European Journal of Chemistry 2017, 8(4), 367-370 | doi: https://doi.org/10.5155/eurjchem.8.4.367-370.1636 | Get rights and content

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Synthesis, characterization and biological activity of some nickel(II) mixed ligands complexes of dithiocarbamate and 1,10-phenanthroline


Salih Hamza Abbas (1,*)

(1) Department of Chemistry, College of Science, University of Basrah, Basrah, 61004, Iraq
(*) Corresponding Author

Received: 11 Aug 2017 | Revised: 23 Sep 2017 | Accepted: 07 Oct 2017 | Published: 31 Dec 2017 | Issue Date: December 2017

Abstract


Two ligands; pyrrolidine-1-carbodithioate sodium (L1) and piperidine-1-carbodithioate sodium salt(L2) and their nickel(II) mixed ligands complexes with 1,10-phenanthroline (L3) have been synthesized and characterized by FT-IR, UV-visible,1H NMR spectra. The biological activities of these complexes were also evaluated. The spectral data indicated that the 1,10-phenanthrolineand dithiocarbamate ligands are considered as a bidentate nitrogen and sulfur ligands, respectively. The study suggested that the above ligands formed complexes of general formula [Ni(Lx)2(L3)1] and [Ni(Lx)1(L3)2]Cl (x=1 or 2) mononuclear (monomer) complexes. The complexes show moderate and selective activity against tested microorganisms.


Keywords


Sulfur ligands; Bidentate nitrogen ligands; Heterocyclicdithiocarbamate; Tetramethylenedithiocarbimate; Pentamethylenedithiocarbimate; Nickel(II) mixed ligand complexes

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DOI: 10.5155/eurjchem.8.4.367-370.1636

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[1]. Ahmed S.M. Al‐Janabi, Mustafa M. Kadhim, Amenah I.A. Al‐Nassiry, Tarek A. Yousef
Antimicrobial, computational, and molecular docking studies of Zn (II) and Pd (II) complexes derived from piperidine dithiocarbamate
Applied Organometallic Chemistry  35(2), , 2021
DOI: 10.1002/aoc.6108
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[2]. Arumugam Jayamani, Rajesh Bellam, Gopalakrishnan Gopu, Stephen O. Ojwach, Nallathambi Sengottuvelan
Copper(II) complexes of bidentate mixed ligands as artificial nucleases: Synthesis, crystal structure, characterization and evaluation of biological properties
Polyhedron  156, 138, 2018
DOI: 10.1016/j.poly.2018.09.011
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[3]. Ayodele T. Odularu, Peter A. Ajibade
Dithiocarbamates: Challenges, Control, and Approaches to Excellent Yield, Characterization, and Their Biological Applications
Bioinorganic Chemistry and Applications  2019, 1, 2019
DOI: 10.1155/2019/8260496
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[4]. Faisal Hayat, Rana Faryad Ali, Zia ur Rehman, Francine Bélanger-Gariepy
Molecular, supramolecular, DNA-binding and biological studies of piperazine and piperidine based dithiocarbamates of biocompatible copper
Inorganic Chemistry Communications  121, 108190, 2020
DOI: 10.1016/j.inoche.2020.108190
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How to cite


Abbas, S. Eur. J. Chem. 2017, 8(4), 367-370. doi:10.5155/eurjchem.8.4.367-370.1636
Abbas, S. Synthesis, characterization and biological activity of some nickel(II) mixed ligands complexes of dithiocarbamate and 1,10-phenanthroline. Eur. J. Chem. 2017, 8(4), 367-370. doi:10.5155/eurjchem.8.4.367-370.1636
Abbas, S. (2017). Synthesis, characterization and biological activity of some nickel(II) mixed ligands complexes of dithiocarbamate and 1,10-phenanthroline. European Journal of Chemistry, 8(4), 367-370. doi:10.5155/eurjchem.8.4.367-370.1636
Abbas, Salih. "Synthesis, characterization and biological activity of some nickel(II) mixed ligands complexes of dithiocarbamate and 1,10-phenanthroline." European Journal of Chemistry [Online], 8.4 (2017): 367-370. Web. 19 Oct. 2021
Abbas, Salih. "Synthesis, characterization and biological activity of some nickel(II) mixed ligands complexes of dithiocarbamate and 1,10-phenanthroline" European Journal of Chemistry [Online], Volume 8 Number 4 (31 December 2017)

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