European Journal of Chemistry

Synthesis, characterization and antioxidant activity of Schiff base and its metal complexes with Fe(II), Mn(II), Zn(II), and Ru(II) ions: Catalytic activity of ruthenium(II) complex

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Published: Mar 31, 2018
DOI: https://doi.org/10.5155/eurjchem.9.1.22-29.1671
Keywords:
Metal complexes, Thiophene ligand, Catalytic properties, Structure elucidation, Antioxidant properties, Transfer hydrogenation
Section
Research Article
Issue
Vol. 9 No. 1 (2018): March 2018
Dates
Received 2017-11-13
Accepted 2017-12-13
Published 2018-03-31
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Main Article Content

Nevin Turan
Department of Chemistry, Faculty of Arts and Sciences, Mus Alparslan University, 49250 Mus, Turkey
https://orcid.org/0000-0001-6740-6812
Kenan Buldurun
Department of Chemistry, Faculty of Arts and Sciences, Mus Alparslan University, 49250 Mus, Turkey
https://orcid.org/0000-0002-2462-7006

Abstract

The synthesis, spectral, catalytic and antioxidant properties of ethyl-2-(2-hydroxy-3-methoxybenzylideneamino)-6-methyl-4,5,6-tetrahydrobenzo[b]thiophene-3-carboxylate (L) substituted iron(II), manganese(II), zinc(II), and ruthenium(II)-arene chlorides are described for the first time. The ligand and its metal complexes were characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, and spectral (1H NMR, 13C NMR, FT-IR, UV-Vis and Mass) techniques. The FT-IR spectra showed that the ligand can act as bidentate or tridentate. Magnetic moments and electronic spectral studies revealed an octahedral geometry for all the complexes obtained. The thermal behavior of the complexes showed that the water molecules were separated in the first step followed immediately by decomposition of the anions and ligand molecules in the subsequent steps. Ru(II) complex was used as catalysts for the transfer hydrogenation of ketones. At the same time, the effect of various bases such as NaOH, KOH, KOBut and NaOAc as organic base were investigated in the transfer hydrogenation of ketones by 2-propanol as the hydrogen source. The complexes and ligand were tested in vitro for their antioxidant activity. The experimental results showed that Ru(II) complex had more potent antioxidant activities than Zn(II), Fe(II), Mn(II) complexes and parent ligand.


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Turan, N.; Buldurun, K. Synthesis, Characterization and Antioxidant Activity of Schiff Base and Its Metal Complexes With Fe(II), Mn(II), Zn(II), and Ru(II) Ions: Catalytic Activity of ruthenium(II) Complex. Eur. J. Chem. 2018, 9, 22-29.

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Mus Alparslan University, 49250 Mus, Turkey.
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