European Journal of Chemistry

Crystal structure of a one-dimensional coordination polymer of gadolinium dibromoacetate with 4,4'-bipyridine

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Published: Sep 30, 2018
DOI: https://doi.org/10.5155/eurjchem.9.3.178-181.1742
Keywords:
Gd complex, 4, 4’-Bipyridine, Carboxylate ligands, Octahedral geometry, Coordination polymer, Single crystal structure
Section
Research Article
Issue
Vol. 9 No. 3 (2018): September 2018
Dates
Received 2018-05-28
Accepted 2018-06-18
Published 2018-09-30
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Leslaw Sieron
Institute of General and Ecological Chemistry, Department of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
http://orcid.org/0000-0002-7797-0262
Agnieszka Czylkowska
Institute of General and Ecological Chemistry, Department of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
http://orcid.org/0000-0001-7157-5408
Bartlomiej Rogalewicz
Institute of General and Ecological Chemistry, Department of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland.
http://orcid.org/0000-0002-9899-6402

Abstract

A new gadolinium(III) complex with 4,4’-bipyridine (4-bpy) and dibromoacetate ligand of general formula [Gd(4-bpy)(CBr2HCOO)3(H2O)]n, has been synthesized, crystallized and characterized by a single-crystal X-ray diffraction analysis. The gadolinium atom has an unsymmetrical eight-coordinate geometry, being coordinated by six oxygen atoms of dibromoacetate anions, one nitrogen atom of 4-bpy and one water molecule. The complex is a one-dimensional polymer as a result of dibromoacetate ligand bridging with the repeating monomeric units. There are π...π stacking interactions between the 4-bpy rings as well as O–H...O and O–H...N hydrogen bonds. Crystal Data for C16H13Br6GdN2O7 (Mw = 981.99 g/mol): triclinic, space group P-1 (no. 2), a = 9.7368(4) Å, b = 11.5416(4) Å, c = 11.7634(4) Å, α = 104.2750(10)°, β = 94.060(2)°, γ = 92.6900(10)°, V = 1275.08(8) Å3, Z = 2, T = 90 K, μ(CuKα) = 28.190 mm-1, Dcalc = 2.558 g/cm3, 8399 reflections measured (7.782° ≤ 2Θ ≤ 133.18°), 4006 unique (Rint = 0.0409, Rsigma = 0.0639) which were used in all calculations. The final R1 was 0.0527 (I > 2σ(I)) and wR2 was 0.1396 (all data).


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Sieron, L.; Czylkowska, A.; Rogalewicz, B. Crystal Structure of a One-Dimensional Coordination Polymer of Gadolinium Dibromoacetate With 4,4’-Bipyridine. Eur. J. Chem. 2018, 9, 178-181.

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