European Journal of Chemistry 2017, 8(2), 101-104. doi:10.5155/eurjchem.8.2.101-104.1544

Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde


Saeedeh Hashemian (1,*) , Mahbobah Mangeli (2)

(1) Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
(2) Department of Chemistry, Islamic Azad University, Yazd Brunch, Yazd, 89195-155, Iran
(*) Corresponding Author

Received: 15 Jan 2017, Accepted: 02 Mar 2017, Published: 30 Jun 2017

Abstract


Reaction of 4-pyridincarbohydrazide, 2-chlorobenzaldehyde and Cd(II) ion in ethanol resulted the complex trans-[Cd(H2O)4(C13H10N3ClO)2](NO3)2. The title complex was characte-rized by elemental analyses, UV-Vis and IR spectroscopy. The structure of complex also was established by single crystal X-ray diffraction analysis. The [Cd(H2O)4(C13H10N3ClO)2](NO3)2complex has monomeric structure with monoclinic crystal system and space group of P21/n, a = 7.7720(16) Å, b = 17.594(4) Å, c = 11.823(2) Å, β = 97.29(3)° with Z = 2. The cadmium atom in the crystal structure has octahedral geometry by coordination of the two nitrogen atoms of ligand and four oxygen atoms of water molecules.


Keywords


Cd complex; Trans-complex; Octahedral geometry; 2-Chlorobenzaldehyde; Single crystal structure; 4-Pyridin-carbohydrazide

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DOI: 10.5155/eurjchem.8.2.101-104.1544

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How to cite


Hashemian, S.; Mangeli, M. Eur. J. Chem. 2017, 8(2), 101-104. doi:10.5155/eurjchem.8.2.101-104.1544
Hashemian, S.; Mangeli, M. Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde. Eur. J. Chem. 2017, 8(2), 101-104. doi:10.5155/eurjchem.8.2.101-104.1544
Hashemian, S., & Mangeli, M. (2017). Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde. European Journal of Chemistry, 8(2), 101-104. doi:10.5155/eurjchem.8.2.101-104.1544
Hashemian, Saeedeh, & Mahbobah Mangeli. "Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde." European Journal of Chemistry [Online], 8.2 (2017): 101-104. Web. 23 Oct. 2019
Hashemian, Saeedeh, AND Mangeli, Mahbobah. "Crystal structure and characterization of new cadmium complex from 4-pyridin-carbohydrazide and 2-chlorobenzaldehyde" European Journal of Chemistry [Online], Volume 8 Number 2 (30 June 2017)

DOI Link: https://doi.org/10.5155/eurjchem.8.2.101-104.1544

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