-55 | doi: https://doi.org/10.5155/eurjchem.7.1.49-55.1352 | Get rights and content

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Synthesis of porphyrins as precursors to PAMAM dendrimers and their metal chelating properties


Raquel Eunice Hernandez-Ramirez (1) , Irina Victorovna Lijanova (2,*) , Natalya Victorovna Likhanova (3) , Octavio Olivares-Xometl (4) , Luis Lartundo-Rojas (5)

(1) Instituto Politécnico Nacional, Centro de Investigación e Innovación Tecnológica, Cerrada Cecati S/N, Colonia Santa Catarina, Azcapotzalco, CP 02250, México D.F., México
(2) Instituto Politécnico Nacional, Centro de Investigación e Innovación Tecnológica, Cerrada Cecati S/N, Colonia Santa Catarina, Azcapotzalco, CP 02250, México D.F., México
(3) Instituto Mexicano del Petróleo, Dirección de Investigación y Posgrado, Eje Central Lázaro Cárdenas No. 152, Col. San Bartolo Atepehuacan, México D.F., 07730, México
(4) Benemérita Universidad Autónoma de Puebla, Facultad de Ingeniería Química, Av. San Claudio y 18 Sur, Col. San Manuel, Ciudad Universitaria, Puebla, 72570, México
(5) Centro de Nanociencias y Micro y Nanotecnologías, Luis Enrique Erro S/N, U. Profesional Adolfo López Mateos, Gustavo A. Madero, C.P. 07738 Ciudad de México, D.F, México
(*) Corresponding Author

Received: 28 Oct 2015 | Revised: 01 Dec 2015 | Accepted: 05 Dec 2015 | Published: 31 Mar 2016 | Issue Date: March 2016

Abstract


Novel meso-porphyrins were synthesized via microwave assistance and implemented as centers to polyamide amine (PAMAM) dendrimers. The molecular structures of the porphyrins were characterized by UV-Vis, 1H and 13C NMR spectroscopy. In addition, porphyrin-PAMAM dendrimers were characterized by 1H and 13C NMR spectroscopy. The molecular weight of the prepared dendrimers were confirmed by MALDI-TOF mass spectrometry. These porphyrin-core-PAMAM-modified dendrimers were used as templates to form Ag0 species and doped nylon membranes, using the XPS technique to confirm the chemical reduction of the metal cation.


Keywords


Chelating; Porphyrin; Metal species; Metal complex; PAMAM sendrimers; Microwave synthesis

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DOI: 10.5155/eurjchem.7.1.49-55.1352

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Funding information


The Instituto de Ciencia y Tecnología del Distrito Federal (296/2010) and by the Instituto Politécnico Nacional (SIP 20151065).

Citations

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[1]. M. Paula Militello, Raquel E. Hernández Ramírez, Irina V. Lijanova, Carlos M. Previtali, Sonia G. Bertolotti, Ernesto M. Arbeloa
PAMAM dendrimers with a porphyrin core as highly selective binders of Li+ in an alkaline mixture. A spectroscopic study
New Journal of Chemistry  43(41), 16246, 2019
DOI: 10.1039/C9NJ04088A
/

[2]. Mosa Alsehli, Shaya Y. Al-Raqa, Inan Kucukkaya, Paul R. Shipley, Brian D. Wagner, Alaa S. Abd-El-Aziz
Synthesis and Photophysical Properties of a Series of Novel Porphyrin Dendrimers Containing Organoiron Complexes
Journal of Inorganic and Organometallic Polymers and Materials  29(2), 628, 2019
DOI: 10.1007/s10904-018-1019-0
/

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How to cite


Hernandez-Ramirez, R.; Lijanova, I.; Likhanova, N.; Olivares-Xometl, O.; Lartundo-Rojas, L. Eur. J. Chem. 2016, 7(1), 49-55. doi:10.5155/eurjchem.7.1.49-55.1352
Hernandez-Ramirez, R.; Lijanova, I.; Likhanova, N.; Olivares-Xometl, O.; Lartundo-Rojas, L. Synthesis of porphyrins as precursors to PAMAM dendrimers and their metal chelating properties. Eur. J. Chem. 2016, 7(1), 49-55. doi:10.5155/eurjchem.7.1.49-55.1352
Hernandez-Ramirez, R., Lijanova, I., Likhanova, N., Olivares-Xometl, O., & Lartundo-Rojas, L. (2016). Synthesis of porphyrins as precursors to PAMAM dendrimers and their metal chelating properties. European Journal of Chemistry, 7(1), 49-55. doi:10.5155/eurjchem.7.1.49-55.1352
Hernandez-Ramirez, Raquel, Irina Victorovna Lijanova, Natalya Victorovna Likhanova, Octavio Olivares-Xometl, & Luis Lartundo-Rojas. "Synthesis of porphyrins as precursors to PAMAM dendrimers and their metal chelating properties." European Journal of Chemistry [Online], 7.1 (2016): 49-55. Web. 22 Jan. 2021
Hernandez-Ramirez, Raquel, Lijanova, Irina, Likhanova, Natalya, Olivares-Xometl, Octavio, AND Lartundo-Rojas, Luis. "Synthesis of porphyrins as precursors to PAMAM dendrimers and their metal chelating properties" European Journal of Chemistry [Online], Volume 7 Number 1 (31 March 2016)

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