Email this article 
Hide
Show all
OPEN ACCESS | 
PEER-REVIEWED |
RESEARCH ARTICLE
|
DOWNLOAD PDF
|
VIEW FULL-TEXT PDF
| TOTAL VIEWS
Synthesis, characterization, magnetic, thermal and redox properties of oxovanadium(IV) complex of heterocyclic acid hydrazone
Jyothy Gopurathinkal Vijayan (1,*)
(1) Department of Chemistry, Christ University, Bengaluru-29, Karnataka, India
(*) Corresponding Author
Received: 30 Mar 2017 | Revised: 02 Jul 2017 | Accepted: 14 Aug 2017 | Published: 31 Dec 2017 | Issue Date: December 2017
Abstract
The hydrazone ligand obtained from 2-thiophene carboxaldehyde and nicotinic hydrazide reacts with equimolar mixture of vanadyl acetyl acetonate in methanol to yield oxovanadium(IV) complex with 2-thiophenecarba nicotinic hydrazone. The prepared compound shows effective solubility in organic solvents such as acetonitrile, DMF and DMSO. Molar conductivity data of the complex revealed its non-electrolytic behavior in DMF and DMSO. EPR spectra of 2-thiophenecarba nicotinic hydrazonato oxovanadium(IV) was recorded in DMF at LNT and g and A values were calculated. The complex was proposed to be square pyramidal in geometry. Cyclic voltammogram of the complex in DMF was studied by changing the scan rates 50, 100, and 200 mV/sec. ΔE values of the complex showed the reversible criterion and ipc/ipa values which were close to 1 indicating that the redox couple as reversible. Thermogram of the complex was recorded to find the weight loss at different temperature ranges. Matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) mass spectra showed mass number of the molecular ions.
Announcements
One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and May 31, 2023 (Voucher code: SPONSOR2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF
DOI: 10.5155/eurjchem.8.4.328-332.1571
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics
This Abstract was viewed 919 times |
PDF Article downloaded 448 times
Funding information
Christ University, Bengaluru-29, Karnataka, India.
Citations
[1]. Alice Prudente Borges, Claudia Cristina Gatto, Victor Marcelo Deflon, Pedro Ivo Da Silva Maia
A dimeric oxidovanadium(V) complex derived from a hydrazonate ligand with an unusual asymmetrically bridged μ-(oxido)μ-(H2O){oxidovanadium(V)}2 core
European Journal of Chemistry 11(1), 1, 2020
DOI: 10.5155/eurjchem.11.1.1-5.1948
References
[1]. Sanjay, E. R.; Rao, A. K.; Yadav, H. S. Curr. Res. Chem. 2011, 3, 106-114.
https://doi.org/10.3923/crc.2011.106.113
[2]. Tahseen, A.; Jabbar, S.; Omar, N. J. Chem. Central 2013, 54, 111-117.
[3]. Rosu, T.; Pahontu, E.; Maxim, C.; Gulea, A. Polyhedron 2010, 29, 757-766.
https://doi.org/10.1016/j.poly.2009.10.017
[4]. Chohan, Z. H.; Sumrra, S. H.; Youssoufi, M. H. Hadda, T. B. Eur. J. Med. Chem. 2010, 45, 3981-3998.
[5]. Jian, L.; Liu, T.; Cai, S.; Wang, X. Inorg. Biochem. 2006, 100, 1888-1896.
https://doi.org/10.1016/j.jinorgbio.2006.07.014
[6]. Nomura, K.; Sagara, A.; Imanishi, Y. Macromolecules 2002, 35, 1583-1590.
https://doi.org/10.1021/ma0117413
[7]. Maurya, M. R. Coord. Chem. Rev. 2003, 237, 163-181.
https://doi.org/10.1016/S0010-8545(02)00293-X
[8]. Rahman, B.; Husseine, H.; Zoppelaro, G. Dalton Trans. 2013, 42, 2803-2812.
https://doi.org/10.1039/C2DT31751F
[9]. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81-122.
https://doi.org/10.1016/S0010-8545(00)80009-0
[10]. Mangalam, N. A.; Kurup, M. R. P. Spectrochim. Acta 2009, 71, 2040-2044.
https://doi.org/10.1016/j.saa.2008.07.043
[11]. Abdel-Latif, S. A.; Hassib, H. B.; Issa, Y. M. Spectrochim. Acta 2007, 67, 950-957.
https://doi.org/10.1016/j.saa.2006.09.013
[12]. Mishra, A. P.; Tiwari, A.; Jain, R. Int. J. Res. Pharm. Sci. 2011, 3, 167-172.
[13]. Collison, D.; Gahan, B.; Garner, C. D. J. Chem. Soc. Dalton Trans. 1980, 667-674.
https://doi.org/10.1039/dt9800000667
[14]. Dickson, F. E.; Kunesh, C. J.; McGinnis, E. L. Anal. Chem. 1972, 44, 978-998.
https://doi.org/10.1021/ac60314a009
[15]. Clich, P. R.; Daniher, A. T.; Challen, P. R. Inorg. Chem. 1996, 35, 347-356.
https://doi.org/10.1021/ic950792b
[16]. Davidson, A.; Edelstein, N.; Holm, R. H. J. Am. Chem. Soc. 1964, 86, 2799-2813.
https://doi.org/10.1021/ja01068a010
[17]. Dianu, M. L.; Kriza, A.; Musuc, A. M.; Kuriakose, M.; Kurup, M. R. P.; Suresh, E. Struct. Chem. 2007, 18, 579-584.
https://doi.org/10.1007/s11224-007-9187-5
[18]. Ray, A.; Banerjee, S.; Sen, S.; Butcher, R. J.; Mitra, S. Struct. Chem. 2008, 19, 209-217.
https://doi.org/10.1007/s11224-007-9274-7
[19]. Mangalam, N. A.; Sheeja, S. R.; Kurup, M. R. P. Polyhedron 2010, 9, 3318-3323.
https://doi.org/10.1016/j.poly.2010.09.007
[20]. Sen, S.; Mitra, M.; Hughes, D. L. Polyhedron 2007, 26, 1740-1744.
https://doi.org/10.1016/j.poly.2006.12.015
[21]. Datta, A.; Das, K.; Jhou, Y. M.; Huang, J. H.; Lee, H. M. Acta Cryst. E 2010, 66, m1271-m1271.
https://doi.org/10.1107/S1600536810034860
[22]. Koh, L. L.; Kon, O. L.; Loh, K. W.; Long, Y. C. Biochem. 1988, 72, 155-162.
[23]. Sreeja, P. B.; Kurup, M. R. P.; Kisore, A. Polyhedron 2004, 23, 575-581.
https://doi.org/10.1016/j.poly.2003.11.005
[24]. Li, S.; Gao, S.; Liu, S. Cryst. Growth Des. 2010, 10, 495-503.
https://doi.org/10.1021/cg9000945
[25]. Sridhar, S.; Saravanan, M.; Ramesh, A. Eur. J. Med. Chem. 2013, 36, 615-625.
https://doi.org/10.1016/S0223-5234(01)01255-7
[26]. Pandey, M. K. R.; Devi, S.; Sreeja, P. B. Asian J. Chem. 2015, 27, 4135-4137.
https://doi.org/10.14233/ajchem.2015.19115
[27]. Rao, S. N.; Mishra, D. D.; Maurya, R. C.; Rao, N. N. Polyhedron 1997, 16, 1825-1829.
https://doi.org/10.1016/S0277-5387(96)00487-1
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.8.4.328-332.1571
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
| 
Save to Zotero
Save to Mendeley
European Journal of Chemistry 2017, 8(4), 328-332 | doi: https://doi.org/10.5155/eurjchem.8.4.328-332.1571 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c)
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.