European Journal of Chemistry

Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde

Main Article Content

Saeedeh Hashemian
Mahbobah Mangeli


Reaction of 4-pyridincarbohydrazide, 2-chlorobenzaldehyde and Cd(II) ion in ethanol resulted the complex trans-[Cd(H2O)4(C13H10N3ClO)2](NO3)2. The title complex was characte-rized by elemental analyses, UV-Vis and IR spectroscopy. The structure of complex also was established by single crystal X-ray diffraction analysis. The [Cd(H2O)4(C13H10N3ClO)2](NO3)2complex has monomeric structure with monoclinic crystal system and space group of P21/n, a = 7.7720(16) Å, b = 17.594(4) Å, c = 11.823(2) Å, β = 97.29(3)° with Z = 2. The cadmium atom in the crystal structure has octahedral geometry by coordination of the two nitrogen atoms of ligand and four oxygen atoms of water molecules.

icon graph This Abstract was viewed 1546 times | icon graph Article PDF downloaded 569 times icon graph Article CIF FILE downloaded 0 times

How to Cite
Hashemian, S.; Mangeli, M. Crystal Structure and Characterization of New Cadmium Complex from 4-Pyridin-Carbohydrazide and 2-Chlorobenzaldehyde. Eur. J. Chem. 2017, 8, 101-104.

Article Details

Crossref - Scopus - Google - European PMC

[1]. Sah, P. P.; Peoples, S. A. J. Am. Pharm. Assoc. Am. Pharm. Assoc. 1954, 43(9), 513-524.

[2]. Singh, B.; Narang, K. K.; Srivastava, R. Synth. React. Inorg. Met. Org. Chem. 2002, 32(9), 1419-1577.

[3]. Naran, K. K.; Singh, V. P. Syn. React. Inorg. Met. Org. Chem. 1997, 27, 721-725.

[4]. Cesur, Z.; Buyuktimkin, S.; Buyuktimkin, N.; Derbentli, S. Archiv der Pharmazie 1990, 323, 141-144.

[5]. Bottari, B.; Maccari, R.; Monforte, F.; Ottana, R.; Rotondo, E.; Vigorita, M. G. Bioorg. Med. Chem. Lett. 2000, 10, 657-660.

[6]. Pahlavani, L.; Kargar, H.; Sepehri, R.; Zahedan, N. J. Res. Med. Sci. 2015, 17(7), 7-10.

[7]. Rodrigues, F. A. R.; Oliveira-Augusto, C. A.; Cavalcanti, B. C.; Pessoa, C.; Pinheiro, A. C.; Souza, M. V. N. Sci. Pharm. 2014, 82(1), 21-28.

[8]. Khan, M. S. Y.; Chawla, M. A. Indian J. Chem. B 2004, 43, 1302-1305.

[9]. Liu, L; Alam, M. S.; Lee, D. U. Bull. Korean Chem. Soc. 2012, 33(10), 3361-3367.

[10]. Mohan, M. G.; Chandra, M. P.; Jha, L. N. K. Inorg. Chim. Acta 1988, 151, 61-68.

[11]. Sinh, R. B.; Jain, P. Talanta 1982, 29, 77-84.

[12]. Kriza, I.; Oprea, O.; Stanica, N. Revista de Chimie Bucharest Orig. Edi. 2010, 61(8), 733-739.

[13]. Mitu, L.; Ilis, M.; Raman, N.; Imran, M.; Ravichandran, S. E-J. Chem. 2012, 9(1), 365-372.

[14]. Fu, Z.; Gao, S.; Liu, S. Acta Crystallog. C 2007, 63, m459-m461.

[15]. Jian, G.; Xian-Hui, A.; Tong-Tao, X.; Yi-Cui, J.; Da-Qi, W. Syn. React. Inorg. Met. Org. Chem. 2006, 36(10), 753-757.

[16]. Ming-Liang, L.; Qiong, Y. Acta Crystallog. C. 2013, 69, 17-20.

[17]. Sheldrick, G. M. SHELX-97, Program for the Solution and Refinement of Crystal Structures; University of Göttingen: Germany, 1997.

[18]. Kriza, A.; Ababei, L.; Stanica, N.; Rau, I. Rev. Chim. (Bucuresti) 2009, 60(8), 774-777.

[19]. Kriza, A.; Pricop, L.; Meghean, A. J. Indian Chem. Soc. 2001, 78, 448-452.

Supporting Agencies

Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
Most read articles by the same author(s)

Dimensions - Altmetric - scite_ - PlumX

Downloads and views


Download data is not yet available.


Metrics Loading ...
License Terms

License Terms


Copyright © 2024 by Authors. This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License ( By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution, or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License ( are administered by Atlanta Publishing House LLC (European Journal of Chemistry).