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Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde
Saeedeh Hashemian (1,*) , Mahbobah Mangeli (2)
(1) Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
(2) Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
(*) Corresponding Author
Received: 15 Jan 2017 | Revised: 02 Mar 2017 | Accepted: 02 Mar 2017 | Published: 30 Jun 2017 | Issue Date: June 2017
Reaction of 4-pyridincarbohydrazide, 2-chlorobenzaldehyde and Cd(II) ion in ethanol resulted the complex trans-[Cd(H2O)4(C13H10N3ClO)2](NO3)2. The title complex was characte-rized by elemental analyses, UV-Vis and IR spectroscopy. The structure of complex also was established by single crystal X-ray diffraction analysis. The [Cd(H2O)4(C13H10N3ClO)2](NO3)2complex has monomeric structure with monoclinic crystal system and space group of P21/n, a = 7.7720(16) Å, b = 17.594(4) Å, c = 11.823(2) Å, β = 97.29(3)° with Z = 2. The cadmium atom in the crystal structure has octahedral geometry by coordination of the two nitrogen atoms of ligand and four oxygen atoms of water molecules.
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Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
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DOI Link: https://doi.org/10.5155/eurjchem.8.2.101-104.1544
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European Journal of Chemistry 2017, 8(2), 101-104 | doi: https://doi.org/10.5155/eurjchem.8.2.101-104.1544 | Get rights and content
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