European Journal of Chemistry 2019, 10(1), 64-71. doi:10.5155/eurjchem.10.1.64-71.1820

Investigation of nigrosine, alizarin, indigo and acid fuchsin removal by modification of CaO derived from eggshell with AgI: Adsorption, kinetic and photocatalytic studies


Ibtighaa Kadhim Radhi (1) orcid , Mouayed Abdulaali Hussein (2,*) orcid , Zaki Naser Kadhim (3) orcid

(1) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(2) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(3) Department of Chemistry, College of Science, University of Basrah, Basrah, 61001, Iraq
(*) Corresponding Author

Received: 24 Nov 2018, Accepted: 26 Dec 2018, Published: 31 Mar 2019

Abstract


Successful removal of nigrosine, alizarin, indigo and acid fuchsin dyes from aqueous solutions using modified CaO nanoparticles has been investigated. The CaO was obtained from eggshells and modified with AgI. The adsorbents were characterized using X-ray diffraction, energy dispersive X-ray spectroscopy, scanning electron microscopy and transmission electron microscopy. The kinetic studies were also investigated, the results showed that the adsorption of alizarin dye follows the pseudo-first-order model, while the adsorption of the nigrosine, indigo, and acid fuchsin follow the pseudo-second-order model onto modified and unmodified CaO. Moreover, the photocatalytic activity of modified adsorbent was tested under sunlight. The modified adsorbent showed a strong photocatalytic activity, a 0.01 g modified adsorbent was sufficient to absorb 100% of acid fuchsin through only 5 min after exposes to sunlight.


Keywords


SEM; TEM; Kinetics; Adsorption; Modification; Photocatalytic

Full Text:

PDF /    /


DOI: 10.5155/eurjchem.10.1.64-71.1820

Article Metrics


This Abstract was viewed 175 times | PDF Article downloaded 87 times

References

[1]. Angyu, C.; Yasuhiro, O.; Fumihide, S. Chem. Eng. J. 2010, 156, 98-105.
https://doi.org/10.1016/j.cej.2009.10.003

[2]. Hu, J.; Song, Z.; Chen, L.; Yang, H.; Li, J.; Richards, R. J. Chem. Eng. Data 2010, 55, 3742-3748.
https://doi.org/10.1021/je100274e

[3]. Hejazifar, M.; Azizian, S.; Sarikhan, H.; Li, Q.; Zhao, D. J. Anal. Appl Pyrolysis 2011, 92, 258-266.
https://doi.org/10.1016/j.jaap.2011.06.007

[4]. Belessi, V.; Romanos, G.; Boukos, N.; Lambropoulou, D.; Trapalis, C. J. Hazard. Mater. 2009, 170, 836-844.
https://doi.org/10.1016/j.jhazmat.2009.05.045

[5]. Tan, X.; Liu, Y.; Zeng, G.; Wang, X.; Hu, X.; Gu, Y.; Yang, Z. Chemosphere 2015, 125, 70-85.
https://doi.org/10.1016/j.chemosphere.2014.12.058

[6]. Ahmad, M.; Lee, S. S.; Dou, X.; Mohan, D.; Sung, J. K.; Yang, J. E.; Ok, Y. S. Bioresour. Technol. 2012, 118, 536-544.
https://doi.org/10.1016/j.biortech.2012.05.042

[7]. Robinson, T.; McMullan, G.; Marchant, R.; Nigam, P. Bioresour. Technol. 2001, 77, 247-255.
https://doi.org/10.1016/S0960-8524(00)00080-8

[8]. Muruganandham, M.; Amutha, R.; Lee, G. J.; Hsieh, S. H.; Wu, J. J.; Sillanpaa, M. J. Phys. Chem. C 2012, 116, 12906-12015.
https://doi.org/10.1021/jp302343f

[9]. Pimpaporn, S.; Sumpun, W. J. Sol-Gel Sci. Technol. 2014, 71, 86-95.
https://doi.org/10.1007/s10971-014-3327-3

[10]. Bhatnagar, A.; Sillanpaa, M. Chem. Eng. J. 2010, 157, 277-296.
https://doi.org/10.1016/j.cej.2010.01.007

[11]. Isık, M.; Sponza, D. T. Chemosphere 2004, 55, 119-128.
https://doi.org/10.1016/j.chemosphere.2003.10.008

[12]. Beak, M. H.; Ijagbemi, C. O.; Kim, D. O. J. Environ. Sci. Heal. A 2009, 44, 623-629.
https://doi.org/10.1080/10934520902784708

[13]. Lau, Y. Y.; Wong, Y. S.; Teng, T. T.; Morad, N.; Rafatullah, M.; Ong, S. A. Chem. Eng. J. 2014, 246, 383-390.
https://doi.org/10.1016/j.cej.2014.02.100

[14]. Venkata Mohan, S.; Karthikeyan, J. Clean Technol. Envir. J. 2004, 6, 196-212.

[15]. Nguyen-Phan, T. D.; Song, M. B.; Yun, H.; Kim, E. J.; Oh, E. S.; Shin, E. W. Appl. Surf. Sci. 2011, 27, 2024-2031.
https://doi.org/10.1016/j.apsusc.2010.09.046

[16]. Han, R.; Wang, Y.; Han, P.; Shi, J.; Yang, J.; Lu, Y. J. Hazard. Mater. 2006, 137, 550-554.
https://doi.org/10.1016/j.jhazmat.2006.02.029

[17]. Vadivelan, V.; Vasanth Kumar, K. J. Colloid Interface Sci. 2005, 286, 90-100.
https://doi.org/10.1016/j.jcis.2005.01.007

[18]. Otero, M.; Rozada, F.; Calvo, L. F.; Garcia, A. I.; Moran, A. Biochem. Eng. J. 2003, 15, 59-68.
https://doi.org/10.1016/S1369-703X(02)00177-8

[19]. Jafari, S.; Tryba, B.; Nejman, E.; Kozar, J.; Morawski, A. W.; Sillanpaa, M. J. Mol. Liq. 2016, 220, 504-512.
https://doi.org/10.1016/j.molliq.2016.02.014

[20]. Janus, M.; Kusiak, E.; Choina, J.; Ziebro, J.; Morawski, A. W. Desalination 2009, 249, 359-363.
https://doi.org/10.1016/j.desal.2009.04.013

[21]. Aksu, Z. Process Biochem. 2005, 40, 997-1026.
https://doi.org/10.1016/j.procbio.2004.04.008

[22]. Jafari, S.; Feiping Z.; Dongbo Z.; Manu L.; Amit B.; Mika S. J. Mol. Liq. 2015, 207, 90-98.
https://doi.org/10.1016/j.molliq.2015.03.026

[23]. Cheng, X.; Yu, X.; Xing, Z. Appl. Surf. Sci. 2012, 258, 3244-3248.
https://doi.org/10.1016/j.apsusc.2011.11.072

[24]. Koumanova, B.; Peeva, P.; Allen, S. J.; Gallagher, K. A.; Healy, M. G. J. Chem. Technol. Biotechnol. 2002, 77, 539-545.
https://doi.org/10.1002/jctb.601

[25]. Tsai, W. T.; Yang, J. M.; Lai, C. W.; Cheng, Y. H.; Lin, C. C.; Yeh, C. W. Bioresour. Technol. 2006, 97, 488-493.
https://doi.org/10.1016/j.biortech.2005.02.050

[26]. Saxen, B. Memoranda Soc. Fauna Flora Fennica 2011, 87, 29-40.

[27]. Aksu, Z. Sep. Purif. Technol. 2001, 21, 285-294.

[28]. Bulut, Y.; Baysal, Z. J. Environ. Manage. 2006, 78, 107-113.
https://doi.org/10.1016/j.jenvman.2005.03.010

[29]. Rauf, M. A.; Bukallah, S. B.; Hamour, F. A.; Nasir, A. S. Chem. Eng. J. 2008, 137, 238-243.
https://doi.org/10.1016/j.cej.2007.04.025

[30]. Banerjee, S.; Sharma, G. C.; Chattopadhyaya, M. C.; Sharma, Y. C. J. Environ. Chem. Eng. 2014, 2, 1870-1880.
https://doi.org/10.1016/j.jece.2014.06.020


How to cite


Radhi, I.; Hussein, M.; Kadhim, Z. Eur. J. Chem. 2019, 10(1), 64-71. doi:10.5155/eurjchem.10.1.64-71.1820
Radhi, I.; Hussein, M.; Kadhim, Z. Investigation of nigrosine, alizarin, indigo and acid fuchsin removal by modification of CaO derived from eggshell with AgI: Adsorption, kinetic and photocatalytic studies. Eur. J. Chem. 2019, 10(1), 64-71. doi:10.5155/eurjchem.10.1.64-71.1820
Radhi, I., Hussein, M., & Kadhim, Z. (2019). Investigation of nigrosine, alizarin, indigo and acid fuchsin removal by modification of CaO derived from eggshell with AgI: Adsorption, kinetic and photocatalytic studies. European Journal of Chemistry, 10(1), 64-71. doi:10.5155/eurjchem.10.1.64-71.1820
Radhi, Ibtighaa, Mouayed Abdulaali Hussein, & Zaki Naser Kadhim. "Investigation of nigrosine, alizarin, indigo and acid fuchsin removal by modification of CaO derived from eggshell with AgI: Adsorption, kinetic and photocatalytic studies." European Journal of Chemistry [Online], 10.1 (2019): 64-71. Web. 20 Nov. 2019
Radhi, Ibtighaa, Hussein, Mouayed, AND Kadhim, Zaki. "Investigation of nigrosine, alizarin, indigo and acid fuchsin removal by modification of CaO derived from eggshell with AgI: Adsorption, kinetic and photocatalytic studies" European Journal of Chemistry [Online], Volume 10 Number 1 (31 March 2019)

DOI Link: https://doi.org/10.5155/eurjchem.10.1.64-71.1820

Refbacks

  • There are currently no refbacks.


Bookmark and Share


Copyright (c) 2019 Authors

Creative Commons License
This work is published and licensed by Atlanta Publishing House LLC, Atlanta, GA, USA. The full terms of this license are available at http://www.eurjchem.com/index.php/eurjchem/pages/view/terms and incorporate the Creative Commons Attribution-Non Commercial (CC BY NC) (International, v4.0) License (http://creativecommons.org/licenses/by-nc/4.0). By accessing the work, you hereby accept the Terms. This is an open access article distributed under the terms and conditions of the CC BY NC License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited without any further permission from Atlanta Publishing House LLC (European Journal of Chemistry). No use, distribution or reproduction is permitted which does not comply with these terms. Permissions for commercial use of this work beyond the scope of the License (http://www.eurjchem.com/index.php/eurjchem/pages/view/terms) are administered by Atlanta Publishing House LLC (European Journal of Chemistry).

© Copyright 2019 • Atlanta Publishing House LLC • All Right Reserved.

The opinions expressed in all articles published in European Journal of Chemistry are those of the specific author(s), and do not necessarily reflect the views of Atlanta Publishing House LLC, or European Journal of Chemistry, or any of its employees.

Copyright 2019 Atlanta Publishing House LLC. All rights reserved. This site is owned and operated by Atlanta Publishing House LLC whose registered office is 4614 Lavista road, Tucker, GA, 30084, USA. Registered in USA.