European Journal of Chemistry

Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde

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Published: Jun 30, 2017
DOI: https://doi.org/10.5155/eurjchem.8.2.101-104.1544
Keywords:
Cd complex, Trans-complex, Octahedral geometry, 2-Chlorobenzaldehyde, Single crystal structure, 4-Pyridin-carbohydrazide
Section
Research Article
Issue
Vol. 8 No. 2 (2017): June 2017
Dates
Received 2017-01-15
Accepted 2017-03-02
Published 2017-06-30


Main Article Content

Saeedeh Hashemian
Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
Mahbobah Mangeli
Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran

Abstract

Reaction of 4-pyridincarbohydrazide, 2-chlorobenzaldehyde and Cd(II) ion in ethanol resulted the complex trans-[Cd(H2O)4(C13H10N3ClO)2](NO3)2. The title complex was characte-rized by elemental analyses, UV-Vis and IR spectroscopy. The structure of complex also was established by single crystal X-ray diffraction analysis. The [Cd(H2O)4(C13H10N3ClO)2](NO3)2complex has monomeric structure with monoclinic crystal system and space group of P21/n, a = 7.7720(16) Å, b = 17.594(4) Å, c = 11.823(2) Å, β = 97.29(3)° with Z = 2. The cadmium atom in the crystal structure has octahedral geometry by coordination of the two nitrogen atoms of ligand and four oxygen atoms of water molecules.


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Hashemian, S.; Mangeli, M. Crystal Structure and Characterization of New Cadmium Complex from 4-Pyridin-Carbohydrazide and 2-Chlorobenzaldehyde. Eur. J. Chem. 2017, 8, 101-104.

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Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
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