European Journal of Chemistry

Reticular synthesis, topological studies and physicochemical properties of a 3D manganese(II) coordination network [Mn3(BTC)2(DMSO)4]n

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Published: Jun 30, 2019
DOI: https://doi.org/10.5155/eurjchem.10.2.180-188.1882
Keywords:
Manganese, Trimesic acid, Reticular synthesis, Coordination polymer, Coordination network, Secondary building unit
Section
Research Article
Issue
Vol. 10 No. 2 (2019): June 2019
Dates
Received 2019-04-16
Accepted 2019-05-28
Published 2019-06-30
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Main Article Content

Leonã da Silva Flores
Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
http://orcid.org/0000-0002-1092-8182
Roselia Ives Rosa
Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
http://orcid.org/0000-0002-5801-7919
Jefferson da Silva Martins
Department of Physics, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
http://orcid.org/0000-0003-4499-8549
Roberto Rosas Pinho
Department of Physics, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
http://orcid.org/0000-0002-8637-6388
Renata Diniz
Department of Chemistry, Federal University of Minas Gerais, Belo Horizonte, 31270-901, Brazil
http://orcid.org/0000-0001-9042-9094
Charlane Cimini Corrêa
Department of Chemistry, Federal University of Juiz de Fora, Juiz de Fora, 36036-900, Brazil
http://orcid.org/0000-0002-7113-8870

Abstract

In order to build a metal-organic framework with mixed ligands (acid-acid), a 3D coordination network based on manganese metal center was obtained [Mn3(BTC)2(DMSO)4]n; where BTC = Benzene-1,3,5-tricarboxylic acid and DMSO = Dimethylsulfoxide. The crystal structure was determined by single crystal X-ray diffraction, showing the assembly of a tridimensional 3,6-connected non-entangled polymeric network, with RTL topology. The secondary building unit (SBU) acts as a node of the 3-periodic expansion and involves carboxylate- and oxo-bridged metals. The DMSO employed in the synthesis is chemically involved in the coordination as a µ2-O bridge between distinct manganese metal centers. The structural characterization of the material was supported by spectroscopic (infrared absorption and Raman scattering), thermal (TG, DTG, and DTA) and elemental analysis.


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Flores, L. da S.; Rosa, R. I.; Martins, J. da S.; Pinho, R. R.; Diniz, R.; Corrêa, C. C. Reticular Synthesis, Topological Studies and Physicochemical Properties of a 3D manganese(II) Coordination Network [Mn3(BTC)2(DMSO)4]n. Eur. J. Chem. 2019, 10, 180-188.

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Supporting Agencies

Brazilian Research Development Agencies, CNPq, CAPES, and FAPEMIG (CEX-APQ- 00947-14 and CEX - APQ-01283-14).
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