European Journal of Chemistry 2019, 10(2), 180-188. doi:10.5155/eurjchem.10.2.180-188.1882

Reticular synthesis, topological studies and physicochemical properties of a 3D manganese(II) coordination network [Mn3(BTC)2(DMSO)4]n


Leonã da Silva Flores (1) orcid , Roselia Ives Rosa (2) orcid , Jefferson da Silva Martins (3) orcid , Roberto Rosas Pinho (4) orcid , Renata Diniz (5) orcid , Charlane Cimini Corrêa (6,*) orcid

(1) Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(2) Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(3) Department of Physics, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(4) Department of Physics, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(5) Department of Chemistry, Federal University of Minas Gerais, Belo Horizonte, 31270-901, Brazil
(6) Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
(*) Corresponding Author

Received: 16 Apr 2019, Accepted: 28 May 2019, Published: 30 Jun 2019

Abstract


In order to build a metal-organic framework with mixed ligands (acid-acid), a 3D coordination network based on manganese metal center was obtained [Mn3(BTC)2(DMSO)4]n; where BTC = Benzene-1,3,5-tricarboxylic acid and DMSO = Dimethylsulfoxide. The crystal structure was determined by single crystal X-ray diffraction, showing the assembly of a tridimensional 3,6-connected non-entangled polymeric network, with RTL topology. The secondary building unit (SBU) acts as a node of the 3-periodic expansion and involves carboxylate- and oxo-bridged metals. The DMSO employed in the synthesis is chemically involved in the coordination as a µ2-O bridge between distinct manganese metal centers. The structural characterization of the material was supported by spectroscopic (infrared absorption and Raman scattering), thermal (TG, DTG, and DTA) and elemental analysis.


Keywords


Manganese; Trimesic acid; Reticular synthesis; Coordination polymer; Coordination network; Secondary building unit

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DOI: 10.5155/eurjchem.10.2.180-188.1882

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How to cite


Flores, L.; Rosa, R.; Martins, J.; Pinho, R.; Diniz, R.; Corrêa, C. Eur. J. Chem. 2019, 10(2), 180-188. doi:10.5155/eurjchem.10.2.180-188.1882
Flores, L.; Rosa, R.; Martins, J.; Pinho, R.; Diniz, R.; Corrêa, C. Reticular synthesis, topological studies and physicochemical properties of a 3D manganese(II) coordination network [Mn3(BTC)2(DMSO)4]n. Eur. J. Chem. 2019, 10(2), 180-188. doi:10.5155/eurjchem.10.2.180-188.1882
Flores, L., Rosa, R., Martins, J., Pinho, R., Diniz, R., & Corrêa, C. (2019). Reticular synthesis, topological studies and physicochemical properties of a 3D manganese(II) coordination network [Mn3(BTC)2(DMSO)4]n. European Journal of Chemistry, 10(2), 180-188. doi:10.5155/eurjchem.10.2.180-188.1882
Flores, Leonã, Roselia Ives Rosa, Jefferson da Silva Martins, Roberto Rosas Pinho, Renata Diniz, & Charlane Cimini Corrêa. "Reticular synthesis, topological studies and physicochemical properties of a 3D manganese(II) coordination network [Mn3(BTC)2(DMSO)4]n." European Journal of Chemistry [Online], 10.2 (2019): 180-188. Web. 22 Sep. 2019
Flores, Leonã, Rosa, Roselia, Martins, Jefferson, Pinho, Roberto, Diniz, Renata, AND Corrêa, Charlane. "Reticular synthesis, topological studies and physicochemical properties of a 3D manganese(II) coordination network [Mn3(BTC)2(DMSO)4]n" European Journal of Chemistry [Online], Volume 10 Number 2 (30 June 2019)

DOI Link: https://doi.org/10.5155/eurjchem.10.2.180-188.1882

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