

Synthesis of nanocellulose/cobalt oxide composite for efficient degradation of Rhodamine B by activation of peroxymonosulfate
Faouzia Khili (1,*)


(1) Unité de Recherche de Physique des Matériaux Lamellaires et Nanomatériaux Hybrides (PMLNH), Faculté des Sciences de Bizerte, Université de Carthage, 7000 Bizerte, Tunisia
(2) Laboratoire de Physico-Chimie des Matériaux Minéraux et Leurs Applications, Centre National des Recherches en Sciences des Matériaux, Technopôle de Bordj Cedria, BP73, 8027 Soliman, Tunisia
(*) Corresponding Author
Received: 16 Sep 2018 | Revised: 17 Oct 2018 | Accepted: 20 Oct 2018 | Published: 31 Mar 2019 | Issue Date: March 2019
Abstract
In recent years, nanofibrous materials derived from biopolymers have attracted more interest due to their numerous applications. In our study, a simple composite of cellulose nanocrystals, and cobalt oxide nanoparticles was elaborated using sodium borohydride as a chemical reducer. It has been shown that Co3O4 nanoparticles were grown on the surface of cellulose nanocrystals. An important quantity of cobalt oxide nanoparticles was detected using ICP-OES (13.5 g contained in 100 mg of the composite). The size, the morphology and the thermal stability of the composite and the obtained nanoparticles were studied using X-ray powder diffraction, Fourier-transform infrared spectroscopy, Ultraviolet-Visible spectrophotometry, Scanning electron microscopic and Transmission electron microscopic. Our obtained material was used for the degradation of Rhodamine B and it was succeeded in degradation of Rhodamine B within very short period of time (16 min). The catalytic degradation of Rhodamine B was investigated and analyzed with UV-Visible absorption spectra.
Announcements
One of our sponsors will cover the article processing fee for all submissions made between May 17, 2023 and June 16, 2023 (Voucher code: SPONSOR2023).
Editor-in-Chief
European Journal of Chemistry
Keywords
Full Text:
PDF

DOI: 10.5155/eurjchem.10.1.19-25.1789
Links for Article
| | | | | | |
| | | | | | |
| | | |
Related Articles
Article Metrics


Citations
References
[1]. Klemm, D.; Heublein, B.; Fink, H. P.; Bohn, A. Angew. Chem. Int. Ed. 2005, 44, 3358-3393.
https://doi.org/10.1002/anie.200460587
[2]. Sjostrom, E, Wood Chemistry: Fundamentals and applications, Academic Press Inc., England, 1993.
[3]. George, J.; Sabapathi, S. N.; Siddaramaiah, Water Soluble Polymer-Based Nanocomposites Containing Cellulose Nanocrystals. In: Thakur V., Hakur M. (eds) Eco-friendly Polymer Nanocomposites. Advanced Structured Materials, vol. 75, pp. 259-293, Springer, New Delhi, 2015.
[4]. Eichhorn, S. J.; Baillie, C. A.; Zafeiropoulos, N.; Mwaikambo, L. Y.; Ansell , M. P.; Dufresne, A.; Entwistle, K. M.; Herrera-Franco, P. J.; Escamilla, G. C.; Groom, L. H.; Hughes, M.; Hill, C.; Rials, T. G.; Wild, P. M. J. Mater. Sci. 2001, 36, 2107-2131.
https://doi.org/10.1023/A:1017512029696
[5]. Masaoka, S.; Ohe, T.; Sakota, N. J. Ferment. Bioeng. 1993, 75, 18-22.
https://doi.org/10.1016/0922-338X(93)90171-4
[6]. Habibi, Y.; Lucia, L. A.; Rojas, O. J. Chem. Rev. 2010, 110, 3479-3500.
https://doi.org/10.1021/cr900339w
[7]. Ahmad, N.; Wahab, R.; Al-Omar, S. Eur. J. Chem. 2014, 5(2), 247-251.
https://doi.org/10.5155/eurjchem.5.2.247-251.971
[8]. Moon, R. J.; Martini, A.; Nairn, J.; Simonsen, J.; Young, B. J. Chem. Soc. Rev. 2011, 40, 3941-3994.
https://doi.org/10.1039/c0cs00108b
[9]. Iwamoto, S.; Kai, W.; Isogai, A.; Iwata, T. Biomacromol. 2009, 10, 2571-2576.
https://doi.org/10.1021/bm900520n
[10]. Lahiji, R. R.; Xu, X.; Reifenberger, R.; Raman, A.; Rudie, A.; Moon, R. J. Langmuir 2010, 26, 4480-4488.
https://doi.org/10.1021/la903111j
[11]. Sturcova, A.; Davies, G. R.; Eichhorn, S. J. Biomacromol. 2005, 6, 1055-1061.
https://doi.org/10.1021/bm049291k
[12]. Revol, J. F.; Bradford, H.; Giasson, J.; Marchessault, R. H.; Gray, D. G. Int. J. Biol. Macromol. 1992, 14, 170-172.
https://doi.org/10.1016/S0141-8130(05)80008-X
[13]. Orts, W. J.; Godbout, L.; Marchessault, R. H.; Revol, J. F. Macromol. 1998, 31, 5717-5725.
https://doi.org/10.1021/ma9711452
[14]. Azizi, S.; Alloin, F.; Sanchez, J. Y.; El Kissi, N.; Dufresne, A. Macromol. 2004, 37, 1386-1393.
https://doi.org/10.1021/ma030532a
[15]. Araki, J.; Wada, M.; Kuga, S.; Okano, T. J. Wood Sci. 1999, 45, 258-261.
https://doi.org/10.1007/BF01177736
[16]. Romany, M.; Shuping, D.; Hirani, A.; Yong, W. L. ACS symposium series. Vol. 1017. Oxford University Press, Cellulose nanocrystals for drug delivery; pp. 81-91, 2009.
[17]. Lam, E.; Male, K. B.; Chong, J. H.; Leung, A. C.; Luong, J. H. Trends Biotechnol. 2012, 30, 283-290.
https://doi.org/10.1016/j.tibtech.2012.02.001
[18]. Taheri, A.; Mohammadi, M. Chem. Biol. Drug. Des. 2015, 86, 102-106.
https://doi.org/10.1111/cbdd.12466
[19]. Jackson, J. K.; Letchford. K.; Wasserman, B. Z.; Ye, L.; Hamad, W. Y.; Burt, H. M. Int. J. Nanomedic. 2011, 6, 321-330.
[20]. Kandalkar, S. G.; Dhawale, D. S.; Kim, C. K.; Lokhande, C. D. Synth. Met. 2010, 160, 1299-1302.
https://doi.org/10.1016/j.synthmet.2010.04.003
[21]. Yoshino, T.; Baba, N. Sol. Energ. Mat. Sol. C 1995, 39, 391-397.
[22]. Okabe, H.; Akimitsu, J.; Kubodera, T.; Matoba, M.; Kyomen, T.; Itoh, M. Phys. B Condens. Matter. 2006, 378-380, 863-864.
[23]. Rashkova, V.; Kitora, S.; Konstantinov, I.; Vitahov, T. Electrochim. Acta 2002, 47, 1555-1560.
https://doi.org/10.1016/S0013-4686(01)00897-0
[24]. Ding, Y.; Wang, Y.; Su, L.; Bellagamba, M.; Zhang, H.; Lei, Y. Biosens. Bioelectron. 2010, 26, 542-548.
https://doi.org/10.1016/j.bios.2010.07.050
[25]. Buratti, S.; Brunetti, B.; Mannino, S. Talanta 2008, 76, 454-457.
https://doi.org/10.1016/j.talanta.2008.03.031
[26]. Xia, Y. S.; Dai, H. X.; Jiang, H. Y.; Zhang, L. Catal. Commun. 2010, 11, 1171-1175.
https://doi.org/10.1016/j.catcom.2010.07.005
[27]. Hou, Y.; Ndamanisha, J. C.; Guo, L. P.; Peng, X. J.; Bai, J. Electrochim. Acta 2009, 54, 6166-6171.
https://doi.org/10.1016/j.electacta.2009.05.091
[28]. Salimi, A.; Hallaj, R.; Soltanian, S.; Mamkhezri, H. Anal. Chim. Acta 2007, 594, 24-31.
https://doi.org/10.1016/j.aca.2007.05.010
[29]. Salimi, A.; Mamkhezri, H.; Hallaj, R.; Soltanian, S. Sens Actuators B 2008, 129, 246-254.
https://doi.org/10.1016/j.snb.2007.08.017
[30]. Qi, Y. C.; Zhao, Y. B.; Wu, Z. S. Mater. Chem. Phys. 2008, 110, 457-462.
https://doi.org/10.1016/j.matchemphys.2008.03.001
[31]. Shinde, V. R.; Mahadik, S. B.; Gujar, T. P.; Lokhande, C. D. Appl. Surf. Sci. 2006, 252, 7487-7492.
https://doi.org/10.1016/j.apsusc.2005.09.004
[32]. Xia, X. H.; Tu, J. P.; Xiang, J. Y.; Huang, X. H.; Wang, X. L.; Zhao, X. B. Power Sources 2010, 195, 2014-2022.
https://doi.org/10.1016/j.jpowsour.2009.11.009
[33]. Casella, I. G.; Guascito, M. R. Electroanal. J. Chem. 1999, 476, 54-63.
https://doi.org/10.1016/S0022-0728(99)00366-6
[34]. Casella, I. G.; Gatta, M.; Electro. Anal. Chem. 2002, 534, 31-38.
https://doi.org/10.1016/S0022-0728(02)01100-2
[35]. Casella, I. G. J. Electroanal. Chem. 2002, 520, 119-125.
https://doi.org/10.1016/S0022-0728(02)00642-3
[36]. Hao, M.; Pegah, K.; Foroo, S.; Pratik, U. J.; Julie, O.; Xue, M.; Christa, M.; Rattapol, P.; Jonathan, K.; Ameya, N.; Weilue, H. M.; Frost, C.; Heldt, C. H.; Lee, B. P. Acta Biomaterialia 2019, 83, 109-118.
https://doi.org/10.1016/j.actbio.2018.10.032
[37]. Spataru, N.; Terashima, C.; Tokuhiro, K.; Sutanto, I.; Tryk, D. A.; Park, S. M.; Fujishima, A. J. Electrochem. Soc. 2003, 150, 337-334.
https://doi.org/10.1149/1.1579037
[38]. McNally, E. A.; Zhitomirsky, I.; Wilkinson, D. S. Mater. Chem. Phys. 2005, 91, 391-398.
https://doi.org/10.1016/j.matchemphys.2004.11.045
[39]. Figgis, B. N. Introduction to Ligand Fields, Interscience, New York, London, Sydney, 1996.
[40]. Faouzia, K.; Joao, B.; Pedro, L. A.; Rabah, B.; Amel, D. O. Waste Biomass. Valori. 2018, 18, 1-15.
[41]. Windisch, C. F.; Exarhos, G. J.; Owings, R. R. J. Appl. Phys. 2004, 95, 5435-5442.
https://doi.org/10.1063/1.1699505
[42]. Navale, S. T.; Liu, C.; Gaikar, P.; Patil, V.; Sagar, R. U. R.; Du, B.; Mane, R. S.; Staler, F. Sens. Actuators B Chem. 2017, 245, 524-532.
https://doi.org/10.1016/j.snb.2017.01.195
[43]. Zhou, T.; Lu, P.; Zhang, Z.; Wang, Q.; Umar, A. Sens. Actuators B Chem. 2016, 235, 457-465.
https://doi.org/10.1016/j.snb.2016.05.075
[44]. Makhlouf, M. T.; Abu-Zied, B. M.; Mansoure, T. H. Fuel J. Nanopart. 2013, 2013, 1-7.
[45]. Monaam, B. A.; Alexandre, B.; Ahmed, A.; Brigitte, S.; Habib, E.;, Mokhtar F.; Sabine, S.; Rabah, B. Phys. Chem. Chem. Phys. 2017, 19, 6569-6578.
[46]. Akir, S.;, Abderrahmane, H.; Ahmed, A.; Yannick, C.; Rabah B.; Amel, D. O. Appl. Surf. Sci. 2017, 400, 461-470.
https://doi.org/10.1016/j.apsusc.2016.12.212
[47]. Abdel-Hady, A. Eur. J. Chem. 2013, 4(3), 292-296.
https://doi.org/10.5155/eurjchem.4.3.292-296.795
How to cite
The other citation formats (EndNote | Reference Manager | ProCite | BibTeX | RefWorks) for this article can be found online at: How to cite item
DOI Link: https://doi.org/10.5155/eurjchem.10.1.19-25.1789

















European Journal of Chemistry 2019, 10(1), 19-25 | doi: https://doi.org/10.5155/eurjchem.10.1.19-25.1789 | Get rights and content
Refbacks
- There are currently no refbacks.
Copyright (c) 2019 Authors

This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).
© Copyright 2010 - 2023 • Atlanta Publishing House LLC • All Right Reserved.
The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.
Copyright 2010-2023 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 2850 Smith Ridge Trce Peachtree Cor GA 30071-2636, USA. Registered in USA.