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Reticular synthesis, topological studies and physicochemical properties of a 3D manganese(II) coordination network [Mn3(BTC)2(DMSO)4]n
Leonã da Silva Flores (1)
, Roselia Ives Rosa (2) , Jefferson da Silva Martins (3) , Roberto Rosas Pinho (4) , Renata Diniz (5) , Charlane Cimini Corrêa (6,*) (1) Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(2) Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(3) Department of Physics, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(4) Department of Physics, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(5) Department of Chemistry, Federal University of Minas Gerais, Belo Horizonte, 31270-901, Brazil
(6) Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(*) Corresponding Author
Received: 16 Apr 2019 | Revised: 20 May 2019 | Accepted: 28 May 2019 | Published: 30 Jun 2019 | Issue Date: June 2019
Abstract
In order to build a metal-organic framework with mixed ligands (acid-acid), a 3D coordination network based on manganese metal center was obtained [Mn3(BTC)2(DMSO)4]n; where BTC = Benzene-1,3,5-tricarboxylic acid and DMSO = Dimethylsulfoxide. The crystal structure was determined by single crystal X-ray diffraction, showing the assembly of a tridimensional 3,6-connected non-entangled polymeric network, with RTL topology. The secondary building unit (SBU) acts as a node of the 3-periodic expansion and involves carboxylate- and oxo-bridged metals. The DMSO employed in the synthesis is chemically involved in the coordination as a µ2-O bridge between distinct manganese metal centers. The structural characterization of the material was supported by spectroscopic (infrared absorption and Raman scattering), thermal (TG, DTG, and DTA) and elemental analysis.
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DOI: 10.5155/eurjchem.10.2.180-188.1882
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Funding information
Brazilian Research Development Agencies: CNPq, CAPES, and FAPEMIG (CEX-APQ- 00947-14 and CEX - APQ-01283-14).
Citations
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DOI Link: https://doi.org/10.5155/eurjchem.10.2.180-188.1882
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European Journal of Chemistry 2019, 10(2), 180-188 | doi: https://doi.org/10.5155/eurjchem.10.2.180-188.1882 | Get rights and content
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